ÌâÄ¿ÄÚÈÝ

ÔÚ298 K¡¢1.01¡Á105 PaÏÂ,½«22 g CO2ͨÈë750 mL 1 mol¡¤L-1NaOHÈÜÒºÖгä·Ö·´Ó¦,²âµÃ·´Ó¦·Å³öx kJµÄÈÈÁ¿¡£ÒÑÖªÔÚ¸ÃÌõ¼þÏÂ,1 mol CO2ͨÈë1 L 2 mol¡¤L-1 NaOHÈÜÒºÖгä·Ö·´Ó¦·Å³öy kJµÄÈÈÁ¿¡£ÔòCO2ÓëNaOHÈÜÒº·´Ó¦Éú³ÉNaHCO3µÄÈÈ»¯Ñ§·½³ÌʽΪ(¡¡¡¡)

A.CO2(g)+NaOH(aq)NaHCO3(aq) ¦¤H=-(2y-x)kJ¡¤mol-1

B.CO2(g)+NaOH(aq)NaHCO3(aq) ¦¤H=-(2x-y)kJ¡¤mol-1

C.CO2(g)+NaOH(aq)NaHCO3(aq) ¦¤H=-(4x-y)kJ¡¤mol-1

D.CO2(g)+NaOH(aq)NaHCO3(aq) ¦¤H=-(8x-2y)kJ¡¤mol-1

 

C

¡¾½âÎö¡¿¸ù¾Ý·´Ó¦CO2+NaOHNaHCO3¡¢CO2+2NaOHNa2CO3+H2O,Ôò22 g CO2ͨÈë750 mL 1 mol¡¤L-1 NaOHÈÜÒºÖгä·Ö·´Ó¦²úÎïΪNaHCO3¡¢Na2CO3µÄ»ìºÏÎï¡£Éè²Î¼Ó·´Ó¦Éú³ÉNaHCO3µÄCO2ÎïÖʵÄÁ¿Îªa,²Î¼Ó·´Ó¦Éú³ÉNa2CO3µÄCO2ÎïÖʵÄÁ¿Îªb,Ôòa+b=0.5 mol,a+2b=0.75 mol,½âµÃ:a=b=0.25 mol¡£¸ù¾ÝÈÈÁ¿ÁйØϵ,ÉÏÊö·´Ó¦ÖвúÉú0.25 mol NaHCO3·Å³öµÄÈÈÁ¿Îª(x-0.25y)kJ,¹ÊÑ¡CÏî¡£

 

Á·Ï°²áϵÁдð°¸
Ïà¹ØÌâÄ¿

Î¥·¨ºÍ²»Á¼ÐÅÏ¢¾Ù±¨µç»°£º027-86699610 ¾Ù±¨ÓÊÏ䣺58377363@163.com

¾«Ó¢¼Ò½ÌÍø