ÌâÄ¿ÄÚÈÝ

»¯Ñ§·´Ó¦ÖмÈÓÐÎïÖʱ仯£¬ÓÖÓÐÄÜÁ¿±ä»¯£¬ÊÍ·Å»òÎüÊÕÈÈÁ¿ÊÇ»¯Ñ§·´Ó¦ÖÐÄÜÁ¿±ä»¯µÄÖ÷ÒªÐÎʽ֮һ¡£ÒÑÖªC(ʯī)¡¢H2(g)ȼÉÕµÄÈÈ»¯Ñ§·½³Ìʽ·Ö±ðΪ£º

¢Ù C(ʯī)+O2(g)£½CO(g)    =-111.0 KJ¡¤mol-1

¢Ú H2(g)+ O2(g) £½H20(g)    =-242.0 kJ¡¤mol-1

¢Û C(ʯī)+O2(g)£½CO2(g)      =-394.0 kJ¡¤mol-1    

Çë½â´ðÏÂÁÐÎÊÌ⣺    

£¨1£©»¯Ñ§·´Ó¦ÖÐÓÐÄÜÁ¿±ä»¯µÄ±¾ÖÊÔ­ÒòÊÇ·´Ó¦¹ý³ÌÖÐÓР         µÄ¶ÏÁѺÍÐγɡ£ÉÏÊöÈý¸ö·´Ó¦¶¼ÊÇ           (Ìî¡°ÎüÈÈ¡±»ò¡°·ÅÈÈ¡±)·´Ó¦¡£

£¨2£©ÔÚÈÈ»¯Ñ§·½³ÌʽÖУ¬ÐèÒª±êÃ÷·´Ó¦Îï¼°Éú³ÉÎïµÄ״̬µÄÔ­ÒòÊÇ                                                  £»ÔÚ¢ÙÖУ¬02µÄ»¯Ñ§¼ÆÁ¿Êý¡°1/2¡±ÊDZíʾ      (Ìî×Öĸ)¡£

a£®·Ö×Ó¸öÊý    b£®ÎïÖʵÄÁ¿    c£®ÆøÌåµÄÌå»ý

£¨3£©·´Ó¦2H20(g)£½2H2(g)+02(g)µÄ=        KJ¡¤mol-1¡£

£¨4£©ÈôC(½ð¸Õʯ)+02(g)£½C02(g)µÄ=-395.0 kJ¡¤mol-1£¬ÔòÎȶ¨ÐÔ£º½ð¸Õʯ          (Ìî¡°£¾¡±¡¢¡°£¼¡±»ò¡°£½¡±)ʯī¡£

£¨5£©ÒÑÖªÐγÉH20(g)ÖеÄ2 mol H-O¼üÄܷųö926.0 kJµÄÄÜÁ¿£¬ÐγÉ1 mol 02(g)ÖеĹ²¼Û¼üÄܷųö498.0 kJµÄÄÜÁ¿£¬Ôò¶ÏÁÑ1 mol H2(g)ÖеÄH-H¼üÐèÒªµÄÄÜÁ¿          KJ¡£

£¨6£©¹¤ÒµÖÆÇâÆøµÄÒ»¸öÖØҪ;¾¶ÊÇÓÃCO(g)ÓëH2O(g)·´Ó¦Éú³ÉC02(g)ºÍH2(g)£¬Ôò¸Ã·´Ó¦µÄÈÈ»¯Ñ§·½³ÌʽÊÇ                                                     ¡£

 

¡¾´ð°¸¡¿

 

£¨1£©»¯Ñ§¼ü    ·ÅÈÈ

£¨2£©·´Ó¦ÈÈÓë·´Ó¦Îï¼°Éú³ÉÎïµÄ״̬µÈÒòËØÓйأ¨ºÏÀí´ð°¸¾ù¿É£©   b

£¨3£©484.0        £¨4£©£¼        £¨5£©435.0

£¨6£©CO(g)£«H2O(g)£½CO2(g)£«H2(g)  ¡÷H£½£­41 kJ¡¤mol£­1

¡¾½âÎö¡¿

ÊÔÌâ·ÖÎö£º£¨2£©ÎïÖÊ״̬²»Í¬Ëùº¬ÓеÄÄÜÁ¿²»Í¬£¬×´Ì¬Ö®¼äµÄת»¯°éËæ×ÅÄÜÁ¿µÄ±ä»¯£¬ËùÒÔÈÈ»¯Ñ§·½³ÌʽÖбØÐë±íÃ÷ÎïÖʵÄ״̬£»£¨3£©¸Ã·´Ó¦µÄÊÇ·´Ó¦¢ÚµÄ2±¶µÄÏà·´Êý£¨ÓÉ·½³ÌʽÅжϣ©£»ÈÈ»¯Ñ§·½³ÌʽÖеļÆÁ¿Êý¾ùÖ¸ÎïÖʵÄÁ¿£¬Ã»ÓÐ΢¹ÛµÄº¬Ò壻£¨4£©ÎïÖʺ¬ÓеÄÄÜÁ¿Ô½¶à£¬Îȶ¨ÐÔÔ½²î£¬½ð¸ÕʯÉú³Éʯī·Å³öÄÜÁ¿£¬µÃ³ö½ð¸Õʯº¬ÓÐÄÜÁ¿¸ß£¬Îȶ¨ÐԲ

£¨5£©¶ÏÁÑ1 mol H2(g)ÖеÄH-H¼üÐèÒªµÄÄÜÁ¿=926.0-498.0¡Â2- 242.0 =435.0 KJ£»

£¨6£©·´Ó¦¢Û£­¢Ù£­¢ÚµÃµ½CO(g)£«H2O(g)£½CO2(g)£«H2(g)  ¡÷H£½£­41 kJ¡¤mol£­1

¿¼µã£º¿¼²é·´Ó¦ÈÈÓйØÎÊÌâ¡£

 

Á·Ï°²áϵÁдð°¸
Ïà¹ØÌâÄ¿

Î¥·¨ºÍ²»Á¼ÐÅÏ¢¾Ù±¨µç»°£º027-86699610 ¾Ù±¨ÓÊÏ䣺58377363@163.com

¾«Ó¢¼Ò½ÌÍø