ÌâÄ¿ÄÚÈÝ
Çë°´ÒªÇóÌî¿Õ£º
£¨1£©Ä³ÔªËØÔ×ӵļ۵ç×Ó¹¹ÐÍΪ3d104s2£¬ËüÊôÓÚµÚ
£¨2£©D3+µÄ3dÑDzãΪ°ë³äÂú£¬Æä»ù̬Ô×ӵĵç×ÓÅŲ¼Ê½Îª
£¨3£©ÒÑÖªÏÂÁÐÔªËØÔÚÖÜÆÚ±íÖеÄλÖã¬Ð´³öËüÃÇ×îÍâ²ãµç×ÓµÄÅŲ¼Ê½ºÍÔªËØ·ûºÅ£º
¢ÙµÚ4ÖÜÆÚ¢ôB×å
¢ÚµÚ5ÖÜÆÚ¢÷A×å
£¨4£©¢ÙCaC2ÖÐC22-ÓëO22+»¥ÎªµÈµç×ÓÌ壬O22+µÄµç×Óʽ¿É±íʾΪ 1mol O22+Öк¬ÓеĦмüÊýĿΪ
¢ÚÒÒȲÓëÇâÇèËá·´Ó¦¿ÉµÃ±ûÏ©ë棨H2C=CH-C¡ÔN£©£®±ûÏ©ëæ·Ö×ÓÖÐ̼Ô×Ó¹ìµÀÔÓ»¯ÀàÐÍÓÐ
£¨1£©Ä³ÔªËØÔ×ӵļ۵ç×Ó¹¹ÐÍΪ3d104s2£¬ËüÊôÓÚµÚ
4
4
ÖÜÆÚ£¬µÚ¢òB
¢òB
×壬ds
ds
ÇøÔªËØ£¬ÔªËØ·ûºÅÊÇZn
Zn
£¬Ä³ÔªËØÔ×ӵļ۵ç×Ó¹¹ÐÍΪ3d54s1£¬ËüÊôÓÚµÚËÄÖÜÆÚ£¬dÇøÔªËØ£¬ÔªËØ·ûºÅÊÇCr
Cr
£®£¨2£©D3+µÄ3dÑDzãΪ°ë³äÂú£¬Æä»ù̬Ô×ӵĵç×ÓÅŲ¼Ê½Îª
[Ar]3d64s2
[Ar]3d64s2
£¬E+µÄK¡¢L¡¢M²ãÈ«³äÂú£¬EµÄÔªËØ·ûºÅÊÇCu
Cu
£¬Æä»ù̬Ô×ӵĵç×ÓÅŲ¼Ê½Îª[Ar]3d104s1
[Ar]3d104s1
£¨3£©ÒÑÖªÏÂÁÐÔªËØÔÚÖÜÆÚ±íÖеÄλÖã¬Ð´³öËüÃÇ×îÍâ²ãµç×ÓµÄÅŲ¼Ê½ºÍÔªËØ·ûºÅ£º
¢ÙµÚ4ÖÜÆÚ¢ôB×å
Ti£¬3d64s2
Ti£¬3d64s2
£»¢ÚµÚ5ÖÜÆÚ¢÷A×å
I£¬5s25p5
I£¬5s25p5
£®£¨4£©¢ÙCaC2ÖÐC22-ÓëO22+»¥ÎªµÈµç×ÓÌ壬O22+µÄµç×Óʽ¿É±íʾΪ 1mol O22+Öк¬ÓеĦмüÊýĿΪ
2
2
£®¢ÚÒÒȲÓëÇâÇèËá·´Ó¦¿ÉµÃ±ûÏ©ë棨H2C=CH-C¡ÔN£©£®±ûÏ©ëæ·Ö×ÓÖÐ̼Ô×Ó¹ìµÀÔÓ»¯ÀàÐÍÓÐ
spÔÓ»¯¡¢sp2 ÔÓ»¯
spÔÓ»¯¡¢sp2 ÔÓ»¯
