ÌâÄ¿ÄÚÈÝ
½«4molAÆøÌåºÍ2molBÆøÌåÔÚ2 LµÄÈÝÆ÷ÖлìºÏ£¬²¢ÔÚÒ»¶¨Ìõ¼þÏ·¢ÉúÈçÏ·´Ó¦£º2A(g)+B(g) 2C(g)¡£Èô¾2 sºó²âµÃCµÄŨ¶ÈΪ0.6mol¡¤L-1£¬ÏÖÓÐÏÂÁм¸ÖÖ˵·¨£º
¢ÙÓÃÎïÖÊA±íʾµÄ·´Ó¦µÄƽ¾ùËÙÂÊΪ0.3 mol¡¤L-1¡¤s-1 £»
¢ÚÓÃÎïÖÊB±íʾµÄ·´Ó¦µÄƽ¾ùËÙÂÊΪ0.6 mol¡¤L-1¡¤s-1£»
¢Û2sʱÎïÖÊAµÄת»¯ÂÊΪ30£¥ £»
¢Ü2sʱÎïÖÊBµÄŨ¶ÈΪ1.4mol¡¤L£1¡£
ÆäÖÐÕýÈ·µÄÊÇ£¨ £©
A£®¢Ù¢Û B£®¢Ù¢Ü C£®¢Ú¢Û D£®¢Û¢Ü
ͨ³£ÈËÃǰѲð¿ª1molij»¯Ñ§¼üËùÎüÊÕµÄÄÜÁ¿»òÐγÉ1molij»¯Ñ§¼üËùÊͷŵÄÄÜÁ¿¿´³É¸Ã»¯Ñ§¼üµÄ¼üÄÜ¡£ÒÑÖªÈÈ»¯Ñ§·½³Ìʽ£ºN2(g)+3H2(g)2NH3(g) ¦¤H£½-92.4kJ/mol
»¯Ñ§¼ü | H£H | N¡ÔN | H£N |
¼üÄÜ | 436 kJ/mol | x | 391kJ/mol |
Çë¸ù¾ÝÈÈ»¯Ñ§·½³ÌʽºÍ±íÖÐÊý¾Ý¼ÆËãN¡ÔN¼üµÄ¼üÄÜxԼΪ£¨ £©
A£®431kJ/mol B£®946kJ/mol C£®649kJ/mol D£®869kJ/mol
ÏÖÓÐʧȥ±êÇ©µÄËÄÆ¿ÎÞÉ«ÈÜÒº·Ö±ðΪNa2CO3ÈÜÒº¡¢Ï¡ÑÎËá¡¢Ba(OH)2ÈÜÒº¡¢NaHSO4ÈÜÒº£¬ÎªÈ·¶¨ËÄÆ¿ÈÜÒº·Ö±ðÊÇʲô£¬½«ÆäËæÒâ±êºÅΪA¡¢B¡¢C¡¢D£¬·Ö±ðÈ¡ÉÙÁ¿ÈÜÒºÁ½Á½»ìºÏ£¬²úÉúµÄÏÖÏóÈçϱíËùʾ¡£
ʵÑé˳Ðò | ʵÑéÄÚÈÝ | ʵÑéÏÖÏó | ʵÑé˳Ðò | ʵÑéÄÚÈÝ | ʵÑéÏÖÏó |
¢Ù | A + B | Éú³É°×É«³Áµí | ¢Ü | B + C | ÎÞÃ÷ÏԱ仯 |
¢Ú | A + C | ·Å³öÎÞÉ«ÆøÌå | ¢Ý | B + D | Éú³É°×É«³Áµí |
¢Û | A + D | ·Å³öÎÞÉ«ÆøÌå | ¢Þ | C + D | ÎÞÃ÷ÏԱ仯 |
ÒÑÖª£ºNaHSO4ÊôÓÚËáʽÑΣ¬ÔÚË®ÈÜÒºÖеĵçÀë·½³ÌʽΪ£ºNaHSO4=Na++H++SO42-¡£
¸ù¾ÝʵÑéÏÖÏ󣬻شðÏÂÁÐÎÊÌ⣺
£¨1£©AΪ £¬CΪ ¡£
£¨2£©Ð´³öÏÂÁз´Ó¦µÄÀë×Ó·½³ÌʽA + B: £¬A + D: £¬
£¨3£©µÈÎïÖʵÄÁ¿Å¨¶È¡¢µÈÌå»ýµÄB¡¢D»ìºÏ·´Ó¦µÄÀë×Ó·½³ÌʽΪ £¬·´Ó¦ºóµÃµ½µÄÈÜÒºÖк¬ÓеÄÒõÀë×ÓÓÐ ¡£
£¨4£©ÉÏÊöûÓÐÃ÷ÏԱ仯µÄʵÑé¢Ü¡¢¢Þ£¬ÆäÖÐ ·¢ÉúÁËÀë×Ó·´Ó¦£¬Àë×Ó·½³ÌʽΪ ¡£