ÌâÄ¿ÄÚÈÝ
17£®£¨1£©½ñÄêÀ´ÎÒ¹ú¶à¸öÊ¡ÊгöÏÖÑÏÖØµÄÎíö²ÌìÆø£®µ¼ÖÂÎíö²ÐγɵÄÖ÷ÒªÎÛȾÎïÊÇd£¨Ìî×Öĸ£©£®
a£®SO2 ¡¡b£®NO2¡¡ c£®CO2¡¡d£®PM2.5
£¨2£©ÌìȻˮÖÐÔÓÖʽ϶࣬³£Ðè¼ÓÈëÃ÷·¯£¬ClO2µÈÎïÖÊ´¦Àíºó²ÅÄÜÒûÓã®Ã÷·¯Äܾ»Ë®µÄÔÀíÊÇÂÁÀë×ÓÓëË®·´Ó¦Éú³ÉµÄÇâÑõ»¯ÂÁ½ºÌå¾ßÓкÜÇ¿µÄÎü¸½ÐÔ£¬¿ÉÎü¸½Ë®ÖÐÐü¸¡Îд³ö¼ìÑéÃ÷·¯ÖÐAl3+µÄʵÑé·½·¨È¡ÉÙÁ¿´ý²âÒºÓÚÒ»Ö§ÊÔ¹ÜÖУ¬ÖðµÎµÎ¼ÓÇâÑõ»¯ÄÆÈÜÒº£¬ÈôÏȳöÏÖ°×É«³Áµí£¬ºóÓÖÈܽ⣬ÔòÖ¤Ã÷´ý²âÒºÖк¬Al3+£®
£¨3£©A¡¢B¡¢C Èý¸ö³ÇÊÐÈ«ÄêÓêË®µÄÔÂÆ½¾ùpH ±ä»¯Èçͼ1 Ëùʾ£®
¢ÙÊÜËáÓêΣº¦×îÑÏÖØµÄÊÇC³ÇÊУ®
¢ÚÆû³µÎ²ÆøÖк¬ÓÐNO2¡¢NO¡¢CO µÈÓк¦ÆøÌ壬д³öÓÉNO2ÐγÉÏõËáÐÍËáÓêµÄ»¯Ñ§·½³Ìʽ3NO2+H2O=2HNO3+NO£®
¢ÛÓÃÄÉÃ×¶þÑõ»¯îѹⴥý¼¼Êõ£¬½«Æû³µÎ²ÆøÖеÄNOx ºÍCO ת»¯ÎªÎÞº¦ÆøÌ壬д³ö¸Ã·´Ó¦µÄ»¯Ñ§·½³Ìʽ2NOx+2xCO$\frac{\underline{\;¶þÑõ»¯îÑ\;}}{¹â}$N2+2xCO2£®
¢Ü²âÁ¿Æû³µÎ²ÆøµÄŨ¶È³£ÓÃµç»¯Ñ§ÆøÃô´«¸ÐÆ÷£¬ÆäÖÐCO ´«¸ÐÆ÷¿ÉÓÃÈçͼ2 ¼òµ¥±íʾ£¬ÔòÑô¼«·¢ÉúµÄµç¼«·´Ó¦CO+H2O-2e-¨TCO2+2H+£®
·ÖÎö £¨1£©PM2.5¡±ÊÇÖ¸´óÆø²ãÖÐÖ±¾¶¡Ý2.5¦ÌmµÄ¿ÅÁ£ÎÄܱ»·ÎÎüÊÕ²¢½øÈëѪҺ£¬¶ÔÈËÌåΣº¦ºÜ´ó£¬ÊÇÐγÉÎíö²µÄÖ÷ÒªÎÛȾÎ
£¨2£©Ã÷·¯ÖÐÂÁÀë×ÓË®½âÉú³É½ºÌå¾ßÓÐÎü¸½ÐÔ£¬Ôò¿É¶ÔË®Öʾ»»¯£»
£¨3£©¢ÙÓêË®µÄpHԽС£¬ËáÐÔԽǿ£¬ÊÜËáÓêΣº¦Ô½ÑÏÖØ£»
¢Ú¶þÑõ»¯µªÓëË®·´Ó¦Éú³ÉÏõËáºÍNO£»
¢ÛÆû³µÉú²úµÄÓк¦ÆøÌåΪNO¡¢CO£¬Í¨¹ý´ß»¯¼Áת»¯ÎªÎÞº¦ÆøÌ壬·´Ó¦Ó¦Éú³ÉµªÆøÓë¶þÑõ»¯Ì¼£¬¾Ý´Ëд³ö·´Ó¦µÄ»¯Ñ§·½³Ìʽ£»
¢ÜÒÀ¾Ýµç½âÔÀí·ÖÎö£¬Ñô¼«ÊÇʧµç×Ó·¢ÉúÑõ»¯·´Ó¦µÄÎïÖÊ£¬½áºÏͼʾ¿ÉÖªÊÇÒ»Ñõ»¯Ì¼Ê§µç×ÓÉú³É¶þÑõ»¯Ì¼£®
½â´ð ½â£º£¨1£©µ¼ÖÂÎíö²ÐγɵÄÖ÷ÒªÎÛȾÎïÊÇpM2.5£¬¹Ê´ð°¸Îª£ºd£»
