ÌâÄ¿ÄÚÈÝ
ÒÑÖªÓÐÒÔÏÂËĸöÈÈ»¯Ñ§·½³Ìʽ¼°Æä·´Ó¦ÈÈ£º¢ÙC(s)+
O2
CO(g) ¦¤H=-akJ¡¤mol-1
¢ÚCH4(g)+
O2(g)
CO(g)+2H2O(g) ¦¤H=-bkJ¡¤mol-1
¢ÛH2S(g)+
O2(g)
S(s)+H2O(g) ¦¤H=-ckJ¡¤mol-1
¢ÜH2(g)+
O2(g)
H2O(g) ¦¤H=-dkJ¡¤mol-1
¿ÉµÃ³ö½áÂÛ£ºC¡¢CH4¡¢H2S¡¢H2µÄȼÉÕÈÈ·Ö±ðÊÇa¡¢b¡¢c¡¢d¡£
ÒÔÉϽáÂÛÊÇ·ñÕýÈ·?˵Ã÷ÔÒò¡£
ÒÔÉϽáÂÛ¾ù²»ÕýÈ·¡£
¢Ù¿ÉȼÎï̼Ϊ1 mol£¬Éú³ÉÎȶ¨Ñõ»¯ÎïӦΪCO2(g)£¬²¢·ÇCO(g)¡£
¢Ú1 mol CH4ÍêȫȼÉÕÉú³ÉÎȶ¨Ñõ»¯Îï³ýҺ̬ˮÍ⻹ӦÓÐCO2(g)£¬²¢²»ÊÇCO(g)¡£
¢ÛͬÑù£¬1 mol H2SȼÉÕºóÓ¦Éú³ÉÎȶ¨Ñõ»¯ÎïSO2(g)£¬²»Ó¦ÊÇS(s)¡£
¢ÜH2ÍêȫȼÉÕÉú³ÉµÄÎȶ¨Ñõ»¯ÎïÓ¦ÊÇH2O(l)¡£
£¨12·Ö£©¢ñ.úȼÉյķ´Ó¦ÈÈ¿Éͨ¹ýÒÔÏÂÁ½¸ö;¾¶À´ÀûÓãºa. ÀûÓÃúÔÚ³ä×ãµÄ¿ÕÆøÖÐÖ±½ÓȼÉÕ²úÉúµÄ·´Ó¦ÈÈ£»b. ÏÈʹúÓëË®ÕôÆø·´Ó¦µÃµ½ÇâÆøºÍÒ»Ñõ»¯Ì¼£¬È»ºóʹµÃµ½µÄÇâÆøºÍÒ»Ñõ»¯Ì¼ÔÚ³ä×ãµÄ¿ÕÆøÖÐȼÉÕ¡£ÕâÁ½¸ö¹ý³ÌµÄÈÈ»¯Ñ§·½³ÌʽΪ£º
C(s)+O2(g)£½CO2(g)£» ¦¤H£½E1 ¢Ù
C(s)£«H2O(g)£½CO(g)£«H2(g) ¦¤H£½E2 ¢Ú
H2(g)+1/2O2(g)£½H2O(g)£» ¦¤H£½E3 ¢Û
CO(g)+1/2O2(g)£½CO2(g)£» ¦¤H£½E4 ¢Ü£¬
ÊԻشðÏÂÁÐÎÊÌâ
£¨1£©Óë;¾¶aÏà±È£¬Í¾¾¶bÓн϶àµÄÓŵ㣬¼´ ¡£
£¨2£©ÉÏÊöËĸöÈÈ»¯Ñ§·½³ÌʽÖЦ¤H£¾0µÄ·´Ó¦ÓÐ ¡£
£¨3£©µÈÖÊÁ¿µÄú·Ö±ðͨ¹ýÒÔÉÏÁ½Ìõ²»Í¬Í¾¾¶²úÉúµÄ¿ÉÀûÓõÄ×ÜÄÜÁ¿¹ØÏµÕýÈ·µÄÊÇ ¡£
| A£®a±Èb¶à | B£®a±ÈbÉÙ | C£® aÓëbÔÚÀíÂÛÉÏÏàͬ | D£®Á½ÕßÎÞ·¨±È½Ï |