£»·Ö×ÓÖд¦ÓÚͬһֱÏßÉϵÄÔ×ÓÊýÄ¿×î¶àΪ3
3
£®·ÖÎö£º£¨1£©¼Ûµç×Ó¹¹ÐÍΪ3d104s2£¬Ó¦Î»ÓÚµÚ4ÖÜÆÚ¢òB×壬¼Ûµç×Ó¹¹ÐÍΪ3d54s1£¬Ó¦ÎªµÚ4ÖÜÆÚ¢öB×壻
£¨2£©D3+µÄ3dÑDzãΪ°ë³äÂú£¬Ôò»ù̬Ô×ӵļ۵ç×ÓÅŲ¼Îª3d64s2£¬Ó¦ÎªÌúÔªËØ£¬E+µÄK¡¢L¡¢M²ãÈ«³äÂú£¬Ó¦ÎªCuÔªËØ£»
£¨3£©µÚ4ÖÜÆÚ¢ôB×åΪTiÔªËØ£¬µÚ5ÖÜÆÚ¢÷A×åΪIÔªËØ£»
£¨4£©O22+µÄµç×ÓʽÓëC22-ÏàËÆ£¬º¬ÓÐO¡ÔO¼ü£¬½áºÏ¼Û²ãµç×Ó¶ÔÅжÏÔÓ»¯ÀàÐÍ£®
£¨2£©D3+µÄ3dÑDzãΪ°ë³äÂú£¬Ôò»ù̬Ô×ӵļ۵ç×ÓÅŲ¼Îª3d64s2£¬Ó¦ÎªÌúÔªËØ£¬E+µÄK¡¢L¡¢M²ãÈ«³äÂú£¬Ó¦ÎªCuÔªËØ£»
£¨3£©µÚ4ÖÜÆÚ¢ôB×åΪTiÔªËØ£¬µÚ5ÖÜÆÚ¢÷A×åΪIÔªËØ£»
£¨4£©O22+µÄµç×ÓʽÓëC22-ÏàËÆ£¬º¬ÓÐO¡ÔO¼ü£¬½áºÏ¼Û²ãµç×Ó¶ÔÅжÏÔÓ»¯ÀàÐÍ£®
½â´ð£º½â£º£¨1£©¼Ûµç×Ó¹¹ÐÍΪ3d104s2£¬Ó¦Î»ÓÚµÚ4ÖÜÆÚ¢òB×壬ΪZnÔªËØ£¬Î»ÓÚÖÜÆÚ±ídsÇø£¬¼Ûµç×Ó¹¹ÐÍΪ3d54s1£¬Ó¦ÎªµÚ4ÖÜÆÚ¢öB×壬ΪCrÔªËØ£¬
¹Ê´ð°¸Îª£º4£»¢òB£»ds£»Zn£»Cr£»
£¨2£©D3+µÄ3dÑDzãΪ°ë³äÂú£¬Ôò»ù̬Ô×ӵļ۵ç×ÓÅŲ¼Îª3d64s2£¬Ó¦ÎªÌúÔªËØ£¬Æä»ù̬Ô×ӵĵç×ÓÅŲ¼Ê½Îª[Ar]3d64s2£¬E+µÄK¡¢L¡¢M²ãÈ«³äÂú£¬Ó¦ÎªCuÔªËØ£¬»ù̬Ô×ӵĵç×ÓÅŲ¼Ê½Îª[Ar]3d104s1£¬
¹Ê´ð°¸Îª£º[Ar]3d64s2£»Cu£»[Ar]3d104s1£»
£¨3£©µÚ4ÖÜÆÚ¢ôB×åΪTiÔªËØ£¬×îÍâ²ãµç×ÓµÄÅŲ¼Ê½Îª3d24s2£¬µÚ5ÖÜÆÚ¢÷A×åΪIÔªËØ£¬×îÍâ²ãµç×ÓµÄÅŲ¼Ê½5s25p5£¬
