ÌâÄ¿ÄÚÈÝ

±ûÏ©¿ÉÓÃÓںϳÉɱ³ý¸ùÁöÏß³æµÄÅ©Ò©£¨·Ö×ÓʽΪC3H5Br2Cl£©ºÍÓ¦Óù㷺µÄDAPÊ÷Ö¬£º

ÒÑÖªõ¥Óë´¼¿É·¢ÉúÈçÏÂõ¥½»»»·´Ó¦£º
RCOOR¡ä+R¡åOH
 ´ß»¯¼Á 
.
 
 RCOOR¡å+R¡äOH £¨R¡¢R¡ä¡¢R¡å´ú±íÌþ»ù£©
£¨1£©Å©Ò©·Ö×ÓC3H5Br2ClÖÐÿ¸ö̼ԭ×ÓÉϾùÁ¬Óбԭ×Ó£®
¢ÙAµÄ½á¹¹¼òʽÊÇ
CH2=CHCH2Cl
CH2=CHCH2Cl
£¬Aº¬ÓеĹÙÄÜÍÅÃû³ÆÊÇ
̼̼˫¼ü¡¢ÂÈÔ­×Ó
̼̼˫¼ü¡¢ÂÈÔ­×Ó
£»
¢ÚÓɱûÏ©Éú³ÉAµÄ·´Ó¦ÀàÐÍÊÇ
È¡´ú·´Ó¦
È¡´ú·´Ó¦
£®
£¨2£©AË®½â¿ÉµÃµ½D£¬¸ÃË®½â·´Ó¦µÄ»¯Ñ§·½³ÌʽÊÇ
£®
£¨3£©CµÄ½á¹¹¼òʽΪCH3COOCH2CH=CH2£¬¸Ã·Ö×ӵĺ˴Ź²ÕñÇâÆ×Öй²ÓÐ
4
4
¸ö·å£®
£¨4£©ÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ£¨Ñ¡ÌîÐòºÅ×Öĸ£©
acd
acd
£®
a£®CÄÜ·¢Éú¾ÛºÏ·´Ó¦¡¢»¹Ô­·´Ó¦ºÍÑõ»¯·´Ó¦
b£®Cº¬ÓÐ2¸ö¼×»ùµÄôÈËáÀàͬ·ÖÒì¹¹ÌåÓÐ4¸ö
c£®D´ß»¯¼ÓÇâµÄ²úÎïÓëB¾ßÓÐÏàͬµÄÏà¶Ô·Ö×ÓÖÊÁ¿
d£®E¾ßÓз¼ÏãÆø棬Ò×ÈÜÓÚÒÒ´¼
£¨5£©EµÄË®½â²úÎï¾­·ÖÀë×îÖյõ½¼×´¼ºÍB£¬¶þÕß¾ù¿ÉÑ­»·ÀûÓÃÓÚDAPÊ÷Ö¬µÄÖƱ¸£®ÆäÖн«¼×´¼ÓëH·ÖÀëµÄ²Ù×÷·½·¨ÊÇ
ÕôÁó
ÕôÁó
£®
·ÖÎö£º±ûÏ©ÔÚ¹âÕÕÌõ¼þÏ·¢ÉúÈ¡´ú·´Ó¦Éú³ÉA£¨CH2=CHCH2Cl£©£¬AÓëäå·¢Éú¼Ó³É·´Ó¦Éú³ÉC3H5Br2Cl£»CµÄ½á¹¹¼òʽΪCH3COOCH2CH=CH2£¬C¡úD·¢Éúõ¥½»»»·´Ó¦£¬ÔòDΪHOCH2CH=CH2£¬EΪCH3COOCH3£¬EË®½âÉú³É¼×´¼ºÍB£¬ÔòBΪÒÒËᣬÒԴ˽áºÏÓлúÎïµÄÐÔÖÊÀ´½â´ð£®
½â´ð£º½â£º±ûÏ©ÔÚ¹âÕÕÌõ¼þÏ·¢ÉúÈ¡´ú·´Ó¦Éú³ÉA£¨CH2=CHCH2Cl£©£¬AÓëäå·¢Éú¼Ó³É·´Ó¦Éú³ÉC3H5Br2Cl£»CµÄ½á¹¹¼òʽΪCH3COOCH2CH=CH2£¬C¡úD·¢Éúõ¥½»»»·´Ó¦£¬ÔòDΪHOCH2CH=CH2£¬EΪCH3COOCH3£¬EË®½âÉú³É¼×´¼ºÍB£¬ÔòBΪÒÒËᣬ
