ÌâÄ¿ÄÚÈÝ
ѧУ¸½½üµÄºþË®Öи¡Æ¼·è³¤£¬Öú³¤Ë®Öʶñ»¯¡£ºþˮˮÑùÖпÉÄܺ¬ÓÐFe3£«¡¢Ba2£«¡¢K£«¡¢H+¡¢NO3£¡¢Cl-¡¢CO32-¡¢SO42-Àë×Ó¡£ÎªÁ˽øÒ»²½È·ÈÏ£¬È¡Ñù½øÐÐʵÑé¼ì²â£º
¢ÙÈ¡Ë®Ñù×Ðϸ¹Û²ì£¬³Ê͸Ã÷¡¢¾ùһ״̬¡£
¢ÚÓÃpHÊÔÖ½²â¶¨ÎÛË®µÄpH£¬ÊÔÖ½ÏÔºìÉ«¡£
¢ÛÏòË®ÑùÖеÎÈëKSCNÈÜÒº£¬³ÊºìÉ«¡£
¢ÜÏòË®ÑùÖеÎÈëÏ¡ÁòËᣬÓдóÁ¿°×É«³Áµí²úÉú£¬ÔÙ¼ÓÏ¡ÏõËᣬ°×É«³Áµí²»Ïûʧ¡£
£¨1£©ÓÉ´Ë¿ÉÖª£¬¸ÃÎÛË®Öп϶¨º¬ÓеÄÀë×ÓÊÇ_________£¬¿Ï¶¨Ã»ÓеÄÀë×ÓÊÇ_________¡£
£¨2£© ¸¡Æ¼·è³¤µÄ¿ÉÄÜÔÒòÊÇË®Öк¬Óн϶àµÄ_____________Àë×Ó¡£
£¨1£©Fe3£«¡¢Ba2£«¡¢H+£» CO32-¡¢SO42-£» £¨2£©K£«¡¢NO3£
½âÎöÊÔÌâ·ÖÎö£ºÓÃpHÊÔÖ½²â¶¨ÎÛË®µÄpH£¬ÊÔÖ½ÏÔºìÉ«£¬ËµÃ÷Ë®Ñù³ÊËáÐÔ£¬Ôòº¬ÓÐH+¡¢CO32-ÒòΪÄÜÓëH+·´Ó¦²»´æÔÚ£¬µÎÈëÏòË®ÑùÖеÎÈëKSCNÈÜÒº£¬³ÊºìÉ«£¬Ö¤Ã÷º¬ÓÐFe3£«£¬²»º¬CO32-£»Fe3£«ÓëCO32-»á·¢ÉúÀë×Ó·´Ó¦¡£ÏòË®ÑùÖеÎÈëÏ¡ÁòËᣬÓдóÁ¿°×É«³Áµí²úÉú£¬ÔÙ¼ÓÏ¡ÏõËᣬ°×É«³Áµí²»Ïûʧ¡£Ö¤Ã÷ÔÈÜÒºÖк¬ÓÐBa2£«¶øÎÞCO32-¡¢SO42- £¬ËüÃǶ¼»áºÍ±µÀë×Ó·¢Éú·´Ó¦¶øʹˮÑù»ë×Ç£¬ÕâÓëÌâÄ¿Ïàì¶Ü¡£¹ÊÔÈÜÒºÒ»¶¨º¬ÓÐFe3£«¡¢Ba2£«¡¢H+Ò»¶¨²»º¬CO32-¡¢SO42-¡£Ö²ÎïÉú³¤ÐèÒª´óÁ¿µÄN¡¢P¡¢KÔªËØ£¬½áºÏË®ÑùËùº¬Àë×Ó£¬ÔÚ¸ÃË®ÑùÖи¡Æ¼·è³¤µÄ¿ÉÄÜÔÒòÊÇË®Öк¬Óн϶àµÄK£«¡¢NO3£Àë×Ó¡£
¿¼µã£º¿¼²éÀë×Ó¹²´æ¡¢Àë×Ó·´Ó¦µÈ֪ʶ¡£

ijÈÜÒºÖнöº¬Ï±íÀë×ÓÖеÄ5ÖÖÀë×Ó£¨²»¿¼ÂÇË®µÄµçÀë¼°Àë×ÓµÄË®½â£©£¬ÇÒÀë×ÓµÄÎïÖʵÄÁ¿¾ùΪ1mol¡£
ÒõÀë×Ó | SO42-¡¢NO3-¡¢Cl- |
ÑôÀë×Ó | Fe3+¡¢Fe2+¡¢NH4+¡¢Cu2+¡¢Al3+ |
¢ÙÈôÏòÔÈÜÒºÖмÓÈëKSCNÈÜÒº£¬ÎÞÃ÷ÏԱ仯¡£¢ÚÈôÏòÔÈÜÒºÖмÓÈë¹ýÁ¿µÄÑÎËᣬÓÐÆøÌåÉú³É£¬ÈÜÒºÖÐÒõÀë×ÓÖÖÀ಻±ä¡£¢ÛÈôÏòÈÜÒºÖмÓÈëBaCl2ÈÜÒº£¬Óа×É«³ÁµíÉú³ÉÊԻشðÏÂÁÐÎÊÌâ¡£
£¨1£©ÈôÏÈÏòÔÈÜÒºÖмÓÈë¹ýÁ¿µÄÑÎËᣬÔÙ¼ÓÈëKSCNÈÜÒº£¬ÏÖÏóÊÇ ¡£
£¨2£©ÔÈÜÒºÖк¬ÓеÄÑôÀë×ÓÊÇ ¡£
£¨3£©ÏòÔÈÜÒºÖмÓÈë×ãÁ¿µÄÑÎËᣬ·¢Éú·´Ó¦µÄÀë×Ó·½³ÌʽΪ ¡£
