ÌâÄ¿ÄÚÈÝ
£¨10·Ö£©ÇëÍê³ÉÏÂÁи÷Ì⣺
£¨1£©Ç°ËÄÖÜÆÚÔªËØÖУ¬»ù̬Ô×ÓÖÐδ³É¶Ôµç×ÓÊýÓëÆäËùÔÚÖÜÆÚÊýÏàͬµÄÔªËØÓС¡¡¡ÖÖ¡£
£¨2£©µÚ¢ó£Á¡¢¢õ£Á×åÔªËØ×é³ÉµÄ»¯ºÏÎïGaN¡¢GaP¡¢GaAsµÈÊÇÈ˹¤ºÏ³ÉµÄÐÂÐÍ°ëµ¼Ìå²ÄÁÏ£¬Æ侧Ìå½á¹¹Óëµ¥¾§¹èÏàËÆ¡££Ç£áÔ×ӵĵç×ÓÅŲ¼Ê½Îª¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡£ÔÚGaN¾§ÌåÖУ¬Ã¿¸ö£Ç£áÔ×ÓÓë¡¡¡¡¡¡¸ö£ÎÔ×ÓÏàÁ¬£¬Óëͬһ¸ö£Ç£áÔ×ÓÏàÁ¬µÄ£ÎÔ×Ó¹¹³ÉµÄ¿Õ¼ä¹¹ÐÍΪ¡¡¡¡¡¡¡¡¡¡¡¡¡£ÔÚËÄ´ó¾§ÌåÀàÐÍÖУ¬GaNÊôÓÚ¡¡¡¡¡¡¡¡¡¡¡¡¾§Ìå¡£
£¨3£©ÔÚ¼«ÐÔ·Ö×ӣΣãì3ÖУ¬£ÎÔ×ӵĻ¯ºÏ¼ÛΪ-3£¬£Ã£ìÔ×ӵĻ¯ºÏ¼ÛΪ£«1£¬ÇëÍƲâ
£Î£Ã£ì3Ë®½âµÄÖ÷Òª²úÎïÊÇ¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡£¨Ìѧʽ£©¡£
£¨1£©Ç°ËÄÖÜÆÚÔªËØÖУ¬»ù̬Ô×ÓÖÐδ³É¶Ôµç×ÓÊýÓëÆäËùÔÚÖÜÆÚÊýÏàͬµÄÔªËØÓС¡¡¡ÖÖ¡£
£¨2£©µÚ¢ó£Á¡¢¢õ£Á×åÔªËØ×é³ÉµÄ»¯ºÏÎïGaN¡¢GaP¡¢GaAsµÈÊÇÈ˹¤ºÏ³ÉµÄÐÂÐÍ°ëµ¼Ìå²ÄÁÏ£¬Æ侧Ìå½á¹¹Óëµ¥¾§¹èÏàËÆ¡££Ç£áÔ×ӵĵç×ÓÅŲ¼Ê½Îª¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡£ÔÚGaN¾§ÌåÖУ¬Ã¿¸ö£Ç£áÔ×ÓÓë¡¡¡¡¡¡¸ö£ÎÔ×ÓÏàÁ¬£¬Óëͬһ¸ö£Ç£áÔ×ÓÏàÁ¬µÄ£ÎÔ×Ó¹¹³ÉµÄ¿Õ¼ä¹¹ÐÍΪ¡¡¡¡¡¡¡¡¡¡¡¡¡£ÔÚËÄ´ó¾§ÌåÀàÐÍÖУ¬GaNÊôÓÚ¡¡¡¡¡¡¡¡¡¡¡¡¾§Ìå¡£
£¨3£©ÔÚ¼«ÐÔ·Ö×ӣΣãì3ÖУ¬£ÎÔ×ӵĻ¯ºÏ¼ÛΪ-3£¬£Ã£ìÔ×ӵĻ¯ºÏ¼ÛΪ£«1£¬ÇëÍƲâ
£Î£Ã£ì3Ë®½âµÄÖ÷Òª²úÎïÊÇ¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡¡£¨Ìѧʽ£©¡£
£¨1£©5£¨2·Ö£©£¨2£©1s22s22p63s23p63d104s24p1(»ò[Ar]3d104s24p1)£¨2·Ö£©£»4£¨2·Ö£©
ÕýËÄÃæÌ壨1·Ö£© Ô×Ó£¨1·Ö£©
£¨3£©HClO £¨1·Ö£© NH3?H2O£¨1·Ö£©
ÕýËÄÃæÌ壨1·Ö£© Ô×Ó£¨1·Ö£©
£¨3£©HClO £¨1·Ö£© NH3?H2O£¨1·Ö£©
