ÌâÄ¿ÄÚÈÝ
(10·Ö)A¡¢B¡¢C¡¢D¡¢E¡¢F¡¢GÆßÖÖÔªËصÄÔ×ÓÐòÊýÒÀ´ÎµÝÔö¡£ÒÑÖª£º
¢ÙGµÄÔ×ÓÐòÊýΪ29£¬ÆäÓàµÄ¾ùΪ¶ÌÖÜÆÚÖ÷×åÔªËØ£»
¢ÚAÊÇÓîÖæÖк¬Á¿×î¶àµÄÔªËØ£¬BÔ×Ó×îÍâ²ãµç×ÓÊýÊÇ´ÎÍâ²ãµç×ÓÊýµÄ2±¶£¬CÔ×ÓºËÍâÓÐÈý¸öδ³É¶Ôµç×Ó£»
¢ÛDºÍEÔ×Ó¼Ûµç×ÓÅŲ¼Ê½¾ùΪns2np4£»¢ÜFµÄµ¥ÖÊÊÇ»ÆÂÌÉ«ÆøÌå¡£
Çë»Ø´ðÏÂÁÐÎÊÌ⣺
(1)G2+µÄºËÍâµç×ÓÅŲ¼Ê½ÊÇ ¡£ÔÚ[G(NH3)4]2+Àë×ÓÖУ¬G2+ÓëNH3·Ö×ÓÐγɵÄÊÇ ¼ü¡£
(2)ÓëB¡¢CÐγɵÄÒõÀë×Ó(BC¡ª)»¥ÎªµÈµç×ÓÌåµÄ΢Á£ÓÐ ¡¢ (·Ö×ÓºÍÀë×Ó¸÷дһÖÖ)¡£
(3)BÓëCÐγɵĻ¯ºÏÎïÖУ¬ÏÂÁÐÅжÏÕýÈ·µÄÊÇ ¡£
a£®Ç⻯ÎïÎȶ¨ÐÔ£ºB>C b£®Ç⻯Îï·Ðµã£ºB<C
c£®×î¸ß¼ÛÑõ»¯ÎïµÄË®»¯ÎïËáÐÔ£ºB<C d£®·Ç½ðÊôÐÔ£ºB>C
(4)B¡¢C¡¢DµÚÒ»µçÀëÄÜÓÉСµ½´óµÄ˳ÐòΪ (ÓÃÔªËØ·ûºÅ×÷´ð)£¬BµÄÒ»ÖÖÇ⻯ÎïÏà¶Ô·Ö×ÓÖÊÁ¿Îª26£¬·Ö×ÓÖеĦҼüÓë¦Ð¼üÊýÄ¿±ÈΪ ¡£
(5)ÆßÖÖÔªËØÖУ¬µç¸ºÐÔ×î´óµÄÔªËØÓëBÔªËØÐγɻ¯ºÏÎïµç×ÓʽΪ £¬¸ÃÎïÖʵľ§ÌåÊôÓÚ ¡£
¢ÙGµÄÔ×ÓÐòÊýΪ29£¬ÆäÓàµÄ¾ùΪ¶ÌÖÜÆÚÖ÷×åÔªËØ£»
¢ÚAÊÇÓîÖæÖк¬Á¿×î¶àµÄÔªËØ£¬BÔ×Ó×îÍâ²ãµç×ÓÊýÊÇ´ÎÍâ²ãµç×ÓÊýµÄ2±¶£¬CÔ×ÓºËÍâÓÐÈý¸öδ³É¶Ôµç×Ó£»
¢ÛDºÍEÔ×Ó¼Ûµç×ÓÅŲ¼Ê½¾ùΪns2np4£»¢ÜFµÄµ¥ÖÊÊÇ»ÆÂÌÉ«ÆøÌå¡£
Çë»Ø´ðÏÂÁÐÎÊÌ⣺
(1)G2+µÄºËÍâµç×ÓÅŲ¼Ê½ÊÇ ¡£ÔÚ[G(NH3)4]2+Àë×ÓÖУ¬G2+ÓëNH3·Ö×ÓÐγɵÄÊÇ ¼ü¡£
(2)ÓëB¡¢CÐγɵÄÒõÀë×Ó(BC¡ª)»¥ÎªµÈµç×ÓÌåµÄ΢Á£ÓÐ ¡¢ (·Ö×ÓºÍÀë×Ó¸÷дһÖÖ)¡£
(3)BÓëCÐγɵĻ¯ºÏÎïÖУ¬ÏÂÁÐÅжÏÕýÈ·µÄÊÇ ¡£
a£®Ç⻯ÎïÎȶ¨ÐÔ£ºB>C b£®Ç⻯Îï·Ðµã£ºB<C
c£®×î¸ß¼ÛÑõ»¯ÎïµÄË®»¯ÎïËáÐÔ£ºB<C d£®·Ç½ðÊôÐÔ£ºB>C
(4)B¡¢C¡¢DµÚÒ»µçÀëÄÜÓÉСµ½´óµÄ˳ÐòΪ (ÓÃÔªËØ·ûºÅ×÷´ð)£¬BµÄÒ»ÖÖÇ⻯ÎïÏà¶Ô·Ö×ÓÖÊÁ¿Îª26£¬·Ö×ÓÖеĦҼüÓë¦Ð¼üÊýÄ¿±ÈΪ ¡£
(5)ÆßÖÖÔªËØÖУ¬µç¸ºÐÔ×î´óµÄÔªËØÓëBÔªËØÐγɻ¯ºÏÎïµç×ÓʽΪ £¬¸ÃÎïÖʵľ§ÌåÊôÓÚ ¡£