¹Ê´ð°¸Îª£ºTi£¬3d64s2£»I£¬5s25p5£»
£¨4£©¢ÙO22+µÄµç×ÓʽÓëC22-ÏàËÆ£¬µç×ÓʽΪ£¬º¬ÓÐO¡ÔO¼ü£¬º¬ÓеĦмüÊýĿΪ2£¬
¹Ê´ð°¸Îª£º£¬2£»
¢ÚH2C=CH-C¡ÔNÖÐCÔ×Ó·Ö±ðÐγÉ3¸ö¦Ä¼üºÍ2¸ö¦Ä¼ü£¬Ôò̼Ô×Ó¹ìµÀÔÓ»¯ÀàÐÍÓÐspÔÓ»¯¡¢sp2 ÔÓ»¯£¬·Ö×ÓÖд¦ÓÚͬһֱÏßÉϵÄÔ×ÓÊýÄ¿×î¶àΪ3£¬
¹Ê´ð°¸Îª£ºspÔÓ»¯¡¢sp2 ÔÓ»¯£»3£®
¹Ê´ð°¸Îª£º4£»¢òB£»ds£»Zn£»Cr£»
£¨2£©D3+µÄ3dÑDzãΪ°ë³äÂú£¬Ôò»ù̬Ô×ӵļ۵ç×ÓÅŲ¼Îª3d64s2£¬Ó¦ÎªÌúÔªËØ£¬Æä»ù̬Ô×ӵĵç×ÓÅŲ¼Ê½Îª[Ar]3d64s2£¬E+µÄK¡¢L¡¢M²ãÈ«³äÂú£¬Ó¦ÎªCuÔªËØ£¬»ù̬Ô×ӵĵç×ÓÅŲ¼Ê½Îª[Ar]3d104s1£¬
¹Ê´ð°¸Îª£º[Ar]3d64s2£»Cu£»[Ar]3d104s1£»
£¨3£©µÚ4ÖÜÆÚ¢ôB×åΪTiÔªËØ£¬×îÍâ²ãµç×ÓµÄÅŲ¼Ê½Îª3d24s2£¬µÚ5ÖÜÆÚ¢÷A×åΪIÔªËØ£¬×îÍâ²ãµç×ÓµÄÅŲ¼Ê½5s25p5£¬
¹Ê´ð°¸Îª£ºTi£¬3d64s2£»I£¬5s25p5£»
£¨4£©¢ÙO22+µÄµç×ÓʽÓëC22-ÏàËÆ£¬µç×ÓʽΪ£¬º¬ÓÐO¡ÔO¼ü£¬º¬ÓеĦмüÊýĿΪ2£¬
¹Ê´ð°¸Îª£º£¬2£»
¢ÚH2C=CH-C¡ÔNÖÐCÔ×Ó·Ö±ðÐγÉ3¸ö¦Ä¼üºÍ2¸ö¦Ä¼ü£¬Ôò̼Ô×Ó¹ìµÀÔÓ»¯ÀàÐÍÓÐspÔÓ»¯¡¢sp2 ÔÓ»¯£¬·Ö×ÓÖд¦ÓÚͬһֱÏßÉϵÄÔ×ÓÊýÄ¿×î¶àΪ3£¬
¹Ê´ð°¸Îª£ºspÔÓ»¯¡¢sp2 ÔÓ»¯£»3£®
µãÆÀ£º±¾Ì⿼²é½ÏΪ×ۺϣ¬Éæ¼°Ô×ÓºËÍâµç×ÓµÄÅŲ¼¡¢ÔªËØÔÚÖÜÆÚ±íÖеÄλÖõÄÅжÏÒÔ¼°ÔÓ»¯ÀàÐ͵È֪ʶ£¬²àÖØÓÚѧÉúµÄ·ÖÎöÄÜÁ¦µÄ¿¼²é£¬ÄѶÈÖеȣ¬×¢ÒâÏà¹Ø»ù´¡ÖªÊ¶µÄ»ýÀÛ£®
Á·Ï°²áϵÁдð°¸
Ïà¹ØÌâÄ¿