ÌâÄ¿ÄÚÈÝ
¡¾ÌâÄ¿¡¿³£ÎÂÏ£¬Ïò20 mL 0.1 mol¡¤L1µÄHAÈÜÒºÖÐÖðµÎ¼ÓÈë0.1mol¡¤L1µÄNaOHÈÜÒº£¬ÈÜÒºÖÐË®ËùµçÀëµÄcË®(H£«)Ëæ¼ÓÈëNaOHÈÜÒºÌå»ýµÄ±ä»¯ÈçͼËùʾ£¬ÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ
A.HAµÄµçÀë³£ÊýKaԼΪ1¡Á105
B.BµãµÄÈÜÒºÖÐÁ£×ÓŨ¶ÈÂú×ã¹Øϵ£ºc(HA)£¾c(Na£«)£¾c(A)
C.C¡¢EÁ½µãÒòΪ¶ÔË®µÄµçÀëµÄÒÖÖÆ×÷Óúʹٽø×÷ÓÃÏàͬ£¬ËùÒÔÈÜÒº¾ù³ÊÖÐÐÔ
D.FµãµÄÈÜÒº³Ê¼îÐÔ£¬Á£×ÓŨ¶ÈÂú×ã¹Øϵc(OH)£½c(HA)£«c(A)£«c(H£«)
¡¾´ð°¸¡¿A
¡¾½âÎö¡¿
A£®ÓÉͼ¿ÉÖª£¬0.1 mol¡¤L1µÄHAÈÜÒºÖÐcË®(H£«)= 1¡Á10-11 mol¡¤L1£¬Ôò0.1 mol¡¤L1µÄHAÈÜÒºÖÐc(H£«)= 1¡Á10-3 mol¡¤L1£¬Óɴ˿ɼÆËã³öHAµÄµçÀë³£ÊýKaԼΪ1¡Á105£¬AÏîÕýÈ·£»
B£®ÓÉͼ¿ÉÖª£¬BµãΪÌå»ý±ÈΪ1:2µÄNaOHÈÜÒººÍHAÈÜÒº·´Ó¦£¬ËùµÃÈÜҺΪµÈŨ¶ÈµÄHAºÍNaAµÄ»ìºÏÈÜÒº£¬´ËʱÈÜÒº³ÊËáÐÔ£¬ËµÃ÷HAµÄµçÀë³Ì¶È´óÓÚA-µÄË®½â³Ì¶È£¬Ôòc(A-)£¾c(Na+)£¾c(HA)£¬BÏî´íÎó£»
C£®CµãÊÇHAºÍNaAµÄ»ìºÏÈÜÒº£¬ÈÜÒº³ÊÖÐÐÔ£¬¶øEµãNaOH¹ýÁ¿£¬ËùµÃÈÜҺΪNaAºÍNaOHµÄ»ìºÏÈÜÒº£¬ÈÜÒº³Ê¼îÐÔ£¬CÏî´íÎó£»
D£®ÓÉͼ¿ÉÖª£¬FµãµÄÈÜҺΪµÈŨ¶ÈµÄNaAºÍNaOHµÄ»ìºÏÈÜÒº£¬ÓÉÖÊ×ÓÊغã¿ÉµÃ£ºc(OH-)£½2c(HA)+c(A-)+c(H+)£¬DÏî´íÎó£»
´ð°¸Ñ¡A¡£