ÌâÄ¿ÄÚÈÝ

¡¾ÌâÄ¿¡¿ÈçͼÊDz¿·Ö¶ÌÖÜÆÚÔªËصĵ¥Öʼ°Æ仯ºÏÎïµÄת»¯¹Øϵͼ£¨Óйط´Ó¦µÄÌõ¼þ¼°Éú³ÉµÄH2OÒÑÂÔÈ¥£©

¼ºÖª£º

£¨a£©A¡¢B¡¢C¡¢DÊǷǽðÊôµ¥ÖÊ£¬ÆäÖÐB¡¢C¡¢DÔÚ³£Î³£Ñ¹ÏÂÊÇÆøÌå¡£

£¨b£©·´Ó¦¢Ù¡¢¢ÚÊÇ»¯¹¤Éú²úÖеÄÖØÒª·´Ó¦¡£

£¨c£©»¯ºÏÎïEÊÇÐγÉËáÓêµÄÎÛȾÎïÖ®Ò»£¬»¯ºÏÎïKÊdz£Óõĵª·Ê¡£

£¨d£©»¯ºÏÎïL¾ßÓÐƯ°×ÐÔ£¬¿ÉÓÉCl2ÓëNaOHÈÜÒº·´Ó¦¶øÖƵá£

£¨e£©»¯ºÏÎïJÓÉÁ½ÖÖÔªËØ×é³É£¬ÆäÏà¶Ô·Ö×ÓÖÊÁ¿Îª32¡£

Çë°´ÒªÇóÌî¿Õ£º

£¨1£©·´Ó¦¢ÛµÄ»¯Ñ§·½³Ìʽ____________________¡£

£¨2£©CµÄ½á¹¹Ê½________£»HµÄ»¯Ñ§Ê½_________¡£

£¨3£©LµÄÈÜÒºÓ뻯ºÏÎïE·´Ó¦µÄÀë×Ó·½³Ìʽ£º£¨¼îÐÔÌõ¼þ£©_______________¡£

£¨4£©»¯ºÏÎïJµÄ»¯Ñ§Ê½_______________¡£

¡¾´ð°¸¡¿£¨1£©2NH3+H2SO4=(NH4)2SO4£»

£¨2£©(NH4)2SO3£»

£¨3£©ClO-+SO2+2OH-=Cl-+SO42-+H2O£»

£¨4£©N2H4¡£

¡¾½âÎö¡¿

ÊÔÌâ·ÖÎö£ºÓɶÌÖÜÆÚÔªËصĵ¥Öʼ°Æ仯ºÏÎïµÄת»¯¹Øϵͼ¿ÉÖª£¬»¯ºÏÎïEÊÇÐγÉËáÓêµÄÎÛȾÎïÖ®Ò»£¬ÔòEΪSO2£¬A¡¢B¡¢C¡¢D¶¼ÊǷǽðÊôµ¥ÖÊ£¬ÆäÖÐB¡¢C¡¢DÔÚ³£Î³£Ñ¹ÏÂÊÇÆøÌ壬ÔòAΪS£¬BΪO2£»»¯ºÏÎïKÊdz£Óõĵª·Ê£¬KΪÁòËá泥¬ËùÒÔFΪ°±Æø£¬ÔòC¡¢D·Ö±ðΪN2¡¢H2£»»¯ºÏÎïL¾ßÓÐƯ°×ÐÔ£¬¿ÉÓÉCl2ÓëNaOHÈÜÒº·´Ó¦¶øÖƵã¬ÔòLΪNaClO£¬°±ÆøÓëNaClO·´Ó¦Éú³ÉJ£¬JÓÉÁ½ÖÖÔªËØ×é³É£¬ËüÊÇ»ð¼ýÍƽø¼ÁµÄ³É·ÖÖ®Ò»£¬ÆäÏà¶Ô·Ö×ÓÖÊÁ¿Îª32£¬ÔòJΪN2H4£»JÓëÑõÆø·´Ó¦Éú³ÉC£¬CΪµªÆø¡£

£¨1£©¸Ã·´Ó¦Îª°±ÆøÓëÁòËá·´Ó¦Éú³ÉÁòËá泥¬»¯Ñ§·´Ó¦Îª2NH3+H2SO4¨T£¨NH4£©2SO4£¬¹Ê´ð°¸Îª£º2NH3+H2SO4¨T£¨NH4£©2SO4£»

£¨2£©CΪµªÆø£¬Æä½á¹¹Ê½ÎªN¡ÔN£¬HΪ¶þÑõ»¯ÁòÓë°±ÆøÔÚË®Öеķ´Ó¦£¬·´Ó¦Éú³É£¨NH4£©2SO3»òNH4HSO3£¬¹Ê´ð°¸Îª£ºN¡ÔN£»£¨NH4£©2SO3»òNH4HSO3£»

