题目内容

【题目】.LiH可作飞船的燃料,已知下列反应:

2Li(s)+H2(g)2LiH(s) H=-182kJ·mol-1

2H2(g)+O2(g)2H2O(1) H=-572kJ·mol-1

4Li(s)+O2(g)2Li2O(s) H=-1196kJ·mol-1

LiHO2中燃烧的热化学方程式为( )

A. 2LiH(s)+O2(g)Li2O(s)+H2O(1) H=-702kJ·mol-1

B. 2LiH(s)+O2(g)Li2O(s)+H2O(1) H=-1950kJ·mol-1

C. 2LiH(s)+O2(g)Li2O(s)+H2O(1) H=-1586kJ·mol-1

D. 2LiH(s)+O2(g)Li2O(s)+H2O(g) H=-988kJ·mol-1

【答案】A

【解析】试题分析:已知:①2Li(s)H2(g)2LiH(s)ΔH1=-182 kJ·mol1

②2H2(g)O2(g)2H2O(l)ΔH2=-572 kJ·mol1

③4Li(s)O2(g)2Li2O(s)ΔH3=-1 196 kJ·mol1

则根据盖斯定律可知(①×2/2即得到LiHO2中燃烧的热化学方程式为2LiH(s)O2(g)Li2O(s)H2O(l)ΔH=-702 kJ·mol1,答案选A

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