£¨1£©¢ÙÓÉÉÏÊö·ÖÎö¿ÉÖª£¬AΪCH2=CHCH2Cl£¬¹ÙÄÜÍÅΪ̼̼˫¼ü¡¢ÂÈÔ­×Ó£¬¹Ê´ð°¸Îª£ºCH2=CHCH2Cl£»Ì¼Ì¼Ë«¼ü¡¢ÂÈÔ­×Ó£»
¢ÚÓɱûÏ©Éú³ÉAµÄ·´Ó¦ÎªÈ¡´ú·´Ó¦£¬¹Ê´ð°¸Îª£ºÈ¡´ú·´Ó¦£»
£¨2£©AË®½â¿ÉµÃµ½D£¬¸ÃË®½â·´Ó¦µÄ»¯Ñ§·½³ÌʽΪ£¬
¹Ê´ð°¸Îª£º£»
£¨4£©CµÄ½á¹¹¼òʽΪCH3COOCH2CH=CH2£¬ÓÐ4ÖÖ²»Í¬µÄHÔ­×Ó£¬Ôò·Ö×ӵĺ˴Ź²ÕñÇâÆ×Öй²ÓÐ4¸ö·å£¬¹Ê´ð°¸Îª£º4£»
£¨5£©a£®CµÄ½á¹¹¼òʽΪCH3COOCH2CH=CH2£¬º¬ÓÐC=C£¬ÔòCÄÜ·¢Éú¾ÛºÏ·´Ó¦¡¢»¹Ô­·´Ó¦ºÍÑõ»¯·´Ó¦£¬¹ÊaÕýÈ·£»
b£®CµÄ½á¹¹¼òʽΪCH3COOCH2CH=CH2£¬º¬ÓÐ2¸ö¼×»ùµÄ¶¡Ï©»ùÓУ¬ÔòCº¬ÓÐ2¸ö¼×»ùµÄôÈËáÀàͬ·ÖÒì¹¹ÌåÓÐ2¸ö£¬¹Êb´íÎó
c£®DΪHOCH2CH=CH2£¬BΪCH3COOH£¬ÔòD´ß»¯¼ÓÇâµÄ²úÎïÓëB¾ßÓÐÏàͬµÄÏà¶Ô·Ö×ÓÖÊÁ¿£¬¹ÊcÕýÈ·
d£®EΪCH3COOCH3£¬ÊôÓÚõ¥ÀàÎïÖÊ£¬ÔòE¾ßÓз¼ÏãÆø棬Ò×ÈÜÓÚÒÒ´¼£¬¹ÊdÕýÈ·£»
¹Ê´ð°¸Îª£ºacd£»
£¨6£©HΪÒÒËáÄÆ£¬Óë¼×´¼µÄ·Ðµã²îÒì½Ï´ó£¬¿ÉÀûÓÃÕôÁóµÄ·½·¨À´·ÖÀ룬¹Ê´ð°¸Îª£ºÕôÁó£®
µãÆÀ£º±¾Ì⿼²éÓлúÎïµÄºÏ³É£¬Ã÷È·ÎïÖʵĽṹ¼°·´Ó¦Ìõ¼þÀ´ÍƶÏÎïÖÊÊǽâ´ðµÄ¹Ø¼ü£¬×¢ÒâºÏ³ÉͼÖйÙÄÜÍŵı仯À´½â´ð£¬ÌâÄ¿ÄѶÈÖеȣ®
Á·Ï°²áϵÁдð°¸
Ïà¹ØÌâÄ¿
±ûÏ©¿ÉÓÃÓںϳÉɱ³ý¸ùÁöÏß³æµÄÅ©Ò©£¨·Ö×ÓʽΪC3H5Br2Cl£©ºÍÓ¦Óù㷺µÄDAPÊ÷Ö¬£ºRCOOR¡ä+R¡åOH
     ¡÷     
.
´ß»¯¼Á
RCOOR¡å+R¡äOH£®ÒÑÖªõ¥Óë´¼¿É·¢ÉúÈçÏÂõ¥½»»»·´Ó¦£º£¨R¡¢R¡ä¡¢R¡å´ú±íÌþ»ù£©

