ÌâÄ¿ÄÚÈÝ
¡¾ÌâÄ¿¡¿Ä³ÎÞÉ«ÈÜÒºÖпÉÄܺ¬ÓÐMg2+¡¢Ba2+¡¢Cl-¡¢HCO3-ÖеÄÒ»ÖÖ»ò¼¸ÖÖÀë×Ó¡£ÎªÈ·¶¨Æä³É·Ö£¬½øÐÐÒÔÏÂʵÑ飺
ʵÑé1£ºÈ¡l0mLÎÞÉ«ÈÜÒº£¬µÎ¼ÓÊÊÁ¿Ï¡ÑÎËáÎÞÃ÷ÏÔÏÖÏó¡£
ʵÑé2£ºÁíÈ¡l0mLÎÞÉ«ÈÜÒº£¬¼ÓÈë×ãÁ¿µÄNa2SO4ÈÜÒº£¬Óа×É«³ÁµíÉú³É¡£
ʵÑé3£º½«ÊµÑélºóµÄÈÜÒºÓÚ׶ÐÎÆ¿ÖУ¬Ïò׶ÐÎÆ¿ÖÐÖðµÎ¼ÓÈëNaOHÈÜÒº£¬µÎ¼Ó¹ý³ÌÖвúÉú³ÁµíµÄÖÊÁ¿Óë¼ÓÈëNaOHÈÜÒºµÄÌå»ýµÄ¹ØϵÈçͼËùʾ¡£
»Ø´ðÏÂÁÐÎÊÌ⣺
£¨1£©ÔÈÜÒºÖв»´æÔÚµÄÀë×ÓÓÐ________£¬´æÔÚµÄÀë×ÓÓÐ___________________¡£
£¨2£©ÊµÑé3ÖУ¬Í¼ÏñÖÐOA¶Î·´Ó¦µÄÀë×Ó·½³ÌʽΪ___________________¡£
£¨3£©¸ù¾ÝͼÏñ¼ÆËãÔÈÜÒºÖÐMg2+µÄÎïÖʵÄÁ¿Å¨¶È______________¡££¨Ð´³ö¼ÆËã¹ý³Ì£©
¡¾´ð°¸¡¿ HCO3- Mg2+¡¢Ba2+¡¢Cl- H++OH-= H2O 1 mol/L
¡¾½âÎö¡¿ÊµÑé1£ºÈ¡l0mLÎÞÉ«ÈÜÒº£¬µÎ¼ÓÊÊÁ¿Ï¡ÑÎËáÎÞÃ÷ÏÔÏÖÏó¡£ËµÃ÷ÔÈÜÒºÖв»´æÔÚHCO3-£»ÊµÑé2£ºÁíÈ¡l0mLÎÞÉ«ÈÜÒº£¬¼ÓÈë×ãÁ¿µÄNa2SO4ÈÜÒº£¬Óа×É«³ÁµíÉú³É¡£ËµÃ÷ÈÜÒºÖÐÓÐBa2+£»ÊµÑé3£º½«ÊµÑélºóµÄÈÜÒºÓÚ׶ÐÎÆ¿ÖУ¬Ïò׶ÐÎÆ¿ÖÐÖðµÎ¼ÓÈëNaOHÈÜÒº£¬µÎ¼Ó¹ý³ÌÖвúÉú³ÁµíµÄÖÊÁ¿Óë¼ÓÈëNaOHÈÜÒºµÄÌå»ýµÄ¹Øϵͼ±íÃ÷£º¿ªÊ¼ÎÞ³Áµí˵Ã÷ÈÜÒºÖÐÓÐH+£¬ÔÙ²úÉúÁ˳Áµí£¬ËµÃ÷ÈÜÒºÖÐÓÐ Mg2+£¬ÓÖÈÜÒº³ÊµçÖÐÐÔ£¬ÈÜÒºÖÐÒ»¶¨ÓÐÒõÀë×ÓCl-¡£
£¨1£©ÔÈÜÒºÖв»´æÔÚµÄÀë×ÓÓÐHCO3-£¬´æÔÚµÄÀë×ÓÓÐMg2+¡¢Ba2+¡¢Cl- ¡££¨2£©ÊµÑé3ÖУ¬Í¼ÏñÖÐOA¶ÎÖкÍÈÜÒºÖÐH+£¬·´Ó¦µÄÀë×Ó·½³ÌʽΪH++OH-= H2O¡££¨3£©¸ù¾ÝͼÏñ¼ÆËãÔÈÜÒºÖÐMg2+µÄÎïÖʵÄÁ¿Å¨¶ÈΪ£ºn(Mg(OH)2)=0.58g/58g¡¤mol£1=0.01mol,c(Mg2£«)=0.01mol/0.01L=1mol¡¤L£1¡£