£¨2£©Ã÷·¯ÖÐÂÁÀë×ÓË®½âÉú³É½ºÌå¾ßÓÐÎü¸½ÐÔ£¬Ôò¿É¶ÔË®Öʾ»»¯£¬Ë®½âÀë×Ó·´Ó¦ÎªA13++3H2O?Al£¨OH£©3£¨½ºÌ壩+3H+£¬È¡ÉÙÁ¿´ý²âÒºÓÚÒ»Ö§ÊÔ¹ÜÖУ¬ÖðµÎµÎ¼ÓÇâÑõ»¯ÄÆÈÜÒº£¬ÈôÏȳöÏÖ°×É«³Áµí£¬ºóÓÖÈܽ⣬ÔòÖ¤Ã÷´ý²âÒºÖк¬Al3+£¬
¹Ê´ð°¸Îª£ºÂÁÀë×ÓÓëË®·´Ó¦Éú³ÉµÄÇâÑõ»¯ÂÁ½ºÌå¾ßÓкÜÇ¿µÄÎü¸½ÐÔ£¬¿ÉÎü¸½Ë®ÖÐÐü¸¡ÎȡÉÙÁ¿´ý²âÒºÓÚÒ»Ö§ÊÔ¹ÜÖУ¬ÖðµÎµÎ¼ÓÇâÑõ»¯ÄÆÈÜÒº£¬ÈôÏȳöÏÖ°×É«³Áµí£¬ºóÓÖÈܽ⣬ÔòÖ¤Ã÷´ý²âÒºÖк¬Al3+£»
£¨3£©¢ÙÓÉͼ¿ÉÖªC³ÇÊÐÓêË®pH×îС£¬¹ÊÊÜËáÓêΣº¦×îÑÏÖØµÄÊÇC³ÇÊУ¬¹Ê´ð°¸Îª£ºC£»
¢Ú¶þÑõ»¯µªÓëË®·´Ó¦Éú³ÉÏõËáÓëNO£¬·´Ó¦Àë×Ó·½³ÌʽΪ£º3NO2+H2O=2HNO3+NO£¬¹Ê´ð°¸Îª£º3NO2+H2O=2HNO3+NO£»
¢ÛÓÃÄÉÃ×¶þÑõ»¯îѹⴥý¼¼Êõ£¬½«Æû³µÎ²ÆøÖеÄNOx ºÍCO ת»¯ÎªÎÞº¦ÆøÌ壬д³ö¸Ã·´Ó¦µÄ»¯Ñ§·½³Ìʽ£¬2NOx+2xCO$\frac{\underline{\;¶þÑõ»¯îÑ\;}}{¹â}$N2+2xCO2£¬
¹Ê´ð°¸Îª£º2NOx+2xCO$\frac{\underline{\;¶þÑõ»¯îÑ\;}}{¹â}$N2+2xCO2£»
¢ÜÑô¼«ÊÇʧµç×Ó·¢ÉúÑõ»¯·´Ó¦µÄÎïÖÊ£¬½áºÏͼʾ¿ÉÖªÊÇÒ»Ñõ»¯Ì¼Ê§µç×ÓÉú³É¶þÑõ»¯Ì¼Í¬Ê±Éú³ÉÇâÀë×Ó£¬µç¼«·´Ó¦Îª£ºCO+H2O-2e-=CO2+2H+£¬
¹Ê´ð°¸Îª£ºCO+H2O-2e-¨TCO2+2H+£®
µãÆÀ ±¾Ì⿼²é»·¾³ÎÛȾÓë·ÀÖΡ¢¶þÑõ»¯ÁòÐÔÖÊ¡¢µç½âÔÀí·ÖÎöµÈ֪ʶ£¬ÌâÄ¿ÄѶȲ»´ó£¬Ã÷È·µªµÄÑõ»¯Îï¡¢ÁòµÄÑõ»¯ÎïµÄÐÔÖʼ°Ó¦Óã¬Ã÷È·ËáÓêµÄ³ÉÒò¼°ÖÎÀí·½·¨Îª½â´ð¹Ø¼ü£¬ÊÔÌâÅàÑøÁËѧÉúµÄÁé»îÓ¦ÓÃÄÜÁ¦£®
| A£® | Na2CO3 | B£® | Na2O | C£® | NaCl | D£® | NaOH |
| A£® | 2H++2e-¨TH2¡ü | B£® | 2H2O+O2+4e-¨T4OH- | ||
| C£® | Fe-3e¨TFe3+ | D£® | Fe-2e¨TFe2+ |
| A£® | ¢Ú¢Û | B£® | ¢Ú¢Ü | C£® | ¢Ú¢Û¢Ü | D£® | ¢Ù¢Ú¢Û¢Ü¢Ý |
| A£® | 1 mol½ðÊôÄÆº¬Óеĵç×ÓÊý | |
| B£® | 1 L 1 mol/LÁòËáÈÜÒºËùº¬µÄH+Êý | |
| C£® | ±ê×¼×´¿öÏ£¬22.4 LËÄÂÈ»¯Ì¼Ëùº¬µÄ·Ö×ÓÊý | |