£¨1£©µÚÒ»ÖÜÆÚÖУ¬ÓÐÒ»¸öδ³É¶Ôµç×ÓµÄÊÇÇâÔ×Ó£¬Æäµç×ÓÅŲ¼Îª1s1;µÚ¶þÖÜÆÚÖУ¬Î´³É¶Ôµç×ÓÊÇÁ½¸öµÄÓÐÁ½ÖÖ¡ª¡ªC:1s22s22p2ºÍ O: 1s22s22p4£»µÚÈýÖÜÆÚÖУ¬Î´³É¶Ôµç×ÓÊÇÈý¸öµÄÊÇP: 1s22s22p63s23p3 ;µÚËÄÖÜÆÚÖÐδ³É¶Ôµç×ÓÊÇËĸöµÄÊÇFe: 1s22s22p63s23p64s23d6
(2) GaÔÚÔªËØÖÜÆÚ±íÖÐÊǵÚËÄÖÜÆÚ¡¢µÚ¢óA×壬Ô×ÓÐòÊýÊÇ31£¬¼´ÆäÔ×ÓºËÍâµç×ÓÊýÊÇ31£¬¸ù¾ÝºËÍâµç×ÓµÄÅŲ¼¹æÂÉ¿ÉÒÔд³ö¸ÃÔ×ӵĵç×ÓÅŲ¼Ê½Îª£º1s22s22p63s23p63d104s24p1»ò[Ar]3d104s24p1£»¸ù¾ÝÌâÄ¿Ëù¸øÐÅÏ¢£¬GaNµÄ¾§Ìå½á¹¹Óëµ¥¾§¹èÏàËÆ£¬¾§Ìå½á¹¹Îª¿Õ¼äÍø×´½á¹¹£¬Ã¿¸öGaÔ×ÓÓëËĸöNÏàÁ¬£¬ÕâËĸöNÔ×Ó¹¹³ÉµÄ¿Õ¼ä¹¹ÐÍÊÇÕýËÄÃæÌåÐÍ£¬ÊôÓÚÔ×Ó¾§Ìå¡£
£¨3£©Ë®½â¼´¸ÃÎïÖÊÖеĴøÕýµçµÄÔ×Ó»òÔ×ÓÍÅÓëË®µçÀë³öµÄOH-½áºÏ³ÉÈõµç½âÖÊ£¬´ø¸ºµçµÄÔ×Ó»òÔ×ÓÍÅÓëË®µçÀë³öµÄH+½áºÏ³ÉÈõµç½âÖʵĹý³Ì£¬Ë®½â·´Ó¦Ç°ºó¸÷ÔªËصĻ¯ºÏ¼Û²»±ä£¬ÀàËÆÓÚ¸´·Ö½â·´Ó¦£¬ÓÉÌâÒâÖªNCl3ÖÐNµÄ»¯ºÏ¼ÛΪ-3¼Û£¬ClµÄ»¯ºÏ¼ÛΪ+1¼Û£¬ÔòÔÚNCl3Ë®½âµÄ²úÎïÖÐNµÄ»¯ºÏ¼ÛÒ²ÊÇ-3¼Û£¬ClµÄ»¯ºÏ¼ÛÊÇ+1¼Û£¬·ÖÎö¿ÉÖªÆäË®½â²úÎïÊÇHClOºÍNH3¡¤H2O¡£
(2) GaÔÚÔªËØÖÜÆÚ±íÖÐÊǵÚËÄÖÜÆÚ¡¢µÚ¢óA×壬Ô×ÓÐòÊýÊÇ31£¬¼´ÆäÔ×ÓºËÍâµç×ÓÊýÊÇ31£¬¸ù¾ÝºËÍâµç×ÓµÄÅŲ¼¹æÂÉ¿ÉÒÔд³ö¸ÃÔ×ӵĵç×ÓÅŲ¼Ê½Îª£º1s22s22p63s23p63d104s24p1»ò[Ar]3d104s24p1£»¸ù¾ÝÌâÄ¿Ëù¸øÐÅÏ¢£¬GaNµÄ¾§Ìå½á¹¹Óëµ¥¾§¹èÏàËÆ£¬¾§Ìå½á¹¹Îª¿Õ¼äÍø×´½á¹¹£¬Ã¿¸öGaÔ×ÓÓëËĸöNÏàÁ¬£¬ÕâËĸöNÔ×Ó¹¹³ÉµÄ¿Õ¼ä¹¹ÐÍÊÇÕýËÄÃæÌåÐÍ£¬ÊôÓÚÔ×Ó¾§Ìå¡£
£¨3£©Ë®½â¼´¸ÃÎïÖÊÖеĴøÕýµçµÄÔ×Ó»òÔ×ÓÍÅÓëË®µçÀë³öµÄOH-½áºÏ³ÉÈõµç½âÖÊ£¬´ø¸ºµçµÄÔ×Ó»òÔ×ÓÍÅÓëË®µçÀë³öµÄH+½áºÏ³ÉÈõµç½âÖʵĹý³Ì£¬Ë®½â·´Ó¦Ç°ºó¸÷ÔªËصĻ¯ºÏ¼Û²»±ä£¬ÀàËÆÓÚ¸´·Ö½â·´Ó¦£¬ÓÉÌâÒâÖªNCl3ÖÐNµÄ»¯ºÏ¼ÛΪ-3¼Û£¬ClµÄ»¯ºÏ¼ÛΪ+1¼Û£¬ÔòÔÚNCl3Ë®½âµÄ²úÎïÖÐNµÄ»¯ºÏ¼ÛÒ²ÊÇ-3¼Û£¬ClµÄ»¯ºÏ¼ÛÊÇ+1¼Û£¬·ÖÎö¿ÉÖªÆäË®½â²úÎïÊÇHClOºÍNH3¡¤H2O¡£
Á·Ï°²áϵÁдð°¸
Ïà¹ØÌâÄ¿