题目内容
【题目】肼(N2H4)是火箭发动机的燃料,反应时N2O4为氧化剂,生成氮气和水蒸气.已知:N2(g)+2O2(g)=N2O4(g)△H=+8.7kJ/mol;N2H4(g)+O2(g)=N2(g)+2H2O(g)△H=-534.0kJ/mol.下列表示肼跟N2O4反应的热化学方程式,正确的是( )
A. 2N2H4(g)+N2O4(g)=3N2(g)+4H2O(g)△H=-542.7kJ/mol
B. 2N2H4(g)+N2O4(g)=3N2(g)+4H2O(g)△H=-1059.3kJ/mol
C. 2N2H4(g)+N2O4(g)=3N2(g)+4H2O(g)△H=-1076.7kJ/mol
D. N2H4(g)+N2O4(g)=N2(g)+2H2O(g)△H=-1076.7kJ/mol
【答案】C
【解析】已知:①N2(g)+2O2(g)=N2O4(g)△H=+8.7kJ/mol
②N2H4(g)+O2(g)=N2(g)+2H2O(g)△H=-534.0kJ/mol
根据盖斯定律可知将方程式②×2-①即得到肼和N2H4 反应的热化学方程式:2N2H4(g)+N2O4(g)=3N2(g)+4H2O(g)△H=-1076.7kJ/mol,或N2H4(g)+N2O4(g)=N2(g)+2H2O(g)△H=-538.35 kJ/mol,答案选C。
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