£¨3£©LΪNaClO£¬EΪSO2£¬ÔÚÈÜÒºÖз¢ÉúÑõ»¯»¹Ô­·´Ó¦Éú³ÉÂÈ»¯ÄÆ¡¢ÁòËáÄÆ£¬Àë×Ó·´Ó¦ÎªClO- + SO2 + 2OH- ¨T Cl- + SO42- + H2O»òClO- + SO2 + H2O ¨T Cl- + SO42- + 2H+£¬¹Ê´ð°¸Îª£ºClO-+SO2+2OH-¨TCl-+SO42-+H2O»òClO-+SO2+H2O¨TCl-+SO42-+2H+£»

£¨4£©ÓÉÉÏÊöÍƶϿÉÖª£¬JΪN2H4£¬¹Ê´ð°¸Îª£ºN2H4¡£

Á·Ï°²áϵÁдð°¸
Ïà¹ØÌâÄ¿

¡¾ÌâÄ¿¡¿Æû³µ×÷ΪһÖÖÏÖ´ú½»Í¨¹¤¾ßÕýÔÚ½øÈëǧ¼ÒÍò»§£¬Æû³µÎ²ÆøÖк¬ÓÐCO¡¢NO2µÈÓж¾ÆøÌ壬ÆäÎÛȾÎÊÌâÒ²³ÉΪµ±½ñÉç»á¼±Ðè½â¾öµÄÎÊÌâ¡£

I£®¶ÔÆû³µ¼ÓװβÆø¾»»¯×°Ö㬿ÉʹCO¡¢NOxÓж¾ÆøÌåÏ໥·´Ó¦×ª»¯ÎªÎÞ¶¾ÆøÌå¡£

2xCO£«2NOx ==2xCO2£«N2

µ±×ªÒƵç×ÓÎïÖʵÄÁ¿Îª0.8x molʱ£¬¸Ã·´Ó¦Éú³É LN2(±ê×¼×´¿öÏÂ)¡£

II£®Ò»Ñõ»¯Ì¼ÊÇÒ»ÖÖÓÃ;Ï൱¹ã·ºµÄ»¯¹¤»ù´¡Ô­ÁÏ¡£¿ÉÒÔ»¹Ô­½ðÊôÑõ»¯Î¿ÉÒÔÓÃÀ´ºÏ³ÉºÜ¶àÓлúÎïÈç¼×´¼(CH3OH)¡¢¶þ¼×ÃÑ(CH3OCH3)µÈ£¬»¹¿ÉÒÔ×÷ȼÁÏ¡£

£¨1£©ÔÚѹǿΪ0.1 MPaÌõ¼þÏ£¬½«a mol COÓë3a mol H2µÄ»ìºÏÆøÌåÔÚ´ß»¯¼Á×÷ÓÃÏÂÄÜ×Ô·¢·´Ó¦Éú³É¼×´¼£º CO(g)£«2H2(g) CH3OH(g) ¡÷H<0

¢Ù¸Ã·´Ó¦µÄƽºâ³£Êý±í´ïʽΪ ¡£

¢ÚÈôÈÝÆ÷ÈÝ»ý²»±ä£¬ÏÂÁдëÊ©¿ÉÔö¼Ó¼×´¼²úÂʵÄÊÇ ¡£

A£®Éý¸ßÎÂ¶È B£®½«CH3OH(g)´ÓÌåϵÖзÖÀë

C£®³äÈëHe£¬Ê¹Ìåϵ×ÜѹǿÔö´ó D£®ÔÙ³äÈë2 mol COºÍ6 mol H2

£¨2£©Ò»¶¨Ìõ¼þÏ£¬COÓëH2¿ÉºÏ³É¼×Í飬·´Ó¦·½³ÌʽΪCO(g)£«3H2(g)CH4 (g)£«H2O(g)

¢ÙÒ»¶¨Ìõ¼þÏ£¬¸Ã·´Ó¦Äܹ»×Ô·¢½øÐеÄÔ­ÒòÊÇ ¡£

¢ÚÒÑÖªH2(g)¡¢CO(g)¡¢ºÍCH4 (g)µÄȼÉÕ¡÷H·Ö±ðµÈÓÚaKJ/molºÍcKJ/mol,д³öCOÓëH2·´Ó¦Éú³ÉCH4ºÍCO2µÄÈÈ»¯Ñ§·½³Ìʽ£º ¡£

£¨3£©¼×´¼ÖÆÈ¡¼×È©¿ÉÓÃAg×÷´ß»¯¼Á£¬º¬ÓÐAgCl»áÓ°ÏìAg´ß»¯¼ÁµÄ»îÐÔ£¬Óð±Ë®¿ÉÒÔÈܽâ³ýÈ¥ÆäÖеÄAgCl,д³ö¸Ã·´Ó¦µÄÀë×Ó·½³Ìʽ£º ¡£

£¨4£©CuFe2O4¿ÉÓõ绯ѧ·½·¨µÃµ½£¬ÆäÔ­ÀíÈçͼËùʾ£¬ÔòÑô¼«µÄµç¼«·´Ó¦Ê½Îª ¡£

Î¥·¨ºÍ²»Á¼ÐÅÏ¢¾Ù±¨µç»°£º027-86699610 ¾Ù±¨ÓÊÏ䣺58377363@163.com

¾«Ó¢¼Ò½ÌÍø