ÌâÄ¿ÄÚÈÝ

3£®¸ù¾ÝÈÈ»¯Ñ§·½³ÌS £¨ s £©+O2 £¨ g £©=SO2 £¨ g £©¡÷H=-297.23kJ/mol £¨·´Ó¦ÔÚ298K£¬101kPaÏ·¢Éú£©·ÖÎöÏÂÁÐ˵·¨²»ÕýÈ·µÄÊÇ£¨¡¡¡¡£©
A£®±ê¿öÏ£¬È¼ÉÕ1mol S·Å³öµÄÈÈÁ¿Îª297.23 kJ
B£®S £¨ g £©+O2 £¨ g £©=SO2 £¨ g £© ·Å³öµÄÈÈÁ¿´óÓÚ297.23 kJ
C£®S £¨ g £©+O2 £¨ g £©=SO2 £¨ g £©  ·Å³öµÄÈÈÁ¿Ð¡ÓÚ297.23 kJ
D£®ÐγÉ1 mol SO2 µÄ»¯Ñ§¼üËùÊͷŵÄ×ÜÄÜÁ¿´óÓÚ¶ÏÁÑ 1 molS £¨ s £©ºÍ 1mol O2 £¨ g £©µÄ»¯Ñ§¼üËùÎüÊÕµÄ×ÜÄÜÁ¿

·ÖÎö ÓÉS£¨s£©+O2£¨g£©¨TSO2£¨g£©¡÷H=-297.23kJ/mol£¬¿ÉÖª¸Ã·´Ó¦Îª·ÅÈÈ·´Ó¦£¬S£¨s£©=S£¨g£©ÎªÎüÈȹý³Ì£¬ÓɸÇ˹¶¨ÂÉ¿ÉÖª£¬S£¨g£©+O2£¨g£©¨TSO2£¨g£©¡÷H£¼-297.23kJ/mol£¬ÒÔ´ËÀ´½â´ð£®

½â´ð ½â£ºÓÉS£¨s£©+O2£¨g£©¨TSO2£¨g£©¡÷H=-297.23kJ/mol£¬
A£®1molSµÄ״̬²»Öª£¬¿ÉÄÜÊÇÆøÌ壬Ҳ¿ÉÄÜÊǹÌÌ壬¹ÊA´íÎó£»
B£®S£¨s£©=S£¨g£©ÎªÎüÈȹý³Ì£¬ÓɸÇ˹¶¨ÂÉ¿ÉÖª£¬S£¨g£©+O2£¨g£©¨TSO2£¨g£©¡÷H£¼-297.23kJ/mol£¬Ôò·Å³öµÄÈÈÁ¿´óÓÚ297.23 kJ£¬¹ÊBÕýÈ·£»
C£®S£¨s£©=S£¨g£©ÎªÎüÈȹý³Ì£¬ÓɸÇ˹¶¨ÂÉ¿ÉÖª£¬S£¨g£©+O2£¨g£©¨TSO2£¨g£©¡÷H£¼-297.23kJ/mol£¬Ôò·Å³öµÄÈÈÁ¿´óÓÚ297.23 kJ£¬¹ÊC´íÎó£»
D£®¸Ã·´Ó¦Îª·ÅÈÈ·´Ó¦£¬ÔòÐγÉ1 mol SO2µÄ»¯Ñ§¼üËùÊͷŵÄ×ÜÄÜÁ¿´óÓÚ¶ÏÁÑ1 mol S£¨s£©ºÍ1 mol O2£¨g£©µÄ»¯Ñ§¼üËùÎüÊÕµÄ×ÜÄÜÁ¿£¬¹ÊDÕýÈ·£»
¹ÊÑ¡AC£®

µãÆÀ ±¾Ì⿼²éȼÉÕÈȵÄÈÈ»¯Ñ§·´Ó¦·½³Ìʽ£¬Ã÷ȷȼÉյĸÅÄî¼°·´Ó¦ÈÈÓë¼üÄÜ¡¢¸Ç˹¶¨ÂɵĹØÏµ¼´¿É½â´ð£¬ÌâÄ¿ÄѶȲ»´ó£®

