ÌâÄ¿ÄÚÈÝ
a£®Ë®ÕôÆø´ß»¯ÖØÕû£ºCH3CH2OH(g)£«H2O(g)¡ú4H2(g)£«2CO(g)¡¡¦¤H£½£«255.58 kJ¡¤mol-1
b£®²¿·Ö´ß»¯Ñõ»¯£ºCH3CH2OH(g)£«1/2O2(g)¡ú3H2(g)£«2CO(g)¡¡¦¤H£½£«13.76 kJ¡¤mol-1
ÔòÏÂÁÐ˵·¨´íÎóµÄÊÇ
B£®´ÓÄÜÁ¿ÏûºÄµÄ½Ç¶ÈÀ´¿´£¬b·ÏßÖÆÇâ¸ü¼ÓÓÐÀû
C£®a·ÏßÖÆÇâÓÉÓÚÒªÏûºÄºÜ¶àÄÜÁ¿£¬ËùÒÔÔÚʵ¼ÊÉú²úÖÐÒâÒå²»´ó
D£®b·Ïß·´Ó¦£¬ÊÇÓɸßÄÜÁ¿ÏòµÍÄÜÁ¿µÄ·´Ó¦
Ë®ÃºÆøÊÇÖØÒª
ȼÁϺͻ¯¹¤ÔÁÏ£¬¿ÉÓÃË®ÕôÆøÍ¨¹ý³ãÈȵÄÌ¿²ãÖÆµÃ£º
C (s) + H2O(g)
CO (g) +H2 (g) ¡÷H£½ +131.3 kJ•mol£1
£¨1£©Êµ¼Ê¹¤ÒµÉú²úÖУ¬ÏòÌ¿²ã¼ä¸ô½»ÌæÍ¨ÈëË®ÕôÆøºÍ¿ÕÆø£¬ÆäÔÒòÊÇ ¡£
£¨2£©Ò»¶¨Î¶ÈÏ£¬Èý¸öÈÝÆ÷Öоù½øÐÐ×ÅÉÏÊö·´Ó¦£¬¸÷ÈÝÆ÷ÖÐÌ¿×ãÁ¿£¬ÆäËüÎïÖʵÄÎïÖʵÄÁ¿Å¨¶È¼°ÕýÄæ·´Ó¦ËÙÂʹØÏµÈçϱíËùʾ¡£ÇëÌîд±íÖÐÏàÓ¦µÄ¿Õ¸ñ¡£
| ÈÝÆ÷±àºÅ | c(H2O)/mol¡¤L£1 | c(CO)/mol¡¤L£1 | c(H2)/mol¡¤L£1 | ¦ÍÕý¡¢¦ÍÄæ±È½Ï |
| I | 0.06 | 0.60 | 0.10 | ¦ÍÕý=¦ÍÄæ |
| ¢ò | 0.12 | 0.20 | ________ | ¦ÍÕý=¦ÍÄæ |
| ¢ó | 0.10 | 0.20 | 0.40 | ¦ÍÕý____¦ÍÄæ |
£¨3£©ÉúÎïÒÒ´¼¿ÉÓɵí·Û»òÏËÎ¬ËØµÈÉúÎïÖÊÔÁÏ·¢½Í»ñµÃ¡£ÀûÓÃÒÒ´¼¿É½ø¶ø»ñµÃºÏ³ÉÆø£¨CO¡¢H2£©¡£
ÓÃÒÒ´¼Éú²úºÏ³ÉÆøÓÐÈçÏÂÁ½Ìõ·Ïߣº
a¡¢Ë®ÕôÆø´ß»¯ÖØÕû£ºCH3CH2OH(g)£«H2O(g)¡ú4H2(g)£«2CO(g)
b¡¢²¿·Ö´ß»¯Ñõ»¯£ºCH3CH2OH(g)£«1/2O2(g)¡ú3H2(g)£«2CO(g)
ijÉúÎïÖÊÄÜÑо¿Ëù×¼±¸ÀûÓÃÒÒ´¼µÃµ½µÄºÏ³ÉÆøºÏ³ÉÒ»ÖÖÉúÎïÆûÓÍ¡£ÒÒ´¼¸÷·ÖÒ»°ë°´a¡¢bÁ½Ê½·´Ó¦¡£ºÏ³ÉÆøºÏ³ÉÉúÎïÆûÓ͵ķ´Ó¦Îª£º2mCO£«(2m£«n)H2¡ú2CmHn£«2mH2O¡£¼Ù¶¨ºÏ³ÉµÄÉúÎïÆûÓÍÖк¬ÓÐX¡¢YÁ½Öֳɷ֣¬ÇÒX¡¢Y¶¼ÊÇÓÐ8¸ö̼Ô×ÓµÄÌþ£¬XÊDZ½µÄͬϵÎYÊÇÍéÌþ¡£
¢ÙXµÄ·Ö×ÓʽΪ £¬YµÄ·Ö×ÓʽΪ ¡£
¢Ú50¶ÖÖÊÁ¿·ÖÊýΪ92%µÄÒÒ´¼¾ÉÏÊöת»¯£¨¼Ù¶¨¸÷²½×ª»¯ÂʾùΪ100%£©£¬Ôò×îÖÕ¿É»ñµÃXµÄÖÊÁ¿Îª¶àÉÙ¶Ö£¿