ÌâÄ¿ÄÚÈÝ

£¨1£©Ä³»¯Ñ§ÐËȤС×é¶Ô¡°Å©·òɽȪ¡±¿óȪˮ½øÐмì²âʱ£¬·¢ÏÖ1.0  L¸Ã¿óȪˮÖк¬ÓÐ45.6mg Mg2+µÄÎïÖʵÄÁ¿Å¨¶ÈΪ
1.90¡Á10-3mol/L
1.90¡Á10-3mol/L
£®£¨Ìáʾ£º1g=1000mg£©
£¨2£©ÔÚKCLºÍCaCl2Ëù×é³ÉµÄij»ìºÏÎïÖУ¬K+ÓëCa2+µÄÎïÖʵÄÁ¿Ö®±ÈΪ2£º1£¬ÔòKClÓëCaCl2µÄÎïÖʵÄÁ¿Ö®±ÈΪ
2£º1
2£º1
£¬¸Ã»ìºÏÎïÖеÄCaCl2µÄÖÊÁ¿·ÖÊýΪ
42.7%
42.7%
£®
·ÖÎö£º£¨1£©¸ù¾Ýn=
m
M
=cV¼ÆË㣻
£¨2£©¸ù¾Ýn£¨KCl£©£ºn£¨CaCl2£©=n£¨K+£©£ºn£¨Ca2+£©¼ÆËãÎïÖʵÄÁ¿Ö®±È£¬¸ù¾Ým=nM¼ÆËãÖÊÁ¿¹Øϵ£¬½ø¶ø¼ÆËãÖÊÁ¿·ÖÊý£®
½â´ð£º½â£º£¨1£©n£¨Mg2+£©=
45.6¡Á10-3g
24g/mol
=1.9¡Á10-3mol£¬c£¨Mg2+£©=
1.9¡Á10-3mol
1.0L
=1.90¡Á10-3mol/L£¬
¹Ê´ð°¸Îª£º1.90¡Á10-3mol/L£»
£¨2£©ÓÉKClÓëCaCl2µÄ»¯Ñ§Ê½¿ÉÖª£ºn£¨KCl£©£ºn£¨CaCl2£©=n£¨K+£©£ºn£¨Ca2+£©=2£º1£¬
ÉèKClΪ2mol£¬ÔòCaCl2Ϊ1mol£¬
Ôòm£¨KCl£©=2mol¡Á74.5g/mol=149g£¬m£¨CaCl2£©=1mol¡Á111g/mol=111g£¬
ËùÒÔ£º¸Ã»ìºÏÎïÖеÄCaCl2µÄÖÊÁ¿·ÖÊýΪ
111g
111g+149g
¡Á100%
=42.7%£¬
¹Ê´ð°¸Îª£º2£º1£»42.7%£®
µãÆÀ£º±¾Ì⿼²éÎïÖʵÄÁ¿µÄÏà¹Ø¼ÆË㣬ÌâÄ¿ÄѶȲ»´ó£¬×¢ÒâÏà¹ØÎïÀíÁ¿µÄ¼ÆË㹫ʽµÄÔËÓã®
Á·Ï°²áϵÁдð°¸
Ïà¹ØÌâÄ¿
µÎ¶¨·¨ÊÇ»¯Ñ§Ñо¿Öг£ÓõĶ¨Á¿ÊµÑé·½·¨£®
£¨1£©Ä³»¯Ñ§ÐËȤС×éÓÃÒÑ֪Ũ¶ÈµÄÁòËáµÎ¶¨Î´ÖªÅ¨¶ÈµÄÇâÑõ»¯ÄÆÈÜÒº²â¶¨ÆäŨ¶È£®
¢ÙʵÑéÖÐӦѡÓõÄָʾ¼ÁΪ
·Ó̪£¨¼×»ù³È£©
·Ó̪£¨¼×»ù³È£©
£®
¢ÚÏÂÁвÙ×÷µ¼Ö²ⶨ½á¹ûÆ«¸ßµÄÓÐ
ac
ac
£®
a£®ËáʽµÎ¶¨¹ÜÓÃÕôÁóË®ÈóÏ´ºóδÓÃÁòËáÈóÏ´
b£®×¶ÐÎÆ¿ÓÃÕôÁóË®ÈóÏ´ºóδÓôý²âÇâÑõ»¯ÄÆÈÜÒºÈóÏ´