(µÚÈýÎÊ2·Ö£¬ÆäÓàÿ¿Õ1·Ö) (1)1s22s22p63s23p63d9 Åäλ
(2)N2¡¢CO¡¢C22£¡¢O22+¡¢NO+µÈ (3)bc (4)C<O<N 3:2 (5) ·Ö×Ó¾§Ìå
(2)N2¡¢CO¡¢C22£¡¢O22+¡¢NO+µÈ (3)bc (4)C<O<N 3:2 (5) ·Ö×Ó¾§Ìå
ÊÔÌâ·ÖÎö£ºGµÄÔ×ÓÐòÊýΪ29£¬ÔòGÊÇÍ¡£AÊÇÓîÖæÖк¬Á¿×î¶àµÄÔªËØ£¬ËùÒÔAÊÇO¡£BÔ×Ó×îÍâ²ãµç×ÓÊýÊÇ´ÎÍâ²ãµç×ÓÊýµÄ2±¶£¬ÔòBÊÇ̼ԪËØ¡£FµÄµ¥ÖÊÊÇ»ÆÂÌÉ«ÆøÌ壬Òò´ËFÊÇCl¡£DºÍEÔ×Ó¼Ûµç×ÓÅŲ¼Ê½¾ùΪns2np4£¬ËùÒÔ¸ù¾ÝÔ×ÓÐòÊý´óС¿ÉÖª£¬DÊÇO£¬EÊÇS¡£ÓÖÒòΪCÔ×ÓºËÍâÓÐÈý¸öδ³É¶Ôµç×Ó£¬ËùÒÔCÊÇN¡£
£¨1£©¸ù¾Ý¹¹ÔìÔÀí¿ÉÖª£¬G2+µÄºËÍâµç×ÓÅŲ¼Ê½ÊÇ1s22s22p63s23p63d9£»ÍÀë×ӺͰ±Æø·Ö×ÓÄÜÐγÉÅäλ¼ü¡£
£¨2£©¼Ûµç×ÓÊýºÍÔ×ÓÊý·Ö±ð¶¼ÏàµÈµÄÊǵȵç×ÓÌ壬Òò´ËÓëB¡¢CÐγɵÄÒõÀë×ÓCN¡ª»¥ÎªµÈµç×ÓÌåµÄ΢Á£ÓÐN2¡¢CO¡¢C22£¡¢O22+¡¢NO+µÈ¡£
£¨3£©·Ç½ðÊôÐÔѹǿ£¬Ç⻯ÎïµÄÎȶ¨ÐÔԽǿ¡£µªÔªËصķǽðÊôÐÔÇ¿ÓÚ̼ԪËصģ¬ËùÒÔÇ⻯ÎïÎȶ¨ÐÔÊÇB£¼C£¬aºÍd¶¼²»ÕýÈ·£»°±Æø·Ö×Ó¼ä´æÔÚÇâ¼ü£¬·Ðµã¸ßÓÚ¼×ÍéµÄ£¬bÕýÈ·£»·Ç½ðÊôÐÔѹǿ£¬×î¸ß¼ÛÑõ»¯ÎïµÄË®»¯ÎïµÄËáÐÔԽǿ£¬cÕýÈ·£¬´ð°¸Ñ¡bc¡£
£¨4£©·Ç½ðÊôÐÔԽǿ£¬µÚÒ»µçÀëÄÜÔ½´ó¡£µ«ÓÉÓÚµªÔªËصÄ2p¹ìµÀµç×ÓÊôÓÚ°ë³äÂú״̬£¬Îȶ¨ÐÔÇ¿£¬ËùÒÔµÚÒ»µçÀëÄÜ´óС˳ÐòÊÇC£¼O£¼N¡£Ïà¶Ô·Ö×ÓÖÊÁ¿Îª26µÄ̼ԪËصÄÇ⻯ÎïÊÇÒÒȲ£¬·Ö×ÓÖк¬ÓÐ̼̼Èý¼ü¡£µ¥¼ü¶¼ÊǦҼü£¬Èý¼üÊÇÓÉ1¸ö¦Ò¼üºÍ2¸ö¦Ð¼ü¹¹³ÉµÄ£¬ËùÒÔÒÒȲ·Ö×ÓÖеĦҼüÓë¦Ð¼üÊýÄ¿±ÈΪ3:2¡£
£¨5£©ÆßÖÖÔªËØÖУ¬µç¸ºÐÔ×î´óµÄÔªËØÊÇÑõÔªËØ£¬ºÍ̼ԪËØÐγɵĻ¯ºÏÎïÊÇCO2£¬º¬Óм«ÐÔ¼ü£¬µç×ÓʽÊÇ
£¬¸ÃÎïÖʵľ§ÌåÊôÓÚ·Ö×Ó¾§Ìå¡£
µãÆÀ£º¸ÃÌâÒÔ¡°ÖÜÆÚ±íÖÐÔªËصÄÍƶϡ±ÎªÔØÌ壬¿¼²éѧÉú¶ÔÔªËØÖÜÆÚ±íµÄÊìϤ³Ì¶È¼°Æä¶Ô±íÖи÷ÔªËØÐÔÖʺÍÏàÓ¦Ô×ӽṹµÄÖÜÆÚÐԵݱä¹æÂɵÄÈÏʶºÍÕÆÎճ̶ȡ£¿¼²éÁËѧÉú¶ÔÎïÖʽṹÓëÐÔÖʹØϵÒÔ¼°ÔËÓÃÔªËØÖÜÆÚÂɽâ¾ö¾ßÌ廯ѧÎÊÌâµÄÄÜÁ¦¡£±¾Ìâ»ù´¡ÐÔ½ÏÇ¿£¬ÖصãÍ»³ö£¬ÄѶȲ»´ó¡£
Á·Ï°²áϵÁдð°¸
Ïà¹ØÌâÄ¿