ÌâÄ¿ÄÚÈÝ
¡¾ÌâÄ¿¡¿£¨·¢ÏÖÎÊÌ⣩Ñо¿ÐÔѧϰС×éÖеÄСÕÅͬѧÔÚѧϰÖз¢ÏÖ£ºÍ¨³£¼ìÑéCO2Óñ¥ºÍʯ»ÒË®£¬ÎüÊÕCO2ÓÃŨNaOHÈÜÒº¡£
£¨ÊµÑé̽¾¿£©ÔÚÌå»ýÏàͬʢÂúCO2µÄÁ½¼¯ÆøÆ¿ÖУ¬·Ö±ð¼ÓÈëµÈÌå»ýµÄ±¥ºÍʯ»ÒË®ºÍŨNaOHÈÜÒº¡£ÊµÑé×°ÖúÍÏÖÏóÈçͼËùʾ¡£ÇëÄãÒ»Æð²ÎÓë¡£
£¨ÏÖÏó½áÂÛ£©¼××°ÖÃÖвúÉú¸ÃʵÑéÏÖÏóµÄ»¯Ñ§·½³ÌʽΪ______________________¡£½âÊÍͨ³£ÓÃʯ»ÒË®¶ø²»ÓÃNaOHÈÜÒº¼ìÑéCO2µÄÔÒò________________________________________________£»ÒÒ×°ÖÃÖеÄʵÑéÏÖÏóÊÇ___________________________¡£ÎüÊÕCO2½Ï¶àµÄ×°ÖÃÊÇ__________________¡£
£¨¼ÆËãÑéÖ¤£©ÁíһλͬѧСÀîͨ¹ý¼ÆËã·¢ÏÖ£¬µÈÖÊÁ¿µÄCa(OH)2ºÍNaOHÎüÊÕCO2µÄÖÊÁ¿£¬Ca(OH)2´óÓÚNaOH¡£Òò´Ë£¬ËûÈÏΪͨ¹ýÎüÊÕCO2Ó¦¸ÃÓñ¥ºÍʯ»ÒË®¡£
£¨Ë¼¿¼ÆÀ¼Û£©ÇëÄã¶ÔСÀîͬѧµÄ½áÂÛ½øÐÐÆÀ¼Û£º________________________________________________________¡£
¡¾´ð°¸¡¿CO2£«Ca(OH)2£½CaCO3¡ý£«H2O£¨CO2ÊÊÁ¿£© CO2ºÍʯ»ÒË®×÷ÓÃÓÐÃ÷ÏÔµÄÏÖÏ󣬺ÍNaOH×÷ÓÃÎÞÃ÷ÏÔÏÖÏó ÆøÇòÌå»ýÔö´ó£¬ÈÜÒº²»±ä»ë×Ç ÒÒ ÒòΪCa(OH)2µÄÈܽâ¶È½ÏС£¬ËùÐγɵı¥ºÍʯ»ÒË®ÖÐÈÜÖʵÄÖÊÁ¿·ÖÊýºÜС
¡¾½âÎö¡¿
¼××°ÖÃÖУ¬³ÎÇåʯ»ÒË®ÖеÄCa(OH)2ÓëCO2·´Ó¦£¬Éú³ÉCaCO3°×É«³Áµí£¬ÓÉ´Ë¿Éд³ö·´Ó¦µÄ·½³Ìʽ¡£NaOHÈÜÒºÎüÊÕCO2£¬¿´²»µ½ÏÖÏó£»ÒÒ×°ÖÃÖУ¬ÓÉÓÚCO2±»NaOHÎüÊÕ£¬µ¼Ö¹ã¿ÚÆ¿ÄÚÆøÌåµÄѹǿ¼õС£¬ÓÚÊÇ¿ÕÆø½øÈëÆøÇòÄÚ£¬ÓÉ´Ë¿ÉÍÆ֪ʵÑéÏÖÏó¡£´ÓÁ½Æ¿ÄÚÈÜÒºÖÐËùº¬ÈÜÖʵÄÎïÖʵÄÁ¿¼°·´Ó¦·½³Ìʽ½øÐÐ×ۺϷÖÎö£¬ÒÔÈ·¶¨ËùѡװÖá£