c£®ËáʽµÎ¶¨¹ÜµÎ¶¨Ç°¼â×ì´¦ÓÐÆøÅÝ£¬µÎ¶¨ºóÆøÅÝÏûʧ
£¨2£©ÄªÀÖ·¨ÊÇÒ»ÖÖ³ÁµíµÎ¶¨·¨£®²â¶¨Ä³ÈÜÒºµÄc£¨Cl-£©£¬ÒÔK2CrO4Ϊָʾ¼Á£¬Óñê×¼ÏõËáÒøÈÜÒºµÎ¶¨´ý²âÒº[Ksp£¨AgCl£©=1.56¡Á10-10£¬Ksp£¨Ag2CrO4£©=1.10¡Á10-12£¬Ag2CrO4ΪשºìÉ«]
¢ÙµÎ¶¨ÖÕµãµÄÏÖÏóÊÇ
Éú³ÉשºìÉ«³Áµí
Éú³ÉשºìÉ«³Áµí
£®
¢Ú¸ÃµÎ¶¨ÊÊÒ˵ÄpH·¶Î§ÊÇ6.5¡«10.5£¬ÈôÈÜÒºÖÐÓÐï§ÑδæÔÚ£¬c£¨NH4+£©£¼0.05mol/Lʱ£¬Ó¦½«ÈÜÒºµÄpH¿ØÖÆÔÚ6.5¡«7.2£®ÏÂÁÐÓйØ˵·¨ÄãÈÏΪÕýÈ·µÄÓÐ
ab
ab
£®
a£®ÈôÈÜÒºpH£¼6.5£¬ÔòƽºâCr2O72-+H2O?2CrO42-+2H+×óÒÆ£¬µ¼Öµζ¨ÖÕµãÖͺó£®
b£®ÈôÈÜÒºÖÐÓÐï§ÑδæÔÚ£¬µ±pH£¾7.2ʱ£¬ÔòÒò¿ÉÄÜÉú³É[Ag£¨NH3£©2]+£¬µ¼ÖÂÖÕµãÖͺó£®
c£®µÎ¶¨Ê±Ó¦¾çÁÒÒ¡¶¯£¬´Ùʹ±»AgCl³ÁµíÎü¸½µÄCl-¼°Ê±ÊͷųöÀ´£¬·ÀÖ¹µÎ¶¨ÖÕµãÖͺó£®
£¨3£©Ñõ»¯»¹Ô­µÎ¶¨ÊÇË®»·¾³¼à²âµÄ³£Ó÷½·¨¿ÉÓÃÓڲⶨ·ÏË®ÖеĻ¯Ñ§ºÄÑõÁ¿£¨µ¥Î»mg/L--ÿÉýË®ÑùÖл¹Ô­ÐÔÎïÖʱ»Ñõ»¯ÐèO2µÄÖÊÁ¿£©£®Ä³ÐËȤС×éÿ´ÎÈ¡100mL·ÏË®£¬ÓÃÁòËáËữºó£¬¼ÓÈë0.01667mol/LK2CrO7ÈÜÒº25.00mL£¬Ê¹Ë®ÑùÖеĻ¹Ô­ÐÔÎïÖÊÍêÈ«Ñõ»¯£¬È»ºóÓÃ0.1000mol/LFeSO4±ê×¼ÈÜÒºµÎ¶¨Ê£ÓàµÄCr2O72-£®ÊµÑéÊý¾Ý¼Ç¼ÈçÏ£º
ʵÑéÐòºÅ FeSO4ÈÜÒºµÄÌå»ý¶ÁÊý/mL
µÎ¶¨Ç° µÎ¶¨ºó
1 0.10 16.20
2 0.30 15.31
3 0.20 15.19
ÊԻشðÏÂÁÐÎÊÌ⣺
¢Ù
1
1
Cr2O72-+
6
6
Fe2++
14H+
14H+
¨T
2
2
Cr3++
6
6
Fe3++
7
7
H2O
¢Ú¼ÆËã¸Ã·ÏË®µÄ»¯Ñ§ºÄÑõÁ¿£®£¨Ð´³ö¼ÆËã¹ý³Ì£¬½á¹û±£ÁôһλСÊý£®£©
¢ñ£®£¨1£©Ä³»¯Ñ§ÐËȤС×éÓû´ÓÏÂÁÐ×°ÖÃÖÐÑ¡È¡±ØÒªµÄ×°ÖÃÖÆÈ¡£¨NH4£©2SO4ÈÜÒº£¬Á¬½ÓµÄ˳Ðò£¨ÓýӿÚÐòºÅ×Öĸ±íʾ£©ÊÇ£ºa
 