£¨4£©ÏòÔÈÜÒºÖмÓÈë×ãÁ¿µÄNaOHÈÜÒº£¬³ä·Ö·´Ó¦ºó£¬¹ýÂË¡¢Ï´µÓ¡¢×ÆÉÕ£¬×îÖÕËùµÃ¹ÌÌåÓÃÍÐÅÌÌìƽ³ÆÁ¿ÖÊÁ¿Îª ¡£
ijµç¶Æͳ§ÓÐÁ½ÖÖ·ÏË®ÐèÒª´¦Àí£¬Ò»ÖÖ·ÏË®Öк¬ÓÐCN-Àë×Ó£¬ÁíÒ»ÖÖ·ÏË®Öк¬ÓÐCr2O72-Àë×Ó£®¸Ã³§ÄⶨÈçͼËùʾµÄ·ÏË®´¦ÀíÁ÷³Ì¡£»Ø´ðÒÔÏÂÎÊÌ⣺
£¨1£©²½Öè¢Ú·¢Éú·´Ó¦µÄÀë×Ó·½³Ìʽ¿É±íʾÈçÏ£ºaCN£+bClO£+2cOH£=dCNO£+eN2¡ü+fCO32£+bCl£+cH2O£¬ÉÏÊöÀë×Ó·½³Ìʽ¿ÉÄܵÄÅäƽϵÊýÓжà×飬Çë»Ø´ð£º
¢Ù·½³ÌʽÖÐe : fµÄֵΪ £¨ÌîÑ¡Ïî±êºÅ£©¡£
A£®1 | B£®1/2 | C£®2 | D£®²»ÄÜÈ·¶¨ |
¢ÛÈô·´Ó¦ÖÐתÒÆ0.6molµç×Ó£¬ÔòÉú³ÉµÄÆøÌåÔÚ±ê¿öϵÄÌå»ýÊÇ ¡£
£¨2£©²½Öè¢ÛÖз´Ó¦Ê±£¬Ã¿0.4molCr2O72-תÒÆ2.4molµÄµç×Ó£¬¸Ã·´Ó¦µÄÀë×Ó·½³ÌʽΪ ¡£
£¨3£©È¡ÉÙÁ¿´ý¼ìË®ÑùÓÚÊÔ¹ÜÖУ¬ÏȼÓÈëNaOHÈÜÒº£¬¹Û²ìµ½ÓÐÀ¶É«³ÁµíÉú³É£¬¼ÌÐø¼ÓÈëNaOHÈÜÒº£¬Ö±µ½²»ÔÙ²úÉúÀ¶É«³ÁµíΪֹ£¬ÔÙ¼ÓÈëNa2SÈÜÒº£¬ÓкÚÉ«³ÁµíÉú³É£¬ÇÒÀ¶É«³ÁµíÖð½¥¼õÉÙ£® ÇëÓÃÀë×Ó·½³Ìʽ±íʾ³öÏÖÉÏÊöÑÕÉ«±ä»¯µÄÔÒò¡£
¢Ù²úÉúÀ¶É«³ÁµíµÄÀë×Ó·½³ÌʽΪ £¬¢ÚºóÓÖ±äºÚÉ«³ÁµíµÄÀë×Ó·½³ÌʽΪ ¡£
£¨4£©ÍÊÇÓëÈËÀà¹Øϵ·Ç³£ÃÜÇеÄÓÐÉ«½ðÊô£¬ÒÑÖª³£ÎÂÏ£¬ÔÚÈÜÒºÖÐCu2+Îȶ¨£¬Cu+Ò×ÔÚËáÐÔÌõ¼þÏ·¢Éú£»2Cu+=" Cu+" Cu2+¡£´ó¶àÊý+1¼Û͵Ļ¯ºÏÎïÊÇÄÑÈÜÎÈ磺Cu2O¡¢CuI¡¢CuCl¡¢CuHµÈ¡£
¢Ùд³öCuHÔÚ¹ýÁ¿Ï¡ÑÎËáÖÐÓÐÆøÌåÉú³ÉµÄÀë×Ó·½³Ìʽ ¡£
¢Ú½«CuHÈܽâÔÚÊÊÁ¿µÄÏ¡ÏõËáÖУ¬Íê³ÉÏÂÁз´Ó¦µÄ»¯Ñ§·½³Ìʽ:

½«1.52 gµÄÍþºÏ½ðÍêÈ«ÈܽâÓÚ50mL14.0 mol/LµÄŨÏõËáÖУ¬µÃµ½NO2ºÍN2O4µÄ»ìºÏÆøÌå1120mL(±ê×¼×´¿ö)£¬Ïò·´Ó¦ºóµÄÈÜÒºÖмÓÈË1.0 mol/L NaOHÈÜÒº£¬µ±½ðÊôÀë×ÓÈ«²¿³Áµíʱ£¬µÃµ½2.54 g³Áµí¡£ÏÂÁÐ˵·¨²»ÕýÈ·µÄÊÇ
A£®Èô¸ÃŨÏõËáµÄÃܶÈΪ1.40g/mLÔò¸ÃŨÏõËáµÄÈÜÖÊÖÊÁ¿·ÖÊýΪ63% |
B£®¸ÃºÏ½ðÖÐÍÓëþµÄÎïÖʵÄ×îÖ®±ÈÊÇ2:1 |
C£®NO2ºÍN2O4µÄ»ìºÏÆøÌåÖУ¬NO2µÄÌå»ý·ÖÊýÊÇ80% |
D£®µÃµ½2.54 g³Áµíʱ£¬¼ÓÈËNaOHÈÜÒºµÄÌå»ýÊÇ620 mL |