题目内容
【题目】N2和H2合成NH3的能量变化如图所示,该反应的热化学方程式是( )
A. N2(g)+3H2(g) = 2NH3(g) ;△H = 2(b—a) kJ/mol
B. N2(g)+3H2(g) = 2NH3(l);△H = 2(a—b—c) kJ/mol
C. N2(g)+H2(g) = NH3(l) ;△H = (b+c—a) kJ/mol
D. N2(g)+H2(g) =NH3(g) ;△H = (a+b) kJ/mol
【答案】B
【解析】根据能量与反应过程的关系,合成氨是放热反应,△H<0,得出热化学反应方程式为:1/2N2(g)+3/2H2(g)=NH3(g) △H=(a-b)kJ·mol-1或N2(g)+3H2(g)=2NH3(g) △H=2(a-b)kJ·mol-1,1/2N2(g)+3/2H2(g)=NH3(l) △H=(a-b-c)kJ·mol-1或N2(g)+3H2(g)=2NH3(l) △H=2(a-b-c)kJ·mol-1,故选项B正确。
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