£¨1£©Å©Ò©C1H3Br2Cl·Ö×ÓÖÐÿ¸ö̼ԭ×ÓÉϾùÁ¬Â±Ô­×Ó£®Aº¬ÓеĹÙÄÜÍÅÃû³ÆÊÇ
̼̼˫¼ü¡¢ÂÈÔ­×Ó
̼̼˫¼ü¡¢ÂÈÔ­×Ó
£»ÓɱûÏ©Éú³ÉAµÄ·´Ó¦ÀàÐÍÊÇ
È¡´ú·´Ó¦
È¡´ú·´Ó¦
£®
£¨2£©AË®½â¿ÉµÃµ½D£¬¸ÃË®½â·´Ó¦µÄ»¯Ñ§·½³ÌʽÊÇ
CH2=CHCH2Cl+H2O
NaOH
¡÷
CH2=CHCH2OH+HCl
CH2=CHCH2Cl+H2O
NaOH
¡÷
CH2=CHCH2OH+HCl
£®DÓжàÖÖͬ·ÖÒì¹¹Ì壬ÆäÑõ»¯²úÎ·Ö×ÓʽΪC3H6O2£©Ò²ÓжàÖÖͬ·ÖÒì¹¹Ì壬ÏÖÓÐÆäÖеÄËÄÖÖX¡¢Y¡¢Z¡¢W£¬ËüÃÇ·Ö×ÓÖоùº¬¼×»ù£¬°ÑËüÃÇ·Ö±ð½øÐÐÏÂÁÐʵÑéÒÔ¼ø±ðÖ®£¬ÆäʵÑé¼Ç¼ÈçÏ£º
NaOHÈÜÒº Òø°±ÈÜÒº ÐÂÖÆCu£¨OH£©2 ½ðÊôÄÆ
X Öкͷ´Ó¦ ÎÞÏÖÏó ÈÜ  ½â ²úÉúÇâÆø
Y ÎÞÏÖÏó ÓÐÒø¾µ ¼ÓÈȺóÓкìÉ«³Áµí ²úÉúÇâÆø
Z Ë®½â·´Ó¦ ÓÐÒø¾µ ¼ÓÈȺóÓкìÉ«³Áµí ÎÞÏÖÏó
W Ë®½â·´Ó¦ ÎÞÏÖÏó ÎÞÏÖÏó ÎÞÏÖÏó
ÔòX¡¢ZµÄ½á¹¹¼òʽ·Ö±ðΪ£ºX
CH3CH2COOH
CH3CH2COOH
£¬Z
CH3CH2OOCH
CH3CH2OOCH
£®
£¨3£©CÕôÆøÃܶÈÊÇÏàͬ״̬ϼ×ÍéÃܶȵÄ6.25±¶£¬CÖи÷ÔªËصÄÖÊÁ¿·ÖÊý·Ö±ðΪ£ºÌ¼60%£¬Çâ8%£¬Ñõ32%£®CµÄ½á¹¹¼òʽÊÇ
CH3COOCH2CH=CH2
CH3COOCH2CH=CH2
£®
£¨4£©ÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ£¨Ñ¡ÌîÐòºÅ×Öĸ£©
a c d
a c d
£®
a£®CÄÜ·¢Éú¾ÛºÏ·´Ó¦¡¢»¹Ô­·´Ó¦ºÍÑõ»¯·´Ó¦
b£®Cº¬ÓÐ2¸ö¼×»ùµÄôÈËáÀàͬ·ÖÒì¹¹ÌåÓÐ4¸ö
c£®D´ß»¯¼ÓÇâµÄ²úÎïÓëB¾ßÓÐÏàͬµÄÏà¶Ô·Ö×ÓÖÊÁ¿
d£®E¾ßÓз¼ÏãÆø棬Ò×ÈÜÓÚÒÒ´¼
£¨5£©FµÄ·Ö×ÓʽΪC10H10O4£®DAPµ¥ÌåΪ±½µÄ¶þԪȡ´úÎÇÒÁ½¸öÈ¡´ú»ù²»´¦ÓÚ¶Ô룬¸Ãµ¥Ìå±½»·ÉϵÄÒ»äåÈ¡´úÎïÖ»ÓÐÁ½ÖÖ£®DºÍF·´Ó¦Éú³ÉDAPµ¥ÌåµÄ»¯Ñ§·½³ÌʽÊÇ
£®
±ûÏ©¿ÉÓÃÓںϳÉɱ³ý¸ùÁöÏß³æµÄÅ©Ò©£¨·Ö×ÓʽΪC3H5Br2Cl£©ºÍÓ¦Óù㷺µÄDAPÊ÷Ö¬£º
¾«Ó¢¼Ò½ÌÍø
ÒÑÖªõ¥Óë´¼¿É·¢ÉúÈçÏÂõ¥½»»»·´Ó¦£º
RCOOR¡ä+R¡åOH
´ß»¯¼Á
¡÷
RCOOR¡å+R¡äOH  £¨R¡¢R¡ä¡¢R¡å´ú±íÌþ»ù£©
£¨1£©Å©Ò©·Ö×ÓC3H5Br2ClÖÐÿ¸ö̼ԭ×ÓÉϾùÁ¬Óбԭ×Ó£®
¢ÙAµÄ½á¹¹¼òʽÊÇ
 