СÀî´ÓÏàͬÁ¿µÄ¼îµÄÎüÊÕÄÜÁ¦¿¼ÂÇ£¬ºöÊÓÁËÈÜÒºµÄŨ¶È¡£
¼××°ÖÃÖУ¬³ÎÇåʯ»ÒË®ÖеÄÈÜÖÊΪCa(OH)2£¬ËüÓëCO2·´Ó¦µÄ»¯Ñ§·½³ÌʽΪCO2£«Ca(OH)2£½CaCO3¡ý£«H2O£¨CO2ÊÊÁ¿£©¡£Í¨³£ÓÃʯ»ÒË®¶ø²»ÓÃNaOHÈÜÒº¼ìÑéCO2£¬ÊÇÒòΪCO2ºÍʯ»ÒË®×÷ÓÃÓÐÃ÷ÏÔµÄÏÖÏ󣬺ÍNaOH×÷ÓÃÎÞÃ÷ÏÔÏÖÏó£»ÒÒ×°ÖÃÖУ¬ÓÉÓÚCO2±»NaOHÎüÊÕ£¬µ¼Ö¹ã¿ÚÆ¿ÄÚÆøÌåµÄѹǿ¼õС£¬ÓÚÊÇ¿ÕÆø½øÈëÆøÇòÄÚ£¬´Ó¶ø¿´µ½ÆøÇòÌå»ýÔö´ó£¬ÈÜÒº²»±ä»ë×Ç¡£ÒòΪ³ÎÇåʯ»ÒË®ÖÐCa(OH)2΢ÈÜÓÚË®£¬Å¨¶ÈºÜС£¬ÈÜÖʵÄÎïÖʵÄÁ¿ºÜС£¬ËùÒÔÎüÊÕCO2½Ï¶àµÄ×°ÖÃÊÇÒÒ¡£´ð°¸Îª£ºCO2£«Ca(OH)2£½CaCO3¡ý£«H2O£¨CO2ÊÊÁ¿£©£»CO2ºÍʯ»ÒË®×÷ÓÃÓÐÃ÷ÏÔµÄÏÖÏ󣬺ÍNaOH×÷ÓÃÎÞÃ÷ÏÔÏÖÏó£»ÆøÇòÌå»ýÔö´ó£¬ÈÜÒº²»±ä»ë×Ç£»ÒÒ£»
СÀî´ÓÏàͬÁ¿µÄ¼îµÄÎüÊÕÄÜÁ¦¿¼ÂÇ£¬ºöÊÓÁËÈÜÒºµÄŨ¶È¡£ÒòΪCa(OH)2µÄÈܽâ¶È½ÏС£¬ËùÐγɵı¥ºÍʯ»ÒË®ÖÐÈÜÖʵÄÖÊÁ¿·ÖÊýºÜС¡£´ð°¸Îª£ºÒòΪCa(OH)2µÄÈܽâ¶È½ÏС£¬ËùÐγɵı¥ºÍʯ»ÒË®ÖÐÈÜÖʵÄÖÊÁ¿·ÖÊýºÜС¡£
¡¾ÌâÄ¿¡¿A¡¢B¡¢C¡¢D¡¢EΪÔ×ÓÐòÊýÒÀ´ÎÔö´óµÄ¶ÌÖÜÆÚÖ÷×åÔªËØ£¬ÆäÔ×Ӱ뾶Óë×îÍâ²ãµç×ÓÊýµÄ¹ØϵÈçÏÂͼ1¡£EÔ×Ó×îÍâ²ãÉϵĵç×ÓÊýÊÇDÔ×Ó×îÍâ²ãµç×ÓÊýµÄ4±¶£¬DÀë×ÓºËÍâµç×ÓÅŲ¼ÓëC2£Ïàͬ¡£
ÊԻشð£º
£¨1£©ÔªËØEÔÚÔªËØÖÜÆÚ±íÖеÄλÖÃÊÇ___________________¡£
£¨2£©ÓëÔªËØDÀë×ÓËùº¬µç×ÓÊýºÍÖÊ×ÓÊý¾ùÏàͬµÄ΢Á£ÊÇ________________¡££¨Óû¯Ñ§Ê½×÷´ð£¬ÏÂͬ£©
£¨3£©BºÍE×î¸ß¼ÛÑõ»¯Îï¶ÔÓ¦µÄË®»¯ÎËáÐÔ½ÏÈõµÄ_________________¡£ÈôÓÃÉÏͼ2ÖÐ×°ÖÃÑéÖ¤ÕâÁ½ÖÖËáµÄËáÐÔÇ¿Èõ£¬ÔòÔÚ×°ÖÃÖмÓÈëµÄÊÔ¼Á·Ö±ðΪ£º¢ñ___________£¬¢ò__________£¬¹Û²ìµ½µÄʵÑéÏÖÏóÊÇ________________________¡£
