ÌâÄ¿ÄÚÈÝ
¡¾ÌâÄ¿¡¿ÄÜÕýÈ·±íʾÏÂÁз´Ó¦µÄÀë×Ó·½³ÌʽÊÇ
A. ÓùýÁ¿Ê¯»ÒÈéÎüÊÕ¹¤ÒµÎ²ÆøÖеÄSO2: Ca2++2OH-+SO2£½CaSO3 ¡ý+ H2O
B. ÓÃËáÐÔKMnO4ÈÜÒºÓëH2O2·´Ó¦£¬Ö¤Ã÷H2O2¾ßÓл¹ÔÐÔ£º2MnO4¡ª+6H++5H2O2£½2Mn2++5O2 ¡ü+8H2O
C. ÓÃÍ×öµç¼«µç½âNaClÈÜÒº:2C1¡ª+2H2OH2¡ü+Cl2¡ü+2OH-
D. ½« Fe2O3¼ÓÈëµ½ HI ÈÜÒºÖУºFe2O3+ 6H+£½2Fe3+ +3H2O
¡¾´ð°¸¡¿B
¡¾½âÎö¡¿ÊÔÌâ·ÖÎö£ºA£®Ê¯»ÒÈéÖеÄÇâÑõ»¯¸ÆÖ»ÓÐÉÙÁ¿Èܽ⣬Óû¯Ñ§Ê½±íʾ£¬¹ÊA´íÎó£»B£®ËáÐÔKMnO4¾ßÓÐÑõ»¯ÐÔ£¬ÓëH2O2·´Ó¦·¢ÉúÑõ»¯»¹Ô·´Ó¦£¬·Å³öÑõÆø£¬¹ÊBÕýÈ·£»C£®ÍÊÇ»îÐԵ缫£¬×÷Ñô¼«Ê±£¬ÍҪʧȥµç×Ó¶øÈܽ⣬¹ÊC´íÎó£»D£®Éú³ÉµÄFe3+¾ßÓÐÑõ»¯ÐÔ£¬Äܹ»Ñõ»¯µâÀë×Ó£¬¹ÊD´íÎó£»¹ÊÑ¡B¡£
¡¾ÌâÄ¿¡¿ÒûÓÃË®Öк¬ÓÐÉé»áµ¼ÖÂÉéÖж¾£¬Ë®ÌåÖÐÈܽâµÄÉéÖ÷ÒªÒÔAs( ¢ó)ÑÇÉéËáÑκÍAs(V)ÉéËáÑÎÐÎʽ´æÔÚ¡£
(1)ÉéÓëÁ×ΪͬһÖ÷×åÔªËØ£¬Á×µÄÔ×ӽṹʾÒâͼΪ___________________¡£
(2)¸ù¾ÝÔªËØÖÜÆÚÂÉ£¬ÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ____________________(Ìî×Öĸ´úºÅ)¡£
a.×î¸ß¼ÛÑõ»¯Îï¶ÔӦˮ»¯ÎïµÄËáÐÔ£ºS>P>As b. Ô×Ӱ뾶£ºS>P>As c.·Ç½ðÊôÐÔ£ºS>P>As
(3)¹ØÓÚµØÏÂË®ÖÐÉéµÄÀ´Ô´ÓжàÖÖ¼ÙÉ裬ÆäÖÐÒ»ÖÖÈÏΪÊǸ»º¬ÉéµÄ»ÆÌú¿ó(FeS2)±»Ñõ»¯ÎªFe(OH)3£¬Í¬Ê±Éú³ÉSO42-£¬µ¼ÖÂÉéÍÑÀë¿óÌå½øÈëµØÏÂË®¡£FeS2±»O2Ñõ»¯µÄÀë×Ó·½³ÌʽΪ_________________________¡£
(4)È¥³ýË®ÌåÖеÄÉ飬¿ÉÏȽ«As(¢ó )ת»¯ÎªAs(V)£¬Ñ¡ÓÃNaClO¿ÉʵÏÖ¸Ãת»¯¡£
ÒÑÖª£ºÍ¶ÁÏÇ°Ë®ÑùpH=5.81£¬0.1 mol/L NaClOÈÜÒºpH=10.5£¬ÈÜÒºÖÐÆðÑõ»¯×÷ÓõÄÎïÖÊÊÇ´ÎÂÈËá¡£
Ñо¿NaClOͶ¼ÓÁ¿¶ÔAs(¢ó)Ñõ»¯ÂʵÄÓ°ÏìµÃµ½ÈçϽá¹û£º
²úÉú´Ë½á¹ûµÄÔÒòÊÇ_________________________¡£
(5)Ç¿ÒõÀë×Ó½»»»Öù¿ÉÒÔÎü¸½ÒÔÒõÀë×ÓÐÎʽ´æÔÚµÄAs(V)£¬´Ó¶ø´ïµ½È¥³ýAsµÄÄ¿µÄ¡£
ÒÑÖª£ºÒ»¶¨Ìõ¼þÏ£¬As(V)µÄ´æÔÚÐÎʽÈçϱíËùʾ£º
pH | <2 | 2¡«7 | 7¡«11 | 11¡«14 |
´æÔÚÐÎʽ | H3AsO4 | H2AsO4- | HAsO42- | HAsO42-¡¢AsO43- |
pH=6ʱ£¬NaClOÑõ»¯ÑÇÉéËá(H3AsO3)µÄÀë×Ó·½³ÌʽÊÇ_____________________¡£