£¬Aº¬ÓеĹÙÄÜÍÅÃû³ÆÊÇ
 
£»
¢ÚÓɱûÏ©Éú³ÉAµÄ·´Ó¦ÀàÐÍÊÇ
 
£®
£¨2£©AË®½â¿ÉµÃµ½D£¬¸ÃË®½â·´Ó¦µÄ»¯Ñ§·½³ÌʽÊÇ
 
£®
£¨3£©CÕôÆøÃܶÈÊÇÏàͬ״̬ϼ×ÍéÃܶȵÄ6.25±¶£¬CÖи÷ÔªËصÄÖÊÁ¿·ÖÊý·Ö±ðΪ£ºÌ¼60%£¬Çâ8%£¬Ñõ32%£®CµÄ½á¹¹¼òʽÊÇ
 
£®
£¨4£©ÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ£¨Ñ¡ÌîÐòºÅ×Öĸ£©
 
£®
a£®CÄÜ·¢Éú¾ÛºÏ·´Ó¦¡¢»¹Ô­·´Ó¦ºÍÑõ»¯·´Ó¦
b£®Cº¬ÓÐ2¸ö¼×»ùµÄôÈËáÀàͬ·ÖÒì¹¹ÌåÓÐ4¸ö
c£®D´ß»¯¼ÓÇâµÄ²úÎïÓëB¾ßÓÐÏàͬµÄÏà¶Ô·Ö×ÓÖÊÁ¿
d£®E¾ßÓз¼ÏãÆø棬Ò×ÈÜÓÚÒÒ´¼
£¨5£©EµÄË®½â²úÎï¾­·ÖÀë×îÖյõ½¼×´¼ºÍB£¬¶þÕß¾ù¿ÉÑ­»·ÀûÓÃÓÚDAPÊ÷Ö¬µÄÖƱ¸£®ÆäÖн«¼×´¼ÓëH·ÖÀëµÄ²Ù×÷·½·¨ÊÇ
 
