ÌâÄ¿ÄÚÈÝ
¡¾ÌâÄ¿¡¿Ä³Ñо¿Ð¡×éÓû¼ìÑé²ÝËᾧÌåÑùÆ··Ö½â²úÎï²¢²â¶¨ÆäÖÊÁ¿·ÖÊý£¨¼ÙÉèÔÓÖʲ»²ÎÓë·´Ó¦£©£®²ÝËᾧÌ壨H2C2O42H2O£©µÄÀí»¯ÐÔÖʼû±í£®
£¨1£©¼ÓÈÈ·Ö½â²ÝËᾧÌå×îÊÊÒ˵Ä×°ÖÃÊÇ£¨Ìîͼ1×ÖĸÐòºÅ£©£®
£¨2£©Í¼2ÊÇÑéÖ¤ÈÈ·Ö½â²úÎïÖк¬CO£¬CO2µÄ×°Öà ¢ÙÒÇÆ÷aºÍbµÄÃû³Æ·Ö±ðÊǺÍ
¢ÚÖ¤Ã÷´æÔÚCO2µÄÏÖÏóÊÇ £¬ Ö¤Ã÷´æÔÚCOµÄÏÖÏóÊÇ £¬ DÖз´Ó¦µÄ»¯Ñ§·½³ÌʽÊÇ £®
¢Û×°ÖÃAµÄ×÷ÓÃÊÇ £¬ ÆøÄÒµÄ×÷ÓÃÊÇ £®
£¨3£©Îª²â¶¨ÑùÆ·ÖвÝËᾧÌåµÄÖÊÁ¿·ÖÊý£¬Éè¼ÆÁ½ÖÖÈçÏ·½°¸£®
ÈÛµã | ·Ðµã | ÈÈÎȶ¨ÐÔ | Óë¼î·´Ó¦ |
101¡ãC¡«102¡ãC | 150¡ãC¡«160¡ãCÉý»ª | 100.1¡ãCʧȥ½á¾§Ë®£¬175¡ãC·Ö½â³ÉCO2 £¬ CO£¬H2O | ÓëCa£¨OH£©2·´Ó¦²úÉú°×É«³Áµí£¨CaC2O4£© |
¢Ù³ÆÒ»¶¨Á¿ÑùÆ·ÓÃÉÏͼװÖýøÐÐʵÑ飬²âµÃ×°ÖÃD·´Ó¦Ç°ºóµÄÖÊÁ¿²î£¬Óɴ˼ÆËã³öµÄʵÑé½á¹û±Èʵ¼ÊֵƫµÍ£¬ÅųýÒÇÆ÷ºÍ²Ù×÷µÄÒòËØ£¬ÆäÔÒò¿ÉÄÜÓУºCOδÍêÈ«·´Ó¦¡¢ £®
¢Ú³ÆÈ¡8.75g²ÝËᾧÌåÑùÆ·ÅäÖÆ50.00gÈÜÒº£¬È¡10.00gÈÜÒº¼ÓÊÊÁ¿µÄÏ¡ÁòËᣬȻºóµÎ¼Ó25.00g3.16%KMnO4ÈÜÒº£¬Ç¡ºÃ·´Ó¦ÍêÈ«£®
£¨ÒÑÖª£º2KMnO4+5H2C2O4+3H2SO4=K2SO4+2MnSO4+10CO2¡ü+8H2O£©ÔòKMnO4ÈÜÒºÏÔÉ«£¬25.00g3.16%KMnO4ÈÜÒºÖÐKMnO4µÄÖÊÁ¿g£®Çë¼ÆËãÑùÆ·ÖеÄÖÊÁ¿·ÖÊý£®[д³ö¼ÆËã¹ý³Ì£¬M2£¨H2C2O4£©=90£¬M2£¨H2C2O42H2O£©=126£¬M2£¨KMnO4£©=158]£®
¡¾´ð°¸¡¿
£¨1£©c
£¨2£©ÉÕ±£»¾Æ¾«µÆ£»BÖгÎÇåµÄʯ»ÒË®±ä»ë×Ç£»DÖкÚÉ«¹ÌÌå±ä³ÉºìÉ«£»CO+CuO Cu+CO2£»³ýÈ¥²ÝËáÕôÆø£¬·ÀÖ¹¶Ô¶þÑõ»¯Ì¼µÄ¼ìÑé²úÉú¸ÉÈÅ£»ÊÕ¼¯Ò»Ñõ»¯Ì¼£¬·ÀÖ¹ÎÛȾ¿ÕÆø
£¨3£©Éú³ÉµÄÍÓÖ±»Ñõ»¯£»×Ϻ죻0.79
