题目内容
已知H2SO4(aq)与Ba(OH)2(aq)反应的ΔH=-1 584.2 kJ·mol-1;HCl(aq)与NaOH(aq)反应的ΔH=-55.6 kJ·mol-1。则生成BaSO4(s)的反应热等于 ( )
A.-1 528.6 kJ·mol-1 B.-1 473 kJ·mol-1
C.1 473 kJ·mol-1 D.1 528.6 kJ·mol-1
答案 B
解析 H+(aq)+OH-(aq)===H2O(l)
ΔH1=-55.6 kJ·mol-1 ①
Ba2+(aq)+SO
(aq)===BaSO4(s) ΔH2 ②
2H+(aq)+2OH-(aq)+Ba2+(aq)+SO
(aq)===BaSO4(s)+2H2O(l) ΔH3=
-1 584.2 kJ·mol-1 ③
根据盖斯定律知,ΔH3=2ΔH1+ΔH2,
ΔH2=-1 473 kJ·mol-1。