ÌâÄ¿ÄÚÈÝ
¡¾ÌâÄ¿¡¿£¨1£©Ä³Î¶ÈÏÂÖØË®(D2O)µÄÀë×Ó»ý³£ÊýΪ1.6¡Á10£15£¬Ïñ¶¨ÒåpHÒ»ÑùÀ´¹æ¶¨pD£½£lgc(D+)£¬Çë»Ø´ðÒÔÏÂÎÊÌ⣺
¢Ùд³öÖØË®µÄµçÀë·½³Ìʽ ¡£
¢Ú¸ÃζÈÏ£¬ÖØË®ÖеÄpD£½_____ ___(ÒÑÖªlg2£½0.3)¡£
¢Û0.01 mol/LµÄNaODÈÜÒºÖÐpD£½____ ____¡£
£¨2£©Ë«ÑõË®£¨H2O2£©ºÍË®¶¼ÊǼ«Èõµç½âÖÊ£¬µ«H2O2±ÈË®¸üÏÔËáÐÔ¡£
¢ÙÈô°ÑH2O2¿´³ÉÊǶþÔªÈõËᣬÇëд³öËüÔÚË®ÖеÚÒ»²½µçÀëµÄ·½³Ìʽ£º______________¡£
¢Ú¼øÓÚH2O2ÏÔÈõËáÐÔ£¬ËüÄÜͬǿ¼î×÷ÓÃÐγÉÕýÑΣ¬ÔÚÒ»¶¨Ìõ¼þÏÂÒ²¿ÉÒÔÐγÉËáʽÑΡ£Çëд³öH2O2ÓëBa(OH)2×÷ÓÃÐγÉÕýÑεĻ¯Ñ§·½³Ìʽ£º_____________________¡£
¢ÛË®µçÀëÉú³ÉH3O+ ºÍOH£½Ð×öË®µÄ×ÔżµçÀ롣ͬˮһÑù£¬H2O2Ò²Óм«Î¢ÈõµÄ×ÔżµçÀ룬Æä×ÔżµçÀë·½³ÌʽΪ£º_______________________¡£
¡¾´ð°¸¡¿
£¨1£©¢ÙD2OD++OD-¢Ú7.4¢Û12.8
£¨2£©¢ÙH2O2H++HO2£
¢ÚH2O2+Ba(OH)2=BaO2+2H2O
¢ÛH2O2+H2O2£½H3O2++HO2£
¡¾½âÎö¡¿
ÊÔÌâ·ÖÎö£º
£¨1£©¢ÙÀà±ÈË®µÄµçÀë·½³Ìʽ£¬¿ÉÖªÖØË®µÄµçÀë·½³ÌʽΪD2OD++OD£¡£
¢ÚijζÈÏÂÖØË®£¨D2O£©µÄÀë×Ó»ý³£ÊýΪ1.6¡Á10-15£¬Ôòc(D+)£½c(OD-)=4¡Á10-8mol/L£¬pD£½8-lg4=7.4¡£
¢Û0.01 mol/LµÄNaODÈÜÒºÖУ¬c(OD-)=0.01mol/L£¬c(D+)£½=1.6¡Á10-13£¬ÆäpD=13.0£lg1.6=12.8¡£
£¨2£©¢ÙÈô°ÑH2O2¿´³ÉÊǶþÔªÈõËᣬÔòÔÚË®Öзֲ½µçÀ룬µÚÒ»²½µçÀëµÄ·½³ÌʽΪH2O2H+ + HO2£¡£
¢ÚH2O2ÏÔÈõËáÐÔ£¬¿´³ÉÊǶþÔªÈõËᣬͬǿ¼î×÷ÓÃÐγÉÕýÑΣ¬ÔòH2O2ÓëBa(OH)2×÷ÓÃÐγÉÕýÑεĻ¯Ñ§·½³ÌʽΪH2O2 + Ba(OH)2 =BaO2 + 2H2O¡£
¢ÛË®µÄ×ÔżµçÀëΪ2H2OH3O+ +OH££¬ÔòH2O2µÄ×ÔżµçÀë·½³ÌʽΪ£ºH2O2 + H2O2£½H3O2+ + HO2£¡£