Á·Ï°²áϵÁдð°¸
Ïà¹ØÌâÄ¿
13£®º¬¸õ£¨¢ö£©·ÏË®ÄÜÓÕ·¢Ö°©£¬¶ÔÈËÀàºÍ×ÔÈ»»·¾³ÓÐÑÏÖØµÄÆÆ»µ×÷Óã®ÀûÓÃCu2O¹â´ß»¯¿ÉÒÔ´¦Àíº¬ÓÐCr2O72-µÄ·ÏË®£®
¢ñ£®ÖÆÈ¡Cu2O
£¨1£©µç½â·¨£ºÀûÓÃÍ­ºÍîÑ×öµç¼«£¬µç½âº¬ÓÐNaClºÍNaOHµÄÈÜҺʱ£¬·´Ó¦Ö»ÏûºÄÁËÍ­ºÍË®£¬ÌåϵpH¼°Cl-Ũ¶Èά³Ö²»±ä£¨ÈÜÒºÌå»ý±ä»¯ºöÂÔ²»¼Æ£©£®
¢ÙÑô¼«²ÄÁÏÊÇ2H2O+2e-=H2¡ü+2OH-£»£®
¢ÚÒõ¼«µÄµç¼«·´Ó¦Ê½ÊÇ£»µç½â×Ü·´Ó¦Îª£º2Cu+H2O$\frac{\underline{\;ͨµç\;}}{\;}$ H2¡ü+Cu2O£®
£¨2£©»¹Ô­·¨
¢Ù¹¤ÒµÉÏ¿ÉÓÃ루N2H4£©ÓëÐÂÖÆµÄCu£¨OH£©2·´Ó¦ÖƱ¸ÄÉÃ×¼¶Cu2O£¬Í¬Ê±·Å³öN2£¬¸Ã·´Ó¦µÄ»¯Ñ§·½³ÌʽΪ4Cu£¨OH£©2+N2H4$\frac{\underline{\;\;¡÷\;\;}}{\;}$N2¡ü+2Cu2O+6H2O£®
¢Ú¿ØÖÆ100¡æ¡¢pH=5µÄÌõ¼þʱ£¬ÀûÓÃÑÇÁòËáÄÆÓëÁòËáÍ­ÈÜÒº·´Ó¦¿ÉÒÔÖÆµÃCu2O£¬Í¬Ê±²úÉúSO2ÆøÌ壮·´Ó¦¹ý³ÌÖÐÐèÒª²»¶ÏµØ¼ÓÈëÉռÆäÔ­ÒòÊÇ2CuSO4+3Na2SO3=Cu2O+2SO2¡ü+3Na2SO4·´Ó¦¹ý³ÌÖÐÈÜÒºµÄËáÐÔ²»¶ÏµØÔöÇ¿£¬Îªµ÷½ÚpHËùÒÔÐèÒª¼ÓÈëÉռ
¢ò£®ÀûÓÃCu2O¹â´ß»¯´¦Àíº¬ÓÐCr2O72-µÄ·ÏË®µÄÑо¿£®
£¨1£©¹âÕÕÉäµ½Cu2O¹â´ß»¯¼ÁÉϲúÉú¹â´ß»¯·´Ó¦£¬Cr2O72-ºÍH2O·Ö±ðÔÚ¹â´ß»¯·´Ó¦ÖÐÐγɵÄ΢µç¼«ÉÏ·¢Éúµç¼«·´Ó¦£¬·´Ó¦Ô­ÀíÈçͼ1Ëùʾ£®ÔÚͼÖÐÓöÌÏߺͼýÍ·»­³öµç×ÓÒÆ¶¯µÄ·½Ïò£¬Ð´³öCr2O72-ת»¯Cr3+µÄµç¼«·´Ó¦£®
£¨2£©Ñо¿ÖжÔCu2OµÄ×÷ÓÃÌá³öÁ½ÖÖ¼ÙÉ裺
a£®Cu2O×÷¹â´ß»¯¼Á£»b£®Cu2O ÓëCr2O72-·¢ÉúÑõ»¯»¹Ô­·´Ó¦£®
ÒÑÖª£ºCu2OµÄÌí¼ÓÁ¿ÊÇ1.74¡Á10-4mol/L£¬Cr2O72-µÄ³õʼŨ¶ÈÊÇ9.60¡Á10-4mol/L£»¶Ô±ÈʵÑ飬·´Ó¦1.5Сʱ½á¹ûÈçͼ2Ëùʾ£®½áºÏÊÔ¼ÁÓÃÁ¿Êý¾ÝºÍʵÑé½á¹û¿ÉµÃµ½µÄ½áÂÛºÍÒÀ¾ÝÊÇCu2O×÷¹â´ß»¯¼Á£»3Cu2O-Cr2O72-£¬¼ÆËã9.60¡Á10-4¡Á3¡Á69.5%=2.00¡Á10-3£¾1.74¡Á10-4mol/L£»ÊµÑé¿ÉÒÔ¿´µ½Ö»ÓÐÑõ»¯ÑÇÍ­ºÍÖ»ÓйâÕÕʱ£¬Cr2O72-µÄת»¯Âʺܵͣ¬ËµÃ÷·´Ó¦Ìõ¼þÊǹâÕÕÌõ¼þϺÍCu2Oͬʱ´æÔÚ£»£®
£¨3£©ÈÜÒºµÄpH¶ÔCr2O72-½µ½âÂʵÄÓ°ÏìÈç3ͼËùʾ£®
ÒÑÖª£ºCu2OCu+CuSO4£»ËáÐÔÔ½´ó£¬Cr2O72-±»»¹Ô­ÂÊÔ½´ó£®
¢ÙÓÉͼ3¿ÉÖª£¬pH·Ö±ðΪ2¡¢3¡¢4ʱ£¬Cr2O72-µÄ½µ½âÂÊ×îºÃµÄÊÇpH=3£¬ÆäÔ­ÒòÊÇpH£¼2.5ʱCu2O»áÆç»¯£¨×ª»¯£©ÎªCu ºÍCu2+£¬ËùÒÔ²»Ñ¡pH=2£»ËáÐÔÔ½´ó£¬Cr2O72-±»»¹Ô­ÂÊÔ½´ó£¬pH=3ËáÐÔÇ¿ÓÚpH=4µÄÈÜÒº£¬ËùÒÔÑ¡ÔñpH=3£®
¢ÚÒÑÖªpH=5ʱ£¬»á²úÉúCr£¨OH£©3³Áµí£®pH=5ʱ£¬Cr2O72-µÄ½µ½âÂʵ͵ÄÔ­ÒòÊÇpH=5ʱ£¬»á²úÉúCr£¨OH£©3³Áµí£¬³Áµí¸²¸ÇÔÚ´ß»¯¼ÁCu2O±íÃæ£¬Ó°Ïì·´Ó¦¼ÌÐø½øÐУ®

Î¥·¨ºÍ²»Á¼ÐÅÏ¢¾Ù±¨µç»°£º027-86699610 ¾Ù±¨ÓÊÏ䣺58377363@163.com

¾«Ó¢¼Ò½ÌÍø