£®
¾«Ó¢¼Ò½ÌÍø
£¨2£©½«×°ÖÃCÖÐÁ½ÖÖÒºÌå·ÖÀ뿪µÄ²Ù×÷Ãû³ÆÊÇ
 
£®×°ÖÃDµÄ×÷ÓÃÊÇ
 
£®
¢ò£®¹ýÑõ»¯¸Æ¿ÉÒÔÓÃÓÚ¸ÄÉƵرíË®ÖÊ¡¢´¦Àíº¬ÖؽðÊôÁ£×Ó·ÏË®ºÍÖÎÀí³à³±£¬Ò²¿ÉÓÃÓÚÓ¦¼±¹©ÑõµÈ£®¹¤ÒµÉÏÉú²ú¹ýÑõ»¯¸ÆµÄÖ÷ÒªÁ÷³ÌÈçÏ£º
¾«Ó¢¼Ò½ÌÍø
ÒÑÖªCaO2?8H2O³Ê°×É«£¬Î¢ÈÜÓÚË®£®I2+2S2O32-=2I-+S4O62-
£¨1£©ÓÃÉÏÊö·½·¨ÖÆÈ¡CaO2?8H2OµÄ»¯Ñ§·½³ÌʽÊÇ
 
£»
£¨2£©¼ìÑ顰ˮϴ¡±ÊÇ·ñºÏ¸ñµÄ·½·¨ÊÇ
 
£»
£¨3£©²â¶¨²úÆ·ÖÐCaO2µÄº¬Á¿µÄʵÑé²½ÖèÊÇ£º
µÚÒ»²½£º×¼È·³ÆÈ¡a g²úÆ·ÓÚ׶ÐÎÆ¿ÖУ¬¼ÓÈëÊÊÁ¿ÕôÁóË®ºÍ¹ýÁ¿µÄb g KI¾§Ì壬ÔÙµÎÈëÉÙÁ¿2mol/LµÄH2SO4ÈÜÒº£¬³ä·Ö·´Ó¦£®
µÚ¶þ²½£ºÏòÉÏÊö׶ÐÎÆ¿ÖмÓÈ뼸µÎµí·ÛÈÜÒº£®
µÚÈý²½£ºÖðµÎ¼ÓÈëŨ¶ÈΪc mol?L-1µÄNa2S2O3ÈÜÒºÖÁ·´Ó¦ÍêÈ«£¬ÏûºÄNa2S2O3ÈÜÒºV mL£®
¢ÙÅжϴ˵ζ¨ÊµÑé´ïµ½ÖÕµãµÄ·½·¨ÊÇ£º
 
£®
¢ÚCaO2µÄÖÊÁ¿·ÖÊýΪ
 
 £¨ÓÃ×Öĸ±íʾ£©£»
¢ÛijͬѧµÚÒ»²½ºÍµÚ¶þ²½µÄ²Ù×÷¶¼ºÜ¹æ·¶£¬µÚÈý²½µÎËÙÌ«Âý£¬ÕâÑù²âµÃµÄCaO2µÄÖÊÁ¿·ÖÊý¿ÉÄÜ
 
£¨Ìî¡°²»ÊÜÓ°Ï족¡¢¡°Æ«µÍ¡±»ò¡°Æ«¸ß¡±£©£®

Î¥·¨ºÍ²»Á¼ÐÅÏ¢¾Ù±¨µç»°£º027-86699610 ¾Ù±¨ÓÊÏ䣺58377363@163.com

¾«Ó¢¼Ò½ÌÍø