ÌâÄ¿ÄÚÈÝ
15£®ÌúÔڵؿÇÖеĺ¬Á¿Ô¼Õ¼ 5%×óÓÒ£®Ìú¿óʯµÄÖÖÀàºÜ¶à£¬ÖØÒªµÄÓдÅÌú¿óʯ£¨Ö÷Òª³É·ÖÊÇFe3O4£©¡¢³àÌú¿óʯ£¨Ö÷Òª³É·ÖÊÇ Fe2O3£©µÈ£®£¨l£©Ð´³ö¹¤ÒµÉϸ߯Á¶ÌúµÄ»¯Ñ§·½³Ìʽ£ºFe2O3+3CO$\frac{\underline{\;\;¡÷\;\;}}{\;}$2Fe+3CO2£®
£¨2£©ºìÈȵÄÌúÄܸúË®ÕôÆø·´Ó¦£¬Ò»ÖÖ²úÎïÓë´ÅÌú¿óµÄÖ÷Òª³É·ÖÏàͬ£¬ÁíÒ»ÖÖ²úÎïÊÇ¿ÉȼÐÔÆøÌ壬ÔòÆä·´Ó¦µÄ»¯Ñ§·½³ÌʽΪ3Fe+4H2O$\frac{\underline{\;¸ßÎÂ\;}}{\;}$Fe3O4+4H2£®
£¨3£©ÔÚ³£ÎÂÏ£¬Ìú¸úË®²»Æð·´Ó¦£®µ«ÔÚ³±ÊªµÄ¿ÕÆøÖУ¬ÌúºÜÈÝÒ×ÉúÐ⣨ÌúÐâµÄÖ÷Òª³É·ÖÊÇ Fe203£©¶ø±»¸¯Ê´£¬Ã¿ÄêÒò¸¯Ê´¶øËðʧµÄ¸Ö²ÄÕ¼ÊÀ½ç¸ÖÌúÄê²úÁ¿µÄËÄ·ÖÖ®Ò»£®ÌúÉúÐâµÄ»¯Ñ§ÔÀíÈçÏ£¬ÇëÄãÓÃÀë×Ó·½³ÌʽºÍ»¯Ñ§·½³Ìʽ²¹³äÍêÕû£®
¢ÙÔµç³Ø·´Ó¦£º¸º¼«£º2Fe-4e-¨T2Fe2+¡¢Õý¼«£ºO2+4e-+2H2O=4OH-
¢ÚÇâÑõ»¯ÎïµÄÐγɣºFe2++2OH-¨TFe£¨OH£©2¡ý¡¢4Fe£¨OH£©2+O2+2H2O=4Fe£¨OH£©3
¢ÛÇâÑõ»¯ÎïµÄ·Ö½â£º2Fe£¨OH£©3¨TFe2O3+3H2O£®
£¨4£©ÎªÁË·ÀÖ¹ÌúÉúÐ⣬¿ÉÔÚÌúÖÆÆ·±íÃæ¶ÆÉÏÒ»²ãÍ£¨ÈçÓÒͼװÖã©£¬ÔòÖ±Á÷µçÔ´a¶ËÊÇÕý¼«£¨Ìî¡°Õý¼«¡±»ò¡°¸º¼«¡±£©£¬ÌúÖÆÆ·±íÃæ·¢ÉúµÄµç¼«·´Ó¦Ê½ÎªCu2++2e-=Cu£®
·ÖÎö £¨1£©¹¤ÒµÉÏÓÃÒ»Ñõ»¯Ì¼»¹ÔÑõ»¯ÌúÁ¶Ìú£»
£¨2£©ÌúÓëË®ÕôÆø·´Ó¦Éú³ÉËÄÑõ»¯ÈýÌúºÍÇâÆø£»
£¨3£©ÔÚ³±ÊªµÄ»·¾³Ï£¬ÌúÈÝÒ×·¢ÉúÎüÑõ¸¯Ê´£¬Õý¼«ÑõÆøµÃµ½µç×ÓÉú³ÉÇâÑõ¸ùÀë×Ó£»¸º¼«Ìúʧȥµç×ÓÉú³É¶þ¼ÛÌúÀë×Ó£»ÇâÑõ»¯ÑÇÌú¾ßÓÐÇ¿µÄ»¹ÔÐÔÈÝÒ×±»¿ÕÆøÖеÄÑõÆøÑõ»¯Éú³ÉÇâÑõ»¯Ìú£»
£¨4£©ÔÚÌúÖÆÆ·±íÃæ¶ÆÉÏÒ»²ãÍ£¬Ôò½ðÊôÍÊÇÑô¼«£¬ÌúÊÇÒõ¼«£¬µç½âÖÊÊǺ¬ÓÐÍÀë×ÓµÄÑΣ¬¸ù¾Ýµç½â³ØµÄ¹¤×÷ÔÀíÀ´»Ø´ð£®
½â´ð ½â£º£¨1£©Ò»Ñõ»¯Ì¼ÓëÑõ»¯Ìú·´Ó¦Éú³ÉÌúÓë¶þÑõ»¯Ì¼£¬»¯Ñ§·½³Ìʽ£ºFe2O3+3CO$\frac{\underline{\;\;¡÷\;\;}}{\;}$2Fe+3CO2£»
