题目内容

【题目】丙烷的燃烧热为△H=﹣a kJ/mol,有以下反应:
①C3H8(g)=C3H6(g)+H2(g)△H=+b kJ/mol
②2C3H6(g)+9O2(g)=6CO2(g)+6H2O(l)△H=﹣c kJ/mol
③2H2(g)+O2(g)=2H2O(l)△H=﹣d kJ/mol (b、c、d均为正值)则正确的(  )
A.2a=c﹣d﹣2b
B.-a=c﹣d﹣2b
C.2a=c+d﹣2b
D.a=c+d﹣b/2

【答案】C
【解析】①C3H8(g)=C3H6(g)+H2(g)△H=+b kJmol1
②2C3H6(g)+9O2(g)=6CO2(g)+6H2O(l)△H=﹣c kJmol1
③2H2(g)+O2(g)=2H2O(l)△H=﹣d kJmol1
依据盖斯定律①×2+②+③得到2C3H8(g)+10O2(g)=6CO2(g)+8H2O(l)△H=(2b﹣c﹣d)KJ/mol;
燃烧热为:C3H8(g)+5O2(g)=3CO2(g)+4H2O(l)△H=﹣a=﹣ (2b﹣c﹣d)KJ/mol;
得到a=﹣ (2b﹣c﹣d),2a=c+d﹣2b;所以选C.

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