ÌâÄ¿ÄÚÈÝ
¡¾ÌâÄ¿¡¿(1)NiO(Ñõ»¯Äø)¾§ÌåµÄ½á¹¹ÓëNaClÏàͬ£¬Ni2+Óë×îÁÚ½üO2-µÄºË¼ä¾àÀëΪa¡Á10-8cm£¬¼ÆËãNiO¾§ÌåµÄÃܶÈ____________________¡£(ÒÑÖªNiOµÄĦ¶ûÖÊÁ¿Îª74.7gmol-1)
(2)ÌìÈ»µÄºÍ¾ø´ó²¿·ÖÈ˹¤ÖƱ¸µÄ¾§Ì嶼´æÔÚ¸÷ÖÖȱÏÝ¡£ÀýÈ磺ÔÚijÖÖNiO¾§ÌåÖоʹæÔÚÈçÏÂͼËùʾµÄȱÏÝ£ºÒ»¸öNi2+¿Õȱ£¬ÁíÓÐÁ½¸öNi2+±»Á½¸öNi3+ËùÈ¡´ú£¬Æä½á¹û¾§ÌåÈԳʵçÖÐÐÔ£¬µ«»¯ºÏÎïÖÐNiºÍOµÄ±Èֵȴ·¢ÉúÁ˱仯¡£Ä³Ñõ»¯ÄøÑùÆ·×é³ÉΪNi0.97O£¬ÊÔ¼ÆËã¸Ã¾§ÌåÖÐNi3+ÓëNi2+µÄÀë×ÓÊýÖ®±È____________________¡£
¡¾´ð°¸¡¿ gcm-3 6¡Ã91
¡¾½âÎö¡¿£¨1£©¾§°ûÖÐNiÔ×ÓÊýĿΪ1+12¡Á=4£¬ÑõÔ×ÓÊýĿΪ8¡Á+6¡Á=4£¬¾§°ûÖÊÁ¿Îª4¡Ág£¬¾§°û±ß³¤Îª2a¡Á10-8cm£¬¾§°ûÌå»ýΪ(2a¡Á10-8cm)3£¬NiO¾§ÌåµÄÃܶÈΪΪ4¡Ág¡Â(2a¡Á10-8cm)3=g/cm3£»£¨2£©Éè1mol Ni0.97OÖк¬Ni3+xmol£¬Ni2+Ϊ(0.97£x)mol£¬¸ù¾Ý¾§ÌåÈԳʵçÖÐÐÔ£¬¿ÉÖª 3x+2¡Á(0.97£x)=2¡Á1£¬x=0.06mol £¬Ni2+Ϊ(0.97£x)mol=0.91mol£¬¼´Àë×ÓÊýÖ®±ÈΪNi3+£ºNi2+=0.06£º0.91=6£º91¡£
¡¾ÌâÄ¿¡¿»ÆÌú¿óʯµÄÖ÷Òª³É·ÖΪFeS2ºÍÉÙÁ¿FeS£¨¼ÙÉèÆäËûÔÓÖÊÖв»º¬Fe¡¢SÔªËØ£¬ÇÒ¸ßÎÂϲ»·¢Éú»¯Ñ§±ä»¯£©£¬ÊÇÎÒ¹ú´ó¶àÊýÁòË᳧ÖÆÈ¡ÁòËáµÄÖ÷ÒªÔÁÏ¡£Ä³»¯Ñ§ÐËȤС×é¶Ô¸Ã»ÆÌú¿óʯ½øÐÐÈçÏÂʵÑé̽¾¿¡£½«m1 g¸Ã»ÆÌú¿óʯµÄÑùÆ··ÅÈëÈçͼװÖ㨼гֺͼÓÈÈ×°ÖÃÂÔ£©µÄʯӢ¹ÜÖУ¬´Óa´¦²»¶ÏµØ»º»ºÍ¨Èë¿ÕÆø£¬¸ßÎÂ×ÆÉÕ»ÆÌú¿óÑùÆ·ÖÁ·´Ó¦ÍêÈ«¡£Æä·´Ó¦µÄ»¯Ñ§·½³ÌʽΪ£º
¡¾ÊµÑéÒ»¡¿£º²â¶¨ÁòÔªËصĺ¬Á¿
·´Ó¦½áÊøºó£¬½«ÒÒÆ¿ÖеÄÈÜÒº½øÐÐÈçÏ´¦Àí£º
¢Ù¹ÄÈë¿ÕÆøµÄ×÷ÓÃÊÇ_________________________________¡£
¢Ú·´Ó¦½áÊøºóÒÒÆ¿ÖеÄÈÜÒºÐè¼Ó×ãÁ¿H2O2ÈÜÒºµÄÄ¿µÄÊÇ£¨Óû¯Ñ§·½³Ìʽ±íʾ£©________________________________________¡£
H2O2¿ÉÒÔ¿´×÷ÊÇÒ»ÖÖºÜÈõµÄËᣬд³öÆäµçÀë·½³Ìʽ£º_____________________¡£
£¨3£©¸Ã»ÆÌú¿óʯÖÐÁòÔªËصÄÖÊÁ¿·ÖÊýΪ______________£¨Áгö±í´ïʽ¼´¿É£©¡£
¡¾ÊµÑé¶þ¡¿£º²â¶¨ÌúÔªËصĺ¬Á¿
£¨4£©¢ÚÖУ¬ÈôÓÃÌú·Û×÷»¹Ô¼Á£¬ÔòËù²âµÃµÄÌúÔªËصĺ¬Á¿____________£¨Ìî¡°Æ«´ó¡±¡¢¡°Æ«Ð¡¡±»ò¡°ÎÞÓ°Ï족£©¡£
£¨5£©¢ÛÖУ¬ÐèÒªÓõ½µÄÒÇÆ÷³ýÉÕ±¡¢²£Á§°ô¡¢½ºÍ·µÎ¹ÜÍ⣬»¹ÓÐ_________________¡£
£¨6£©Ä³Í¬Ñ§Ò»¹²½øÐÐÁËËĴεζ¨ÊµÑ飬ʵÑé½á¹û¼Ç¼ÈçÏ£º
ʵÑé´ÎÊý | µÚÒ»´Î | µÚ¶þ´Î | µÚÈý´Î | µÚËÄ´Î |
ÏûºÄKMnO4ÈÜÒºÌå»ý/mL | 25.00 | 25.03 | 20.00 | 24.97 |
¸ù¾ÝËù¸øÊý¾Ý£¬¼ÆËã¸ÃÏ¡ÊÍÒºÖÐFe2+µÄÎïÖʵÄÁ¿Å¨¶ÈΪc(Fe2+) £½_______________¡£
¡¾ÌâÄ¿¡¿½«Ò»¶¨Á¿µÄSO2ͨÈëµâË®ÖУ¬·Ö±ð½øÐÐÏÂÁÐʵÑ飬ÄÜÖ¤Ã÷SO2Óëµâ·¢ÉúÑõ»¯»¹Ô·´Ó¦µÄÊÇ
²Ù×÷ | ÏÖÏó»ò½á¹û | |
A | È¡»ìºÏÈÜÒº¼ÓÈëµí·ÛÈÜÒº | ÈÜÒº±äÀ¶ |
B | È¡»ìºÏÈÜÒº¼ÓÈëBaCl2ÈÜÒº | Óа×É«³Áµí |
C | ²âͨÈëÇ°ºóÈÜÒºµÄpH | pH¼õС |
D | È¡»ìºÏÈÜÒº¼ÓÈëAgNO3ÈÜÒº | ÓлÆÉ«³Áµí |
A. A B. B C. C D. D