£¨4£©ÓÉÒÔÉÏÎåÖÖÔªËØ×é³ÉµÄÎïÖÊ£¬Æä×é³ÉºÍ½á¹¹ÐÅÏ¢ÈçÏÂ±í£º
ÎïÖÊ | ×é³ÉºÍ½á¹¹ÐÅÏ¢ |
a | º¬ÓÐA¡¢C¡¢DµÄÑÎ |
b | C¡¢D×é³ÉµÄ»¯ºÏÎÇÒÔ×ÓÊýÖ®±ÈΪ1¡Ã1 |
c | »¯Ñ§×é³ÉΪAC2 |
¢Ùaº¬ÓеĻ¯Ñ§¼üÓÐ___________________________________£»
¢ÚbÓëc·´Ó¦µÄ»¯Ñ§·½³ÌʽΪ_________________________________¡£
¡¾ÌâÄ¿¡¿ÏÂÁÐʵÑéÓëͼÏ󲻶ÔÓ¦µÄÊÇ
Ñ¡Ïî | A | B | C | D |
ʵÑé | ÏòNH4C1ÈÜÒºÖмÓÈë¹ýÁ¿Na2O2¹ÌÌå | ÏòÏ¡ÏõËáÈÜÒºÖмÓÈë¹ýÁ¿µÄÌú·Û | Ã÷·¯ÈÜÒºÖÐÖðµÎ¼ÓBa£¨OH£©2ÈÜÒºÖÁ¹ýÁ¿ | Ïòº¬µÈÎïÖʵÄÁ¿µÄNaOHºÍNa2CO3µÄ»ìºÏÈÜÒºÖеμӹýÁ¿µÄÏ¡ÑÎËá |
ͼÏó |
A.AB.BC.CD.D
¡¾ÌâÄ¿¡¿ÒÑÖª£ºpAg£½-lgc(Ag+)£¬pX£½-lg c(Xn-)¡£298Kʱ£¬¼¸ÖÖÎïÖʵÄKspÈçÏÂ±í£º
»¯Ñ§Ê½ | AgCl | AgSCN | Ag2CrO4 |
ÑÕÉ« | °× | dz»Æ | ºì |
Ksp | 1.8¡Á1010 | 1.0¡Á1012 | 2.0¡Á1012 |
AgCl¡¢AgSCN¡¢Ag2CrO4µÄ±¥ºÍÈÜÒºÖУ¬ÑôÀë×ÓºÍÒõÀë×ÓµÄŨ¶È¹ØϵÈçͼËùʾ¡£ÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ
A.ͼÖÐx´ú±íAgClÇúÏߣ¬z´ú±íAgSCNÇúÏß
B.298Kʱ£¬ÔÚCl£ºÍCrO42£µÄÎïÖʵÄÁ¿Å¨¶È¾ùΪ0.1mol/LµÄÈÜÒºÖУ¬µÎÈëÉÙÁ¿0.1mol/LµÄAgNO3ÈÜÒº£¬Ê×ÏȲúÉúµÄÊǺìÉ«³Áµí
C.298KʱÈôÔö´ópµãµÄÒõÀë×ÓŨ¶È£¬ÔòyÉϵĵãÑØÇúÏßÏòÉÏÒƶ¯
D.298KʱAg2CrO4(s)£«2SCN£(aq) 2AgSCN(s)£«CrO42- (aq)µÄƽºâ³£ÊýK£½2.0¡Á1012