ÌâÄ¿ÄÚÈÝ
¡¾ÌâÄ¿¡¿ÔÚÊÒÎÂÏ£¬ÏÂÁйØÓÚµç½âÖʵÄ˵·¨ÖÐÕýÈ·µÄÊÇ
A. Öк͵ÈÌå»ý¡¢µÈŨ¶ÈµÄ°±Ë®ºÍÇâÑõ»¯ÄÆÈÜÒºÖÁpH£½7£¬Ç°ÕßÏûºÄµÄÑÎËá¶à
B. ÏòNH4ClÈÜÒºÖмÓÈëÉÙÁ¿µÈŨ¶ÈµÄÏ¡ÑÎËᣬÔòµÄÖµ¼õС
C. ÏòNaHSÈÜÒºÖмÓÈëÊÊÁ¿ KOH ºó£ºc(Na£«)£½c(H2S)£«c(HS£)£«c(S2£)
D. ½«a mol¡¤L£1µÄ´×ËáÓë0.01 mol¡¤L£1µÄÇâÑõ»¯ÄÆÈÜÒºµÈÌå»ý»ìºÏ(ºöÂÔÌå»ý¡¢Î¶ȱ仯)£¬ËùµÃÈÜÒºÖÐc(Na£«)£½c(CH3COO£)£¬Ôò´×ËáµÄµçÀë³£ÊýKa£½ (Óú¬aµÄ´úÊýʽ±íʾ)
¡¾´ð°¸¡¿C
¡¾½âÎö¡¿Öк͵ÈÌå»ý¡¢µÈŨ¶ÈµÄ°±Ë®ºÍÇâÑõ»¯ÄÆÈÜÒºÖÁpH£½7£¬°±Ë®ÏûºÄµÄÑÎËáÉÙ£¬¹ÊA´íÎó£»ÏòNH4ClÈÜÒºÖмÓÈëÉÙÁ¿µÈŨ¶ÈµÄÏ¡ÑÎËᣬÑÎËáÒÖÖÆ笠ùÀë×ÓË®½â£¬ËùÒÔµÄÖµÔö´ó£¬¹ÊB´íÎ󣻸ù¾ÝÎïÁÏÊغ㣬ÏòNaHSÈÜÒºÖмÓÈëÊÊÁ¿ KOH ºó£ºc(Na£«)£½c(H2S)£«c(HS£)£«c(S2£)£¬¹ÊCÕýÈ·£»½«a mol¡¤L£1µÄ´×ËáÓë0.01 mol¡¤L£1µÄÇâÑõ»¯ÄÆÈÜÒºµÈÌå»ý»ìºÏ(ºöÂÔÌå»ý¡¢Î¶ȱ仯)£¬ËùµÃÈÜÒºÖÐc(Na£«)£½c(CH3COO£)=0.005 mol¡¤L£1£¬Ôòc(CH3COOH)= mol¡¤L£1£¬Ôò´×ËáµÄµçÀë³£ÊýKa£½ £¬¹ÊD´íÎó¡£
¡¾ÌâÄ¿¡¿Ò»¶¨Î¶ÈÏ£¬Ïò10 mL 0.40 mol¡¤L£1 H2O2ÈÜÒºÖмÓÈëÊÊÁ¿FeCl3ÈÜÒº£¬²»Í¬Ê±¿Ì²âµÃÉú³ÉO2µÄÌå»ý(ÒÑÕÛËãΪ±ê×¼×´¿ö)ÈçϱíËùʾ£º
t / min | 0 | 2 | 4 | 6 |
V(O2) / mL | 0 | 9.9 | 17.2 | 22.4 |
×ÊÁÏÏÔʾ£¬·´Ó¦·ÖÁ½²½½øÐУº¢Ù 2Fe3+£«H2O2 == 2Fe2+£«O2¡ü£«2H+£¬¢Ú H2O2£«2Fe2+£«2H+ == 2H2O£«2Fe3+¡£·´Ó¦¹ý³ÌÖÐÄÜÁ¿±ä»¯ÈçÏÂͼËùʾ¡£ÏÂÁÐ˵·¨´íÎóµÄÊÇ
A. Fe3+µÄ×÷ÓÃÊÇÔö´ó¹ýÑõ»¯ÇâµÄ·Ö½âËÙÂÊ
B. ·´Ó¦¢ÙÊÇÎüÈÈ·´Ó¦¡¢·´Ó¦¢ÚÊÇ·ÅÈÈ·´Ó¦
C. ·´Ó¦2H2O2(aq) == 2H2O(l)£«O2(g)µÄ¦¤H£½E1£E2£¼0
D. 0¡«6 minµÄƽ¾ù·´Ó¦ËÙÂÊ£ºv(H2O2)£½3.33¡Á10£2 mol¡¤L£1¡¤min£1