题目内容
已知下列热化学方程式:
①CH3COOH(1)+202(g)=2CO2(g)+2H2O(1) △H1=" —870.3" kJ·mol—1
②C(s)+O2(g)=CO2(g) △H2=" —393.5" kJ·mol—1
③H2(g)+1/2O2(g)=H2O(1) △H3=" —285.8" kJ·mol—1
则反应④2C(s)+2H2(g)+O2(g)=CH3COOH(1)的焓变为( )
①CH3COOH(1)+202(g)=2CO2(g)+2H2O(1) △H1=" —870.3" kJ·mol—1
②C(s)+O2(g)=CO2(g) △H2=" —393.5" kJ·mol—1
③H2(g)+1/2O2(g)=H2O(1) △H3=" —285.8" kJ·mol—1
则反应④2C(s)+2H2(g)+O2(g)=CH3COOH(1)的焓变为( )
A.+488.3 kJ·mol—1 | B.—224.15 kJ·mol—1 |
C.—488.3 kJ·mol—1 | D.+244.15 kJ·mol—1 |
C
考查盖斯定律的应用。将②×3+③×2-①即得到2C(s)+2H2(g)+O2(g)=CH3COOH(1),所以反应热为2△H2+2△H3-△H1=—393.5 kJ/mol×2—285.8 kJ/mol×2+—870.3 Kj/mol=—488.3 kJ/mol,所以正确的答案是C。
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