¡¾½âÎö¡¿½â£º£¨1£©²ÝËáµÄÈÛµã½ÏµÍ£¬ÊÜÈÈÈÝÒ×ÈÛ»¯£¬ÓÃc×°ÖüÓÈȲÝËáʱ²»ÈÝÒ×ÏÂÁ÷£¬ÊÊÒËÓÃÀ´¼ÓÈȲÝËᣮ ¹ÊÌc£®£¨2£©¢ÙÒÇÆ÷aºÍbµÄÃû³Æ·Ö±ðÊÇÉÕ±¡¢¾Æ¾«µÆ£®
¹ÊÌÉÕ±£»¾Æ¾«µÆ£®¢ÚÖ¤Ã÷´æÔÚCO2µÄÏÖÏóÊÇ£ºBÖгÎÇåµÄʯ»ÒË®±ä»ë×Ç£»Ö¤Ã÷´æÔÚCOµÄÏÖÏóÊÇ£ºDÖкÚÉ«¹ÌÌå±ä³ÉºìÉ«£®
¹ÊÌBÖгÎÇåµÄʯ»ÒË®±ä»ë×Ç£»DÖкÚÉ«¹ÌÌå±ä³ÉºìÉ«£®
DÖÐÑõ»¯ÍºÍÒ»Ñõ»¯Ì¼ÔÚ¼ÓÈÈʱ·´Ó¦ÄÜÉú³ÉͺͶþÑõ»¯Ì¼£¬·´Ó¦µÄ»¯Ñ§·½³ÌʽÊÇ£ºCO+CuO Cu+CO2 £®
¹ÊÌCO+CuO Cu+CO2 £® ¢Û×°ÖÃAµÄ×÷ÓÃÊÇ£º³ýÈ¥²ÝËáÕôÆû£¬·ÀÖ¹¶Ô¶þÑõ»¯Ì¼µÄ¼ìÑé²úÉú¸ÉÈÅ£»ÆøÄÒµÄ×÷ÓÃÊÇ£ºÊÕ¼¯Ò»Ñõ»¯Ì¼£¬·ÀÖ¹ÎÛȾ¿ÕÆø£®
¹ÊÌ³ýÈ¥²ÝËáÕôÆû£¬·ÀÖ¹¶Ô¶þÑõ»¯Ì¼µÄ¼ìÑé²úÉú¸ÉÈÅ£»ÊÕ¼¯Ò»Ñõ»¯Ì¼£¬·ÀÖ¹ÎÛȾ¿ÕÆø£®£¨3£©¢ÙÒ»Ñõ»¯Ì¼²¿·Ö·´Ó¦£¬Éú³ÉµÄÍÖØб»Ñõ»¯µÈÒòËض¼Äܹ»µ¼Ö¼ÆËã³öµÄʵÑé½á¹û±Èʵ¼ÊֵƫµÍ£®
¹ÊÌÉú³ÉµÄÍÓÖ±»Ñõ»¯£®¢Ú¸ßÃÌËá¼ØÈÜÒºÊÇÑÕÉ«×ϺìÉ«µÄ£®
¹ÊÌ×Ϻ죮
25.00g3.16%KMnO4ÈÜÒºÖÐKMnO4µÄÖÊÁ¿Îª£º25.00g¡Á3.16%=0.79g£®
¹ÊÌ0.79£®
Éè10.00gÈÜÒºÖк¬²ÝËᾧÌåµÄÖÊÁ¿ÎªX£¬
ÓÉ2KMnO4+5H2C2O4+3H2SO4=K2SO4+2MnSO4+10CO2¡ü+8H2O¿ÉÖª£¬
5H2C2O42H2O¡ú5H2C2O4¡ú | 2KMnO4 £¬ |
630 | 316 |
x | 0.79g |
=
X=1.575g£¬
50.00gÈÜÒºÖк¬²ÝËᾧÌåµÄÖÊÁ¿Îª£º1.575g¡Á5=7.875g£¬
²ÝËᾧÌåµÄÖÊÁ¿·ÖÊýΪ£º ¡Á100%=90%£¬
´ð£ºÑùÆ·ÖвÝËᾧÌåµÄÖÊÁ¿·ÖÊýΪ90%£®
¡¾ÌâÄ¿¡¿ÏÂÁÐËĸöͼÏóÖУ¬ÄÜÕýÈ·±íʾ¶Ô·´Ó¦±ä»¯¹ØϵµÄÊÇ£¨ £©
A£®ÏòÒ»¶¨Á¿Ï¡ÑÎËáÖмÓˮϡÊÍ | B£®Ò»¶¨Î¶ÈÏ£¬Ïò²»±¥ºÍÏõËá¼ØÈÜÒºÖмÓÈëÏõËá¼Ø | C£®¼ÓÈÈÒ»¶¨Á¿µÄ¸ßÃÌËá¼Ø¹ÌÌå | D£®ÏòÑÎËáºÍÂÈ»¯Ã¾µÄ»ìºÏÈÜÒºÖмÓÇâÑõ»¯¼ØÈÜÒº |
A.A
B.B
C.C
D.D