£®
£¨6£©FµÄ·Ö×ÓʽΪC10H10O4£®DAPµ¥ÌåΪ±½µÄ¶þԪȡ´úÎÇÒÁ½¸öÈ¡´ú»ù²»´¦ÓÚ¶Ô룬¸Ãµ¥Ìå±½»·ÉϵÄÒ»äåÈ¡´úÎïÖ»ÓÐÁ½ÖÖ£®DºÍF·´Ó¦Éú³ÉDAPµ¥ÌåµÄ»¯Ñ§·½³ÌʽÊÇ
 
£®

±ûÏ©¿ÉÓÃÓںϳÉɱ³ý¸ùÁöÏß³æµÄÅ©Ò©(·Ö×ÓʽΪC3H5Br2Cl)ºÍÓ¦Óù㷺µÄDAPÊ÷Ö¬£º

ÒÑÖªõ¥Óë´¼¿É·¢ÉúÈçÏÂõ¥½»»»·´Ó¦£º

RCOOR¡ä£«R¡åOHRCOOR¡å£«R¡äOH(R¡¢R¡ä¡¢R¡å´ú±íÌþ»ù)

(1)Å©Ò©C3H5Br2Cl·Ö×ÓÖÐÿ¸ö̼ԭ×ÓÉϾùÁ¬Óбԭ×Ó¡£

¢ÙAµÄ½á¹¹¼òʽÊÇ_________________________________________________________£¬

Aº¬ÓеĹÙÄÜÍÅÃû³ÆÊÇ________________£»

¢ÚÓɱûÏ©Éú³ÉAµÄ·´Ó¦ÀàÐÍÊÇ______________¡£

(2)AË®½â¿ÉµÃµ½D£¬¸ÃË®½â·´Ó¦µÄ»¯Ñ§·½³ÌʽÊÇ_____________________________¡£

(3)CÕôÆøÃܶÈÊÇÏàͬ״̬ϼ×ÍéÃܶȵÄ6.25±¶£¬CÖи÷ÔªËصÄÖÊÁ¿·ÖÊý·Ö±ðΪ£ºÌ¼60%£¬

Çâ8%£¬Ñõ32%¡£CµÄ½á¹¹¼òʽÊÇ________________¡£

(4)ÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ(Ñ¡ÌîÐòºÅ×Öĸ)________¡£

a£®CÄÜ·¢Éú¾ÛºÏ·´Ó¦¡¢»¹Ô­·´Ó¦ºÍÑõ»¯·´Ó¦

b£®Cº¬ÓÐÁ½¸ö¼×»ùµÄôÈËáÀàͬ·ÖÒì¹¹ÌåÓÐ4¸ö

c£®D´ß»¯¼ÓÇâµÄ²úÎïÓëB¾ßÓÐÏàͬµÄÏà¶Ô·Ö×ÓÖÊÁ¿

d£®E¾ßÓз¼ÏãÆø棬Ò×ÈÜÓÚÒÒ´¼

(5)EµÄË®½â²úÎï¾­·ÖÀë×îÖյõ½¼×´¼ºÍB£¬¶þÕß¾ù¿ÉÑ­»·ÀûÓÃÓÚDAPÊ÷Ö¬µÄÖƱ¸¡£Æä

Öн«¼×´¼ÓëH·ÖÀëµÄ²Ù×÷·½·¨ÊÇ________¡£

(6)FµÄ·Ö×ÓʽΪC10H10O4¡£DAPµ¥ÌåΪ±½µÄ¶þԪȡ´úÎÇÒÁ½¸öÈ¡´ú»ù²»´¦ÓÚ¶Ô룬¸Ãµ¥Ìå±½»·ÉϵÄÒ»äåÈ¡´úÎïÖ»ÓÐÁ½ÖÖ¡£DºÍF·´Ó¦Éú³ÉDAPµ¥ÌåµÄ»¯Ñ§·½³ÌʽÊÇ________________________________________________________________________________________________________________________________________________¡£

