题目内容
在一定条件下,合成氨反应为:N2+3H2?2NH3,在2L密闭容器中进行,5min内氨的质量增加了1.7g,则5min内此反应以各物质的浓度变化表示的平均反应速率中不正确的是( )
A、v(H2)=0.015mol/(L?min) | B、v(N2)=0.005mol/(L?min) | C、v(NH3)=0.0017mol/(L?min) | D、v(NH3)=0.01mol/(L?min) |
分析:在2L密闭容器中进行,5min内氨的质量增加了1.7g,n(NH3)=
=0.1mol,v(NH3)=
=0.01mol/(L.min),结合反应速率之比等于化学计量数之比来解答.
1.7g |
17g/mol |
| ||
5min |
解答:解:在2L密闭容器中进行,5min内氨的质量增加了1.7g,n(NH3)=
=0.1mol,v(NH3)=
=0.01mol/(L.min),
A.v(H2)=0.01mol/(L.min)×
=0.015mol/(L.min),故A正确;
B.v(N2)=0.01mol/(L.min)×
=0.005mol/(L?min),故B正确;
C.v(NH3)=
=0.01mol/(L.min),故C错误;
D.v(NH3)=
=0.01mol/(L.min),故D正确;
故选C.
1.7g |
17g/mol |
| ||
5min |
A.v(H2)=0.01mol/(L.min)×
3 |
2 |
B.v(N2)=0.01mol/(L.min)×
1 |
2 |
C.v(NH3)=
| ||
5min |
D.v(NH3)=
| ||
5min |
故选C.
点评:本题考查化学反应速率的计算及速率与化学计量数的关系,把握计算公式及反应速率之比等于化学计量数之比为解答的关键,注重基础知识的考查,题目难度不大.
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