ÒÑÖª£º CH4(g)£«H2O(g)£½CO(g)£«3H2(g) ¦¤H£½+206.2kJ¡¤mol£1
CH4(g)£«CO2(g)£½2CO(g)£«2H2(g) ¦¤H£½+247.4 kJ¡¤mol£1
ÒÔ¼×ÍéΪÔÁÏÖÆÈ¡ÇâÆøÊǹ¤ÒµÉϳ£ÓõÄÖÆÇâ·½·¨¡£CH4(g)ÓëH2O(g)·´Ó¦Éú³ÉCO2(g)ºÍH2(g)µÄÈÈ»¯Ñ§·½³ÌʽΪ ¡£
¢ñ.úȼÉյķ´Ó¦ÈÈ¿Éͨ¹ýÒÔÏÂÁ½¸ö;¾¶À´ÀûÓãºa. ÀûÓÃúÔÚ³ä×ãµÄ¿ÕÆøÖÐÖ±½ÓȼÉÕ²úÉúµÄ·´Ó¦ÈÈ£»b. ÏÈʹúÓëË®ÕôÆø·´Ó¦µÃµ½ÇâÆøºÍÒ»Ñõ»¯Ì¼£¬È»ºóʹµÃµ½µÄÇâÆøºÍÒ»Ñõ»¯Ì¼ÔÚ³ä×ãµÄ¿ÕÆøÖÐȼÉÕ¡£ÕâÁ½¸ö¹ý³ÌµÄÈÈ»¯Ñ§·½³ÌʽΪ£º
C(s)+O2(g)£½CO2(g)£» ¦¤H£½E1 ¢Ù
C(s)+H2O(g)£½CO(g)+H2(g) ¦¤H£½E2 ¢Ú
H2(g)+1/2O2(g)£½H2O(g)£» ¦¤H£½E3 ¢Û
CO(g)+1/2O2(g)£½CO2(g)£» ¦¤H£½E4 ¢Ü£¬
ÊԻشðÏÂÁÐÎÊÌâ
£¨1£©Óë;¾¶aÏà±È£¬Í¾¾¶bÓн϶àµÄÓŵ㣬¼´________¡£
£¨2£©ÉÏÊöËĸöÈÈ»¯Ñ§·½³ÌʽÖЦ¤H£¾0µÄ·´Ó¦ÓÐ________¡£
£¨3£©µÈÖÊÁ¿µÄú·Ö±ðͨ¹ýÒÔÉÏÁ½Ìõ²»Í¬Í¾¾¶²úÉúµÄ¿ÉÀûÓõÄ×ÜÄÜÁ¿¹ØÏµÕýÈ·µÄÊÇ________¡£
| A£®a±Èb¶à | B£®a±ÈbÉÙ | C£® aÓëbÔÚÀíÂÛÉÏÏàͬ | D£®Á½ÕßÎÞ·¨±È½Ï |
¢ò.ÇâÆøÊÇÒ»ÖÖÇå½àÄÜÔ´£¬ÇâÆøµÄÖÆÈ¡Óë´¢´æÊÇÇâÄÜÔ´ÀûÓÃÁìÓòµÄÑо¿Èȵ㡣
ÒÑÖª£º CH4(g)+H2O(g)£½CO(g)+3H2(g) ¦¤H£½+206.2kJ¡¤mol-1
CH4(g)+CO2(g)£½2CO(g)+2H2(g) ¦¤H£½+247.4 kJ¡¤mol-1
ÒÔ¼×ÍéΪÔÁÏÖÆÈ¡ÇâÆøÊǹ¤ÒµÉϳ£ÓõÄÖÆÇâ·½·¨¡£CH4(g)ÓëH2O(g)·´Ó¦Éú³ÉCO2(g)ºÍH2(g)µÄÈÈ»¯Ñ§·½³ÌʽΪ________¡£