ÌâÄ¿ÄÚÈÝ
£¨14·Ö£©A¡¢B¡¢C¶¼ÊÇÔªËØÖÜÆÚ±íÖеĶÌÖÜÆڷǽðÊôÔªËØ£¬ËüÃǵĺ˵çºÉÊýÒÀ´ÎÔö´ó¡£AÔ×ӵĺËÍâ³É¶Ôµç×ÓÊýÓëδ³É¶Ôµç×ÓÊýÏàµÈ£¬BÔ×ÓµÄ×îÍâ²ãp¹ìµÀµÄµç×ÓΪ°ëÂú½á¹¹£¬CÊǵؿÇÖк¬Á¿×î¶àµÄÔªËØ¡£D¡¢EÊǵÚËÄÖÜÆÚÔªËØ£¬DÔ×ÓºËÍâ×îÍâ²ãµç×ÓÊýÓÐ1¸öµç×Ó£¬ÆäÓà¸÷²ãµç×Ó¾ù³äÂú£»EÔ×ÓºËÍâδ³É¶Ôµç×ÓÊýÔÚͬÖÜÆÚÖÐ×î¶à¡£ÇëÓöÔÓ¦µÄÔªËØ·ûºÅ»ò»¯Ñ§Ê½Ìî¿Õ£º
¢ÅA¡¢B¡¢CµÄµÚÒ»µçÀëÄÜÓÉСµ½´óµÄ˳ÐòΪ ¡£
¢ÆDÓëEµÄÔ×Ó»¯ÈÈ·Ö±ðΪ340 kJ¡¤mol-1ºÍ125 kJ¡¤mol-1£¬ÔòËüÃǵÄÈ۵㣺D E(Ìî¡°£¾¡±¡¢¡°£¼¡±¡¢¡°=¡± )¡£
¢Ç·Ö×ÓA2B2ÖмüÓë¼üÖ®¼äµÄ¼Ð½ÇΪ180¡ã£¬²¢ÓжԳÆÐÔ£¬Ã¿¸öÔ×Ó×îÍâ²ãµç×ÓÊý¾ùÂú×ã°Ëµç×Ó£¬Æä½á¹¹Ê½Îª_____________£¬1mol¸Ã·Ö×ÓÖк¬ÓмüµÄÊýĿΪ ¡£
¢È»ù̬£ÅÔ×ÓµÄÍâΧµç×ÓÅŲ¼Ê½Îª ¡£EO2Cl2È۵㣺£96 .5¡æ£¬·Ðµã£º117¡æ£¬Ôò¹Ì̬EO2Cl2ÊôÓÚ ¾§Ìå¡£
¢ÉDµÄÇ⻯ÎïµÄ¾§Ìå½á¹¹ÈçÓÒͼËùʾ£¬Æ仯ѧʽÊÇ £¬Í¼Öа×Çò¹¹³ÉµÄ¾§Ìå½á¹¹ÊÇÓÉ¡¡¡¡¡¡¡¡¡¡¡¡¡¡£¨Ìî¡°ÃÜÖò㡱»ò¡°·ÇÖÃÃܲ㡱£©°´Ò»¶¨µÄ·½Ê½ÔÚÈýά¿Õ¼ä¶Ñ»ýÐγɵģ¬Ð´³ö´ËÇ⻯ÎïÔÚÂÈÆøÖÐȼÉյĻ¯Ñ§·½³Ìʽ ¡£
¢ÅC£¼O£¼N£¨1·Ö£© ¢Æ£¾ £¨1·Ö£©
¢ÇN¡ÔC£C¡ÔN¡¡£¨2·Ö£©4NA£¨»ò2.408¡Á1024£©£¨2·Ö£©
¢È3d54s1 £¨1·Ö£© ·Ö×Ó£¨1·Ö£©
¢ÉCuH£¨2·Ö£© ÃÜÖò㣨2·Ö£© 2CuH+3Cl2 £½ 2CuCl2+2HCl£¨2·Ö£©
¡¾½âÎö¡¿¸ù¾ÝÔªËصĽṹ¼°ÐÔÖÊ¿ÉÖª£¬A¡¢B¡¢C¡¢D¡¢EÎåÖÖÔªËØ·Ö±ðÊÇC¡¢N¡¢O¡¢Cu¡¢Cr¡£
£¨1£©·Ç½ðÊôÐÔԽǿ£¬µÚÒ»µçÀëÄÜÔ½´ó£¬µ«ÓÉÓÚNÔ×ÓµÄ2p¹ìµÀµç×ÓÊÇ°ë³äÂú״̬£¬Îȶ¨ÐÔÇ¿£¬ËùÒÔµÚÒ»µçÀëÄÜ´óÓÚÑõÔªËصģ¬¼´C£¼O£¼N¡£
£¨2£©Ô×Ó»¯ÈÈÔ½´ó£¬½ðÊô¾§ÌåµÄÈÛµãÔ½¸ß£¬ËùÒÔ͵ĴóÓÚCrµÄ¡£
£¨3£©½á¹¹ÊÇÖ±ÏßÐÍ£¬ÇÒ¶¼Âú×ã8µç×ÓÎȶ¨½á¹¹£¬ËùÒԽṹʽΪN¡ÔC£C¡ÔN£»ÓÉÓÚÈý¼üÓÉ1¸ö¼üºÍ2¸ö¦Ð¼ü¹¹³ÉµÄ£¬ËùÒÔº¬ÓÐ4mol¼ü¡£
£¨4£©¸ù¾Ý¹¹ÔìÔÀí¿ÉÖª£¬CrÔ×Ó»ù̬£ÅÔ×ÓµÄÍâΧµç×ÓÅŲ¼Ê½Îª3d54s1£»¡£EO2Cl2µÄÈ۷е㣬ËùÒÔÐγɵľ§ÌåÊÇ·Ö×Ó¾§Ìå¡£
£¨5£©¸ù¾Ý¾§°û¿ÉÖªÍÔ×ÓÊÇ8¡Á1/8£«6¡Á1/2£½4£¬¶øÇâÔ×ÓÊÇ4¸ö£¬ËùÒÔ»¯Ñ§Ê½ÎªCuH£»ÍÔ×ÓÊÇÃÜÖòãµÄ£»¸ù¾Ý»¯ºÏÎïµÄ×é³ÉÔªËØ¿ÉÖª£¬ºÍÂÈÆø·´Ó¦µÄÉú³ÉÎïÊÇÂÈ»¯ÍºÍÂÈ»¯Ç⣬·½³ÌʽΪ2CuH+3Cl2 £½ 2CuCl2+2HCl¡£