| D£® | 0.012 kg 12CËùº¬µÄÔ×ÓÊý |
| ζÈ/¡æ | 0 | 100 | 200 | 300 | 400 |
| ƽºâ³£Êý | 667 | 13 | 1.9¡Á10-2 | 2.4¡Á10-4 | 1¡Á10-5 |
| A£® | ¸Ã·´Ó¦µÄ¡÷H£¾0 | |
| B£® | ¼Óѹ¡¢Ôö´óH2Ũ¶ÈºÍ¼ÓÈë´ß»¯¼Á¶¼ÄÜÌá¸ßCOµÄת»¯ÂÊ | |
| C£® | ¹¤ÒµÉϲÉÓÃ5¡Á103kPaºÍ 250¡æµÄÌõ¼þ£¬ÆäÔÒòÊÇÔÁÏÆøµÄת»¯ÂÊ¸ß | |
| D£® | t¡æÊ±£¬Ïò 1 LÃܱÕÈÝÆ÷ÖÐͶÈë0.1 mol COºÍ0.2 mol H2£¬Æ½ºâʱCOת»¯ÂÊΪ50%£¬Ôò¸ÃζÈʱ·´Ó¦µÄƽºâ³£ÊýµÄÊýֵΪ100 |
£¨1£©CO¿ÉÓÃÓÚÁ¶Ìú£¬ÒÑÖª£ºFe2O3£¨s£©+3C£¨s£©¨T2Fe£¨s£©+3CO£¨g£©¡÷H1=+489.0kJ•mol-1£¬C£¨s£©+CO2£¨g£©¨T2CO£¨g£©¡÷H2=+172.5kJ•mol-1£®ÔòCO»¹ÔFe2O3£¨s£©µÄÈÈ»¯Ñ§·½³ÌʽΪFe2O3£¨s£©+3CO£¨g£©?2Fe£¨s£©+3CO2£¨g£©¡÷H=-28.5kJmol-1£®
£¨2£©CO2ºÍH2³äÈëÒ»¶¨Ìå»ýµÄÃܱÕÈÝÆ÷ÖУ¬ÔÚÁ½ÖÖζÈÏ·¢Éú·´Ó¦£ºCO2£¨g£©+3H2£¨g£©?CH3OH£¨g£©+H2O£¨g£© ²âµÃCH3OHµÄÎïÖʵÄÁ¿ËæÊ±¼äµÄ±ä»¯¼ûͼ£®
¢ÙÇúÏߢñ¡¢¢ò¶ÔÓ¦µÄƽºâ³£Êý´óС¹ØÏµÎªK¢ñ£¾K¢ò£¨Ìî¡°£¾¡±»ò¡°=¡±»ò¡°£¼¡±£©£®
¢ÚÒ»¶¨Î¶ÈÏ£¬ÔÚÈÝ»ýÏàͬÇҹ̶¨µÄÁ½¸öÃܱÕÈÝÆ÷ÖУ¬°´ÈçÏ·½Ê½¼ÓÈë·´Ó¦Îһ¶Îʱ¼äºó´ïµ½Æ½ºâ£®
| ÈÝ Æ÷ | ¼× | ÒÒ |
| ·´Ó¦ÎïͶÈëÁ¿ | 1molCO2¡¢3molH2 | a molCO2¡¢b molH2¡¢ c molCH3OH£¨g£©¡¢c molH2O£¨g£© |
¢ÛÒ»¶¨Î¶ÈÏ£¬´Ë·´Ó¦ÔÚºãѹÈÝÆ÷ÖнøÐУ¬ÄÜÅжϸ÷´Ó¦´ïµ½»¯Ñ§Æ½ºâ״̬µÄÒÀ¾ÝÊÇbd£®
a£®ÈÝÆ÷ÖÐѹǿ²»±ä b£®H2µÄÌå»ý·ÖÊý²»±ä c£®c£¨H2£©=3c£¨CH3OH£©
d£®ÈÝÆ÷ÖÐÃܶȲ»±ä e£®2¸öC=O¶ÏÁѵÄͬʱÓÐ6¸öH-H¶ÏÁÑ£®
| A£® | ±ûÓëÎìµÄÔ×ÓÐòÊýÏà²î28 | |
| B£® | ÆøÌ¬Ç⻯ÎïµÄÎȶ¨ÐÔ£º¸ý£¼¼º£¼Îì | |
| C£® | ³£ÎÂÏ£¬¸ýºÍÒÒÐγɵϝºÏÎïÒ×ÈÜÓÚË® | |
| D£® | ¶¡µÄ×î¸ß¼ÛÑõ»¯Îï²»ÓëÈκÎËá·´Ó¦ |