¹Ê´ð°¸Îª£ºFe2O3+3CO$\frac{\underline{\;\;¡÷\;\;}}{\;}$2Fe+3CO2£»
£¨2£©ÌúÓëË®ÕôÆø·´Ó¦Éú³ÉËÄÑõ»¯ÈýÌúºÍÇâÆø£¬»¯Ñ§·½³Ìʽ£º3Fe+4H2O$\frac{\underline{\;¸ßÎÂ\;}}{\;}$Fe3O4+4H2£»
¹Ê´ð°¸Îª£º3Fe+4H2O$\frac{\underline{\;¸ßÎÂ\;}}{\;}$Fe3O4+4H2£»
£¨3£©ÔÚ³±ÊªµÄ»·¾³Ï£¬ÌúÈÝÒ×·¢ÉúÎüÑõ¸¯Ê´£¬Õý¼«ÑõÆøµÃµ½µç×ÓÉú³ÉÇâÑõ¸ùÀë×Ó£¬µç¼«·´Ó¦Ê½Îª£ºO2+4e-+2H2O=4OH-£»
ÇâÑõ»¯ÑÇÌúÓëÑõÆø¡¢Ë®·´Ó¦Éú³ÉÇâÑõ»¯Ìú£¬»¯Ñ§·½³Ìʽ£º4Fe£¨OH£©2+O2+2H2O=4Fe£¨OH£©3£»
O2+4e-+2H2O=4OH-£¬4Fe£¨OH£©2+O2+2H2O=4Fe£¨OH£©3£»
£¨4£©ÔÚÌúÖÆÆ·±íÃæ¶ÆÉÏÒ»²ãÍ£¬Ôò½ðÊôÍÊÇÑô¼«£¬ºÍµçÔ´µÄÕý¼«ÏàÁ¬£¬Õý¼«£¬Òõ¼«ÉÏ·¢Éú»¹Ô·´Ó¦£¬¼´Cu2++2e-=Cu£¬
¹Ê´ð°¸Îª£ºÕý¼«£»Cu2++2e-=Cu£®
µãÆÀ ±¾Ì⿼²éÁË»¯Ñ§·½³Ìʽ¡¢µç¼«·´Ó¦Ê½µÄÊéд£¬Ã÷È·Ôµç³Ø¡¢µç½â³Ø¹¤×÷ÔÀíÊǽâÌâ¹Ø¼ü£¬ÌâÄ¿ÄѶȲ»´ó£®
A£® | Ca£¨HCO3£©2ÈÜÒºÓë¹ýÁ¿Ca£¨OH£©2ÈÜÒº·´Ó¦£ºCa2++HCO3-+OH-¨TCaCO3¡ý+H2O | |
B£® | ÓöèÐԵ缫µç½âMgCl2ÈÜÒº£º2Cl-+2H2O$\frac{\underline{\;ͨµç\;}}{\;}$H2¡ü+Cl2¡ü+2OH- | |
C£® | ÂÈÆøͨÈëË®ÖУºC12+H2O¨T2H++C1-+C1O- | |
D£® | ÑÇÁòËá±µÓëÏ¡ÏõËá·´Ó¦£ºBaSO3+2H+¨TBa2++SO2¡ü+H2O |
A£® | ¼×Í黯ѧÐÔÖʱȽÏÎȶ¨£¬²»Äܱ»ÈκÎÑõ»¯¼ÁÑõ»¯ | |
B£® | ÒÒÏ©ºÍ±½·Ö×ÓÖи÷Ô×Ó¶¼ÔÚͬһƽÃæ | |
C£® | ÒÒÏ©ºÍ±½¾ù¿ÉʹäåË®ÍÊÉ«£¬ÇÒÆäÍÊÉ«ÔÀíÏàͬ | |
D£® | ʯÓ͵ÄÁÑ»¯¡¢·ÖÁó¡¢Áѽ⣬úµÄ¸ÉÁó¶¼ÊÇ»¯Ñ§±ä»¯ |
A£® | ×îÍâ²ãµç×ÓÊýÓë´ÎÍâ²ãµç×ÓÊýÏàµÈµÄÔ×Ó | |
B£® | M²ãµç×ÓÊýΪK²ãµç×ÓÊýÒ»°ëµÄÔ×Ó | |
C£® | ×îÍâ²ãÓÐ2¸öµç×ÓµÄÔ×Ó | |
D£® | M²ãµç×ÓÊýµÈÓÚÆäÄÚ²ãµç×ÓÊýÖ®ºÍ$\frac{1}{5}$µÄÔ×Ó |