ÌâÄ¿ÄÚÈÝ
¡¾ÌâÄ¿¡¿ÀûÓÃÈçͼװÖòⶨÖкÍÈȵÄʵÑé²½ÖèÈçÏ£º
¢ÙÓÃÁ¿Í²Á¿È¡50mL0.25mol¡¤L-1ÁòËáµ¹ÈëСÉÕ±ÖУ¬²â³öÁòËáζȣ»
¢ÚÓÃÁíÒ»Á¿Í²Á¿È¡50mL0.55mol¡¤L-1NaOHÈÜÒº£¬²¢ÓÃÁíһζȼƲâ³öÆäζȣ»
¢Û½«NaOHÈÜÒºµ¹ÈëСÉÕ±ÖУ¬É跨ʹ֮»ìºÏ¾ùÔÈ£¬²â³ö»ìºÏÒºµÄ×î¸ßζȡ£
»Ø´ðÏÂÁÐÎÊÌ⣺
£¨1£©µ¹ÈëNaOHÈÜÒºµÄÕýÈ·²Ù×÷ÊÇ___¡£
A.Ñز£Á§°ô»ºÂýµ¹Èë B.·ÖÈý´ÎÉÙÁ¿µ¹Èë C.Ò»´ÎѸËÙµ¹Èë
£¨2£©Ê¹ÁòËáÓëNaOHÈÜÒº»ìºÏ¾ùÔȵÄÕýÈ·²Ù×÷ÊÇ__¡£
A.ÓÃζȼÆСÐĽÁ°è B.½Ò¿ªÓ²Ö½Æ¬Óò£Á§°ô½Á°è
C.ÇáÇáµØÕñµ´ÉÕ± D.ÓÃÌ×ÔÚζȼÆÉϵĻ·Ðβ£Á§½Á°è°ôÇáÇáµØÉÏÏÂÒƶ¯
£¨3£©ÊµÑéÊý¾ÝÈçÏÂ±í£º
¢ÙÇëÌîдϱíÖеĿհףº
ÎÂ¶È ÊµÑé´ÎÊý | ÆðʼζÈt1¡æ | ÖÕֹζÈt2/¡æ | ζȲîƽ¾ùÖµ(t2£t1)/¡æ | ||
H2SO4 | NaOH | ƽ¾ùÖµ | |||
1 | 26.2 | 26.0 | 26.1 | 29.5 | ___________ |
2 | 25.9 | 25.9 | 25.9 | 29.2 | |
3 | 26.4 | 26.2 | 26.3 | 29.8 |
¢Ú½üËƵØÈÏΪ0.55mol¡¤L-1NaOHÈÜÒººÍ0.25mol¡¤L-1ÁòËáÈÜÒºµÄÃܶȶ¼ÊÇ1g¡¤cm-3£¬ÖкͺóÉú³ÉÈÜÒºµÄ±ÈÈÈÈÝc=4.18J¡¤g-1¡¤¡æ-1¡£ÔòÖкÍÈȦ¤H=__(ȡСÊýµãºóһλ)¡£
¡¾´ð°¸¡¿C D 3.4 -56.8kJ/mol
¡¾½âÎö¡¿
(1)µ¹ÈëÇâÑõ»¯ÄÆÈÜҺʱ£¬±ØÐëÒ»´ÎѸËٵĵ¹È룬ĿµÄÊǼõÉÙÈÈÁ¿µÄɢʧ£»
(2)¸ù¾ÝÖкÍÈȲⶨÕýÈ·²Ù×÷·½·¨·ÖÎö£»
(3)¢Ù3´ÎζȲî·Ö±ðΪ£º3.4¡æ£¬3.3¡æ£¬3.5¡æ£¬¾ùÓÐЧ£¬¼ÆËãζȲîƽ¾ùÖµ£»
¢Ú¸ù¾Ý¹«Ê½½øÐмÆËã¡£
(1)µ¹ÈëÇâÑõ»¯ÄÆÈÜҺʱ£¬±ØÐëÒ»´ÎѸËٵĵ¹È룬ĿµÄÊǼõÉÙÈÈÁ¿µÄɢʧ£¬²»ÄÜ·Ö¼¸´Îµ¹ÈëÇâÑõ»¯ÄÆÈÜÒº£¬·ñÔò»áµ¼ÖÂÈÈÁ¿É¢Ê§£¬Ó°Ïì²â¶¨½á¹û£¬¹Ê´ð°¸Îª£ºC£»
(2)ʹÁòËáÓëNaOHÈÜÒº»ìºÏ¾ùÔȵÄÕýÈ·²Ù×÷·½·¨ÊÇ£ºÓÃÌ×ÔÚζȼÆÉϵĻ·Ðβ£Á§½Á°è°ôÇáÇáµØ½Á¶¯£»Î¶ȼÆÊDzâÁ¿Î¶ȵģ¬²»ÄÜʹÓÃζȼƽÁ°è£»Ò²²»ÄÜÇáÇáµØÕñµ´ÉÕ±£¬·ñÔò¿ÉÄܵ¼ÖÂÒºÌ彦³ö»òÈÈÁ¿É¢Ê§£¬Ó°Ïì²â¶¨½á¹û£»¸ü²»ÄÜ´ò¿ªÓ²Ö½Æ¬Óò£Á§°ô½Á°è£¬·ñÔò»áÓÐÈÈÁ¿É¢Ê§£¬¹Ê´ð°¸Îª£ºD£»
(3)¢Ù3´ÎζȲî·Ö±ðΪ£º3.4¡æ£¬3.3¡æ£¬3.5¡æ£¬¾ùÓÐЧ£¬Î¶Ȳîƽ¾ùÖµ=3.4¡æ£¬¹Ê´ð°¸Îª£º3.4£»
¢Ú50mL0.25mol/LÁòËáÓë50mL0.55mol/L NaOHÈÜÒº½øÐÐÖкͷ´Ó¦Éú³ÉË®µÄÎïÖʵÄÁ¿Îª0.05L¡Á0.25mol/L¡Á2=0.025mol£¬ÈÜÒºµÄÖÊÁ¿Îª£º100ml¡Á1g/ml=100g£¬Î¶ȱ仯µÄֵΪ¡÷T=3.4¡æ£¬ÔòÉú³É0.025molË®·Å³öµÄÈÈÁ¿ÎªQ=mc¡÷T=100g¡Á4.18J/(g¡æ)¡Á3.4¡æ=1421.2J£¬¼´1.4212kJ£¬ËùÒÔʵÑé²âµÃµÄÖкÍÈÈ¡÷H=-1.4212kJ/0.025mol=-56.8kJ/mol£¬¹Ê´ð°¸Îª£º-56.8kJ/mol¡£