±ûÏ©¿ÉÓÃÓںϳÉɱ³ý¸ùÁöÏß³æµÄÅ©Ò©£¨·Ö×ÓʽΪC3H5Br2Cl£©ºÍÓ¦Óù㷺µÄDAPÊ÷Ö¬£º

ÒÑÖªõ¥Óë´¼¿É·¢ÉúÈçÏÂõ¥½»»»·´Ó¦£º

£¨1£©Å©Ò©C3H5Br2Cl·Ö×ÓÖÐÿ¸ö̼ԭ×ÓÉϾùÁ¬Óбԭ×Ó¡£

AµÄ½á¹¹¼òʽÊÇ__________________£»AÖÐËùº¬¹ÙÄÜÍŵÄÃû³ÆÊÇ____________________¡£

±ûÏ©¡úAµÄ·´Ó¦ÀàÐÍÊÇ_______________£»A¡úC3H5Br2CIµÄ·´Ó¦ÀàÐÍÊÇ_____________¡£

£¨2£©AË®½â¿ÉµÃµ½D£®¸ÃË®½â·´Ó¦µÄ»¯Ñ§·½³ÌʽΪ£º

_______________________________________________________________________.

£¨3£©CÕôÆøÃܶÈÊÇÏàͬ״̬ϼ×ÍéÃܶȵÄ6.25±¶£¬SÖи÷ÔªËصÄÖÊÁ¿·ÖÊý·Ö±ðΪ£ºÌ¼60%£¬Çâ8%£¬Ñõ32%. SµÄ½á¹¹¼òʽΪ_________________________________£®

£¨4£©ÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ______________£¨Ìî×Öĸ´úºÅ£©¡£

a£®CÄÜ·¢Éú¾ÛºÏ·´Ó¦¡¢»¹Ô­·´Ó¦ºÍÑõ»¯·´Ó¦

b£®Cº¬ÓÐ2¸ö¼×»ùµÄôÈËáÀàͬ·ÖÒì¹¹ÌåÓÐ4¸ö

c£®D´ß»¯¼ÓÇâµÄ²úÎïÓëB¾ßÓÐÏàͬµÄÏà¶Ô·Ö×ÓÖÊÁ¿

d£®E¾ßÓз¼ÏãÆø棬Ò×ÈÜÓÚÒÒ´¼

£¨5£©EµÄË®½â²úÎï¾­·ÖÀë×îÖյõ½¼×´¼ºÍB£¬¶þÕß¾ù¿ÉÑ­»·ÀûÓÃÓÚDAPÊ÷Ö¬µÄÖƱ¸¡£ÆäÖн«¼×´¼ÓëH·ÖÀëµÄ²Ù×÷·½·¨ÊÇ__________________¡£

£¨6£©FµÄ·Ö×ÓʽΪC10H10O4. ¡£DAPµ¥ÌåΪ±½µÄ¶þԪȡ´úÎÇÒÁ½¸öÈ¡´ú»ù²»´¦ÓÚ¶Ô룬¸Ãµ¥Ìå±½»·ÉϵÄÒ»äåÈ¡´úÎïÖ»ÓÐÁ½ÖÖ¡£×ãÁ¿DºÍF·´Ó¦Éú³ÉDAPµ¥ÌåµÄ»¯Ñ§·½³ÌʽΪ£º

_______________________________________________________________________.

£¨7£©ÊµÑéÊÒÓÉ2-±û´¼ÖƱ¸±ûϩʱ£¬»¹²úÉúÉÙÁ¿SO2¡¢ CO2 ¼°Ë®ÕôÆø£¬Ä³Í¬Ñ§ÓÃÒÔÏÂÊÔ¼Á

¼ìÑéÕâËÄÖÖÆøÌ壬»ìºÏÆøÌåͨ¹ýÊÔ¼ÁµÄ˳ÐòÊÇ_______________£¨ÌîÐòºÅ£©¡£

¢Ù±¥ºÍNa2SO3ÈÜÒº¢ÚËáÐÔKMnO4ÈÜÒº  ¢Ûʯ»ÒË®  ¢ÜÎÞË®CuSO4¢ÝÆ·ºìÈÜÒº

 

Î¥·¨ºÍ²»Á¼ÐÅÏ¢¾Ù±¨µç»°£º027-86699610 ¾Ù±¨ÓÊÏ䣺58377363@163.com

¾«Ó¢¼Ò½ÌÍø